Mineralogy and geochemistry of El Dorado epithermal gold deposit, El Sauce district, central-northern Chile

Summary The El Dorado Au-Cu deposit is located in an extensive intra-caldera zone of hydrothermal alteration affecting Upper Cretaceous andesites of the Los Elquinos Formation at La Serena (≈ 29°47′S Lat., 70°43′W Long., Chile). Quartz-sulfide veins of economic potential are hosted by N25W and N20E fault structures associated with quartz-illite alteration (+supergene kaolinite). The main ore minerals in the deposit are pyrite, chalcopyrite ± fahlore (As/(As + Sb): 0.06−0.98), with electrum, sphalerite, galena, bournonite-seligmanite (As/(As + Sb): 0.21−0.31), marcasite, pyrrhotite being accessory phases. Electrum, with an Ag content between 32 and 37 at.%, occurs interstitial to pyrite aggregates or along pyrite fractures. Pyrite commonly exhibits chemical zonation with some zones up to 1.96 at.% As. Electron probe microanalyses of pyrite indicate that As-rich zones do not exhibit detectable Au values. Fluid inclusion microthermometry shows homogenization temperatures between 130 and 352 °C and salinities between 1.6 and 6.9 wt.% NaCl eq. Isotope data for quartz, ankerite and phyllosilicates and estimated temperatures show that δ¹⁸O and δD for the hydrothermal fluids were between 3 and 10‰ and between −95 and −75‰, respectively. These results suggest the mineralizing fluids were a mixture of meteoric and magmatic waters. An epithermal intermediate-sulfidation model is proposed for the formation of the El Dorado deposit. Author’s present address: J. Carrillo-Rosúa, Dpto. de Didáctica de las Ciencias Experimentales, Universidad de Granada, Campus de Cartuja, 18071, Granada, Spain     

Boron incorporation into mullite

Summary Boron-doped mullites were synthesized using aluminium nitrate-nonahydrate, tetraethoxysilane and boric acid in a sol–gel process with subsequent annealing at 950 and 1300 °C for five hours. Two different bulk compositions with constant Al₂O₃ contents (60 and 70 mol%, respectively) and varying SiO₂ plus B₂O₃ contents were investigated. X-ray powder diffraction analyses yielded a linear decrease of the lattice parameters with increasing bulk B₂O₃ content, which was interpreted as to be due to boron incorporation. Related to the increasing boron content, corresponding infrared spectra revealed a slight and continuous shift for most of the absorption bands. These data show that mullite is able to incorporate large amounts of boron into its structure (up to about 20 mol% B₂O₃ depending on the bulk composition of the starting materials). Infrared analyses suggest that boron is incorporated into the mullite structure in form of planar three-fold coordinated BO₃ groups. Author’s address: A. Beran, Institut für Mineralogie und Kristallographie, Universit?t Wien-Geozentrum, Althanstra?e 14, 1090 Wien, Austria     

Methodology of hydrogeological characterization of deep carbonate aquifers as potential reservoirs of groundwater. Case of study: the Jurassic aquifer of <Emphasis Type="Italic">El Maestrazgo</Emphasis> (Castellón,Spain)

A methodology for the characterization of deep carbonate aquifers has been developed and applied to El Maestrazgo Jurassic aquifer in Castellón, Spain. Characterization of these aquifer formations, located at more than 300 m deep, consisted of a previous phase of compilation, analysis and synthesis of the existing information about the area, followed by a coordinated combination of different speciality studies: geology, stratigraphy, structural analysis, hydrogeology, hydrochemistry, geophysics and remote sensing. Geological studies included geological mapping, definition of stratigraphical units and facies and structural analysis. The aim of the hydrogeology study was to define aquifer formations, recharge area, aquifer points inventory and groundwater flow directions for the establishment of piezometric and water quality observation nets. Special techniques were applied, like thermal infrared aerial images and the evaluation of submarine groundwater discharge by means of natural radium isotopes. Hydrochemical techniques, including majority elements characterization and stable isotopes (¹⁸O, ²H and ³H) determination, allowed classifying hydrochemical facies and establishing a renewal pattern for water within the system. Geophysics was useful in determining the aquifer geometry, the features of the basement and the petrophysical characteristics of the geological formations. Preliminary results show an important tectonic complexity and the possibilities for groundwater uses in the area of study.     

Nonlinear Analysis of Local Site Effects on Seismic Ground Response in the Bam Earthquake

The influence of local geologic and soil conditions on the intensity of ground shaking is addressed in this study. The amplification of the ground motion due to local site effects resulted in severe damage to dwellings in the Bam area during the 2003 Bam Earthquake. A unique set of strong motion acceleration recordings was obtained at the Bam accelerograph station. Although the highest peak ground acceleration recorded was the vertical component (nearly 1 g), the longitudinal component (fault-parallel motion) clearly had the largest maximum velocity as well as maximum ground displacement. Subsurface geotechnical and geophysical (down-hole) data in two different sites have been obtained and used to estimate the local site condition on earthquake ground motion in the area. The ground response analyses have been conducted considering the nonlinear behavior of the soil deposits using both equivalent linear and nonlinear approaches. The fully nonlinear method embodied in FLAC was used to evaluate the nonlinear soil properties on earthquake wave propagation through the soil layer, and compare with the response from the equivalent linear approach. It is shown that thick alluvium deposits amplified the ground motion and resulted in significant damage in residential buildings in the earthquake stricken region. The comparison of results indicated similar response spectra of the motions for both equivalent and nonlinear analyses, showing peaks in the period range of 0.3–1.5 s. However, the amplification levels of nonlinear analysis were less than the equivalent linear method especially in long periods. The observed response spectra are shown to be above the NEHRP building code design requirements, especially at high frequencies.     

Analysis of the 2003 Varunawat Landslide,Uttarkashi, India using Earth Observation data

Mass movements such as landslides in mountainous terrains are natural degradation processes and one of the most important landscape-building factors. Varunawat Parbat overlooking Uttarkashi town witnessed a series of landslides on 23 September 2003 and the debris slides and rock falls continued for 2 weeks. This landslide complex was triggered due to the incessant rainfall prior to the event, and its occurrence led to the blockage of the pilgrim route to Gangotri (source of the Ganges river) and evacuation of thousands of people to safer places. Though there was no loss of lives due to timely evacuation, heavy losses to the property were reported. High-resolution stereoscopic earth observation data were acquired after the incidence to study the landslide in detail with emphasis on the cause of the landslide and mode of failure. Areas along the road and below the Varunawat foothill region are mapped for landslide risk. It was found that the foothill region of the Varunawat Parbat was highly disturbed by man-made activities and houses are dangerously located below steep slopes. The potential zones for landslides along with the existing active and old landslides are mapped. These areas are critical and their treatment with priority is required in order to minimise further landslide occurrences.     

Cyclotron amplification of geomagnetic micropulsations Pc1 in the magnetosphere

A numerical analysis of cyclotron instabilities is carried out by computing the dispersion relation for a three component cold plasma-beam system. Rates of growth and damping for various values of the stream density are calculated from the dispersion relation. The rates of growth and damping increase monotonically as the number density of the proton stream increases. It is found that the frequencies at the rates of maximum growth and the damping decrease slightly to lower frequencies and a sharp peak at these frequencies becomes blunt. The minimum e-folding times of an ion cyclotron wave for (a) σ_s = 10⁻⁴, σ_i = 10⁻² and (b) σ_s = 10⁻¹, σ_i = 10⁻² are about 3·84 and 0·16 sec respectively in the vicinity of the equatorial plane at 6 Re, where σ_s and σ_i are the ratios of the beam density N_s and the helium ion (H₆⁺) density N_i to the total positive ions in the plasma-beam system.     

SOME EXPERIMENTS CONCERNING THE PRIMARY SEISMIC PULSE*

Recordings were made with three types of detector of the primary compressional (P) and shear (S) wave pulses generated by explosions in boreholes. Charge weights varied from 0.08 kg to 9.5 kg and detector distances varied from about 3 m to about 80 m. Scaling by the simple factor W^1/3 where W is the charge weight, enabled observations from different sized charges to be fitted to a single expression. Experiments were carried out in the Bunter sandstone and the London clay and both fluid and solid tamping were used. This variation in tamping had no significant effect on the P-waves but it may have affected the generation of SV-waves. In both media the P-wave energy carried at 30 m from the shot by frequencies less than 100 Hz decreased rapidly with depth and was usually 1–2 % of the available chemical energy for a shot depth of 15 m. The S-wave energy was much less than this, but was highly directional. The P-wave pulse had the appearance of a damped sinusoid in very good agreement with the predictions of the ‘equivalent radiator’ hypothesis. However, the surface of this radiator should be identified not with the blown cavity but with the surface at which the tensile stresses associated with the stress wave become less than the tensile strength of the rock. The predominant frequency for a 1 kg charge at a depth of 15 m was 24 Hz in the clay and 52 Hz in the sandstone. In these and similar media, therefore, an effort should be made to keep individual charges less than 1 kg in reflection shooting and less than 10 kg in refraction shooting. The value of Q was about 50 in clay and about 25 in the sandstone. These estimates are rather uncertain because of the small distances over which the pulses were observed. The Z-transforms of the sampled pulses indicated that they were all of minimum phase, or very near to it.