Fluid production and isograd reactions at contacts of carbonate-rich and carbonate-poor layers during progressive metamorphism

ABSTRACT With increasing temperature during prograde metamorphism reactions will occur first at the lithological contacts of mixed pelite and calcsilicate terranes. At these interfaces, a fluid of lower chemical potential of H₂O and CO₂ than that required to produce a fluid in either layer can be produced whether reaction is caused by fluid infiltration or is initially fluid absent. If the interface region does not allow fluid transport then as temperature increases, a fluid pressure greater than lithostatic can develop. At some degree of over-pressure relative to rock pressure, the fluid hydraulically fractures the rock and a gradient in fluid composition away from the contact can be produced. These phenomena occur at the compositional interfaces whenever univariant reactions in the differing layers cross on a temperature vs. mole fraction of CO₂ diagram with slopes of opposite sign. The first occurrence of these reaction products at lithological contacts delineates an isograd that defines temperature as well as the mole fraction of CO₂ at constant pressure in systems open to fluid transport. These isograds can be contrasted with fluid-producing isograds in closed systems. As an illustration of possible effects, the reactions quartz + clinozoisite + muscovite = anorthite + K-feldspar + H₂O and phlogopite + quartz + calcite = tremolite + K-feldspar + H₂O + CO₂ at 4 kbar are analysed and equations for fluid production and transport are developed.     

SHRIMP U–Pb ages of diagenetic and hydrothermal xenotime from the Archaean Witwatersrand Supergroup of South Africa

SHRIMP dating of xenotime overgrowths on detrital zircon grains can constrain maximum durations since diagenesis and therefore provide minimum dates of sediment deposition. Thus, xenotime dating has significant economic application to Precambrian sediment-hosted ore deposits, such as Witwatersrand Au–U, for which there are no precise depositional ages. The growth history of xenotime in the Witwatersrand Supergroup is texturally complex, with several phases evident. The oldest authigenic xenotime ²⁰⁷Pb/²⁰⁶Pb age obtained in sandstone underlying the Vaal Reef is 2764 ± 5 Myr (1 σ), and most likely represents a mixture of diagenetic and hydrothermal growth. Nevertheless, this represents the oldest authigenic mineral age yet recorded in the sequence and provides a minimum age of deposition. Other xenotime data record a spread of ages that correspond to numerous post-diagenetic thermotectonic events (including a Ventersdorp event at ≈ 2720 Ma) up to the ≈2020 Ma Vredefort event.     

The mass ratio of Nova Muscae 1991

We report intermediate resolution H spectroscopy of the black hole candidate Nova Muscae 1991 during quiescence. We classify the companion star as a K3-K4V which contributes 85±6 percent to the total flux from the binary. The photospheric absorption lines are broadened by 106±13 kms⁻¹ with respect to template field stars, leading to a system mass ratio of q =M₁/M₂ = 7.8_−2.0^+3.4. Doppler imaging of the H line shows strong emission coming from the secondary star (EW=3.1±0.6Å) which we associate with chromospheric activity. However, the hot-spot is not detected and this may indicate a lower mass transfer rate than in other X-ray transients of comparable orbital periods. The surface brightness distribution of the accretion disk in H follows a relation I∝R^−1.1, less steep than typically observed in cataclysmic variables. Updated system parameters are also presented.     

Spectral Study of Ionized Xenon Using a Capillary Pulsed Discharge

This work presents preliminaries spectroscopic results about ionized xenon and xenon-helium mixture using a capillary pulsed discharge under several experimental results.     

Structurally controlled gold and sulfosalt mineralization: the Altenberg example, Salzburg Province, Austria

Summary ?In the south-eastern Altenbergkar–Silbereck area in the eastern Tauern window (Lungau, Salzburg) structurally controlled precious-metal (Au–Ag) mineralization is hosted in marbles of the Permo(?)-Mesozoic Silbereck Formation and in the underlying Variscan Central gneiss. During the Alpine otogeny both lithologies were affected by ductile deformation (shearing, D1; folding, D2/D3) and subsequent brittle deformation (tension gashes, D4; normal faulting, D5) related to the uplift and exhumation of the Tauern window. Mineralization is controlled by brittle D4 structures. NE–SW trending steeply dipping tension gashes of the “Tauerngoldgang” type occur within the Central gneiss. Three different marble-hosted ore types following fracture systems as well as foliation and bedding planes can be distinguished: 1) metasomatic replacement ores, 2) ores in tension gashes and 3) ores in talc-bearing structures, often containing high-grade gold and silver mineralization (native gold in association with Ag–Pb–Bi–sulfosalts). Four stages of mineralization can be distinguished which occur in all ore types: arsenopyrite–pyrite–pyrrhotite (first stage), Au–(Ag–Pb–Bi–sulfosalts) (second stage), base-metal sulfides and tetrahedrite–tennantite (third stage) and Ag-rich galena (fourth stage). Preliminary fluid inclusion data indicate temperatures of ore formation well above 300 °C (346 °C mean) for the second stage within the Central gneiss and temperatures between 310 and 230 °C for the second and third stages in the marble. Received October 12, 2001; revised version accepted September 5, 2002 Published online March 10, 2003     

Effect of metamorphism and partial melting of host rocks on zircons

Abstract Zircons have been studied from different layers of migmatites (from Arvika, western Sweden and Nelaug, southern Norway) and from a paragneiss (from Arvika) associated with one of the migmatites. The main purpose of the investigation is to establish whether or not information about zircons can help in the elucidation of the parentage and rock-forming processes of migmatites.
The elongation ratio of zircons from all layers is small and characteristic of sedimentary zircons. Further, the absence of characteristic colours and the growth trends of the zircons (indicated by the reduced major axes) observed in the various samples both support a sedimentary parentage for these rocks. The zircons of all layers exhibit secondary growth (overgrowth, outgrowth and multiple growth) due to metamorphism. Compared with the zircons from the paragneiss, those of the migmatite layers are more clouded and less rounded, some of them becoming opaque or even skeletal; this is especially true of the zircons from the leucosomes. These observations indicate an alteration of the original sedimentary zircons in the migmatite, especially in the leucosomes, in response to the migmatization process, previously interpreted as partial melting.