Occurrence and geochemistry of arsenic in the groundwater of Eastern Croatia

In order to examine the extent of the As enrichment and the factors influencing this enrichment in the groundwater of Eastern Croatia, groundwater samples were collected from 56 production wells in two counties, Osijek-Baranja and Vukovar-Srijem, suspected to be more affected. Hydrochemical analyses were performed at all locations including in situ As speciation at 32 locations. Arsenic was detected in 46 out of 56 groundwater samples with total As concentrations up to 491 μg/L. Thirty-six of the studied wells yielded groundwater with total As concentrations that exceeded the WHO Maximum Contaminant Level for arsenic in drinking water of 10 μg/L. Only inorganic As species were detected with arsenite As(III) as the predominant form. The spatial distribution of As in the groundwater was significantly linked with geological, geomorphological and hydrogeological development of the alluvial basin of the Drava and Sava rivers. The most probable groundwater As sources are deeper sediments from the Middle and Upper Pleistocene. The results obtained suggest that biogeochemical processes controlling As concentration in the groundwater are complex and location-specific. Reductive dissolution of Fe oxides, desorption of As from Fe oxides and/or clay minerals as well as competition for the sorption sites with organic matter and phosphate could be the principal mechanisms that control As mobilization. The extent of those processes vary in the different parts of the Drava and Sava depressions and could be linked to different site related parameters, such as lithology, mineralogy, local hydrology and hydrogeology; thus different processes of As mobilization have been proposed for the different types of water in relation to groundwater evolution.     

The spatial structure of the dayside ionospheric trough

Tomographic imaging provides a powerful technique for obtaining images of the spatial distribution of ionospheric electron density at polar latitudes. The method, which involves monitoring radio transmissions from the Navy Navigation Satellite System at a meridional chain of ground receivers, has particular potential for complementing temporal measurements by other observing techniques such as the EISCAT incoherent-scatter radar facility. Tomographic reconstructions are presented here from a two-week campaign in November 1995 that show large-scale structuring of the polar ionosphere. Measurements by the EISCAT radar confirm the authenticity of the technique and provide additional information of the plasma electron and ion temperatures. The dayside trough, persistently observed at high latitudes during a geomagnetically quiet period but migrating to lower latitudes with increasing activity, is discussed in relationship to the pattern of the polarcap convection.     

The 1 Mpc giant head-tail radio galaxy IC 711: 3-dimensional simulation and additional constraints on the ram pressure theory

Recent observations of the longest known head-tail galaxy IC 711, at long wavelengths have shown it to extend farther than previously known. At δ 74 cm, Vallée and Roger (1987) found it to stretch 17′ (930 kpc) behind the optical nucleus of this elliptical galaxy. At δ92 cm, Vallée and Strom (1988) found it to stretch 18.3′ (1 Mpc) behind the optical nucleus. What new physics can be learned from it? To that end, a theoretical simulation in 3 dimensions of the longest head-tail galaxy has been performed, building the radio trail cell by cell inside a volume of space composed of 8 million cells, with each cell being assigned a proper radio emissivity. Matching ram pressure theory and recent observations yields a primary fast decrease of the radio luminosity with time or distance from the optical nucleus of the galaxy, and a secondary periodic variation of the radio luminosity every 500 kpc. Near the end of the tail, a sudden and unpredicted flare-up of the observed width of the tail requires a sudden change in the jet's physical conditions about 2 Gyr earlier, or that of the surroundings. These simulations provide some additional constraints on the ram pressure theory. Along the tail ridge, particle aging and particle acceleration must combine to give a luminosity function that mimics an exponential decrease with time. Across the tail ridge, no edge brightening is necessary, suggesting that particle aging and particle acceleration must combine via central turbulences and central instabilities (not by edge effects). The disappearance of the radio trail at two points along the radio ridge is unexpected from the ram pressure theory. Thus particle aging and particle acceleration must combine once more to mimic a sinusoidal modulation with time of the radio luminosity, perhaps near the nucleus inside the optical galaxy.     

The Doppler Imaging System: Initial observations of the auroral thermosphere

During December 1982, a novel Fabry-Perot interferometer—a Doppler Imaging System (DIS)— was used at Kiruna Geophysical Institute (KGI), Sweden (67.8°N, 21.2°E) to complement a series of coordinated observations of global thermospheric dynamics utilizing a number of conventional ground-based Fabry-Perot interferometers and the NASA Dynamics Explorer satellite. The DIS is an interferometer with two unique attributes : it has a luminosity or étendue more than one hundred times that of the conventional Fabry-Perot interferometer, and it is also capable of deducing a two-dimensional velocity field of a suitable line-emitting areal source by independently measuring the Doppler shift at a large number of points within the field of view. On 17 December 1982, a very large geomagnetic Storm Sudden Commencement (08.05 U.T.) preceded a major geomagnetic disturbance. During this disturbance, Northern Scandinavia was influenced by a strong eastward auroral electrojet for an extended period (10–19 U.T.). The DIS was able to observe the dynamical response of the upper thermosphere to this event in conjunction with a second Fabry-Perot interferometer (FPI) at KGI. Westward thermospheric winds of about 900 m s^?1 occurred during the disturbance and, at the peak of the disturbance, the combined DIS and FPI observations indicate that the thermospheric flow was quite chaotic. Fluctuations of the order of ± 150 ms^?1, associated with spatial scales of the order of 100 or 200 km occurred within the mean westward flow inside the 800 km diameter region observed from Kiruna.     

A note on estimating the effect of a limited fetch on micrometeorological evaporation measurements

A formula for the effective fetch of micrometeorological evaporation measurements is derived by application of diffusion theory, using Calder's approximation of a uniform wind field and neutral atmospheric stability. This simplification allows estimation of the likely sampling error, which would result from an upwind step-change in evaporation rate, without change in roughness.     

A simplified hydrodynamic mesoscale model suitable for use over high plateau regions

Summary A simplified hydrodynamic primitive equation model in -coordinates is described. This model includes the main physical processes that influence development and motion of mesoscale vortices over plateau regions: elevated terrain effects, effects of large-scale and synoptic-scale systems on the mesoscale systems, sensible heating from the earth's surface, moisture cycle and condensation heating released by both large-scale stable precipitation and cumulus convective precipitation, evaporation and the feedback effect of precipitation on evaporation, friction in the planetary boundary layer, horizontal diffusion by subgrid scale eddies and vertical eddy flux of meteorological elements (momentum, temperature, moisture, etc.) due to turbulence, cumulus convection and other smaller-scale physical processes. The model incorporates observed data as much as possible and equations are simplified so that it may be run using either a high-speed computer or a desktop computer.Two developing vortices that originated over the Qinghai-Xizang (Tibet) Platau and moved eastward producing heavy precipitation over the lower elevations are used to test the model. It is shown that the model is capable of simulating the major features of the vortices including the precipitation distribution and may be used for studies of mesoscale and synoptic scale weather systems over plateau regions.

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Ein vereinfachtes für hochländer geeignetes hydrodynamisches mesoscale-modell

Zusammenfassung Es wird ein vereinfachtes hydrodynamisches Grundgleichungsmodell in -Koordinaten be schrieben. Dieses Modell beinhaltet die wichtigsten physikalischen Prozesse, die die Entwicklung und Bewegung von mesoskaligen Wirbeln über Hochplateaus beeinflussen: Effekte der Hochfläche, Effekte von großräumigen und synoptischen Systemen, die fühlbare Wärme von der Erdoberfläche, den Feuchtigkeitskreislauf und die Kondensationswärme, sowohl von großräumigen als auch von Konvektionsniederschlägen, die Evaporation und die Beeinflussung der Evaporation durch den Niederschlag, die Reibung in der planetaren Grenzschicht, die horizontale Diffusion durch Turbulenzen, die kleiner als die Gitterkonstante sind und den vertikalen Fluß meteorologischer Elemente (Impuls, Temperatur, Feuchte etc.) durch Turbulenzen, Konvektion und andere kleinräumige Prozesse. In das Modell sind die Beobachtungswerte weitestgehend integriert und die Gleichungen soweit vereinfacht, daß es sowohl auf einem Hochleistungs- als auch auf einem Mikrocomputer laufen kann.Zum Testen des Modells wurden zwei sich entwickelnde Wirbel verwendet, die vom Qinghai-Xizang-Plateu (Hochland von Tibet) ausgingen, sich ostwärts bewegten und dabei zu schweren Niederschlägen in den Tiefländern führten. Es wird gezeigt, daß das Modell die wichtigsten Eigenschaften der Wirbel und die Niederschlagsverteilung simulieren und für Untersuchungen von mesoskaligen und synoptischen Wettersystemen über Hochländern herangezogen werden kann.

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With 18 figures     

The impact of doubled CO2 on the energetics and hydrologic processes of mid-latitude transient eddies

The Northern Hemisphere winter (DJF) stationary eddy response of a general circulation model (GCM) to a doubling of atmospheric CO₂ is simulated with a linear steady state model as a response to anomalies in diabatic heating (latent, sensible and radiative), mountain and transient eddy effects. For this analysis the doubled CO₂ experiment performed by Wilson and Mitchell (1987) is used. The linear simulations of the control and perturbation climate capture most of the important features of the GCMs stationary eddies. The simulation of the anomalous stationary eddy pattern in the Northern Hemisphere captures only some of the important features of the GCMs anomalies. The climate anomalies in the Southern Hemisphere are poorly simulated. In the Northern Hemisphere the climate anomalies are dominated by the effect of transient eddies and mountains. In low latitudes also the contribution of latent heating is important. The contributions of sensible and radiative heating are small.     

Kankan diamonds (Guinea) III: δ13C and nitrogen characteristics of deep diamonds

Diamonds from the Kankan area in Guinea formed over a large depth profile beginning within the cratonic mantle lithosphere and extending through the asthenosphere and transition zone into the lower mantle. The carbon isotopic composition, the concentration of nitrogen impurities and the nitrogen aggregation level of diamonds representing this entire depth range have been determined. Peridotitic and eclogitic diamonds of lithospheric origin from Kankan have carbon isotopic compositions ('¹³C: peridotitic -5.4 to -2.2‰; eclogitic -19.7 to -0.7‰) and nitrogen characteristics (N: peridotitic 17-648 atomic ppm; eclogitic 0-1,313 atomic ppm; aggregation from IaA to IaB) which are generally typical for diamonds of these two suites worldwide. Geothermobarometry of peridotitic and eclogitic inclusion parageneses (worldwide sources) indicates that both suites formed under very similar conditions within the cratonic lithosphere, which is not consistent with a derivation of diamonds with light carbon isotopic composition from subducted organic matter within subducting oceanic slabs. Diamonds containing majorite garnet inclusions fall to the isotopically heavy side ('¹³C: -3.1‰ to +0.9‰) of the worldwide diamond population. Nitrogen contents are low (0-126 atomic ppm) and one of the two nitrogen-bearing diamonds shows such a low level of nitrogen aggregation (30% B-centre) that it cannot have been exposed to ambient temperatures of the transition zone (̿,400 °C) for more than 0.2 Ma. This suggests rapid upward transport and formation of some Kankan diamonds pene-contemporaneous to Cretaceous kimberlite activity. Similar to these diamonds from the asthenosphere and the transition zone, lower mantle diamonds show a small shift towards isotopic heavy compositions (-6.6 to -0.5‰, mode at -3.5‰). As already observed for other mines, the nitrogen contents of lower mantle diamonds were below detection (using FTIRS). The mutual shift of sublithospheric diamonds towards isotopic heavier compositions suggests a common carbon source, which may have inherited an isotopic heavy composition from a component consisting of subducted carbonates.     

Fan beheading and drainage diversion as evidence of a 3200-2800 BP earthquake event in the Esmeraldas-Tumaco seismic zone: A case study for the effects of great subduction earthquakes

The San Lorenzo area belongs to the Esmeraldas–Tumaco seismic zone where some of the strongest earthquakes of South America occurred during the 20th century. This paper provides evidence for a succession of geomorphic changes characterized by the disruption of the Quaternary drainage network and the reshaping of the Cayapas–Santiago estuary. The rise of the La Boca uplift bordered by the La Boca and San Lorenzo faults is responsible for the southward diversion of the Palabi, Tululbi, Bogotá and Carolina rivers toward the Santiago and Cayapas rivers. The increase of the discharge directed to the Cayapas River generated the change of the channel pattern downstream from the confluence, and the avulsion of a new estuary through the coastal plain. According to the dating of beach ridges the avulsion occurred in the period 3200–2800 BP. This period corresponds also to a faster accretion of the beach ridge margin, interpreted as a response to a small uplift of the shore. The coherency of the three morphologic evidences—diversion of drainage network, avulsion and increase of coastal accretion—suggest a unique morphotectonic event, in relation with the activity of the Esmaraldas–Tumaco seismic zone. The opening of a direct communication through the mangrove margin may have brought favorable conditions for the development of the La Tolita archaeological site after 3000 BP.     

Comparing palaeolimnological and instrumental evidence of climate change for remote mountain lakes over the last 200 years

This paper compares the palaeolimnological evidence for climate change over the last 200 years with instrumental climate data for the same period at seven European remote mountain lakes. The sites are Øvre Neådalsvatn (Norway), Saanajärvi (Finland), Gossenköllesee (Austria), Hagelseewli (Switzerland), Jezero v Ledvici (Slovenia), Estany Redó (Spain, Pyrenees), and Niné Terianske Pleso (Slovakia). We used multiple regression analysis to transfer homogenised lowland air temperature records to each of the sites, and these reconstructions were validated using data from on-site automatic weather stations. These data showed that mean annual temperature has varied over the last 200 years at each site by between 1 and 2 °C, typical of the high frequency variability found throughout the Holocene, and appropriate, therefore, to test the sensitivity of the various proxy methods used. Sediment cores from each site were radiometrically dated using ²¹⁰Pb, ¹³⁷Cs and ²⁴¹Am and analysed for loss-on-ignition, C, N, S, pigments, diatoms, chrysophytes, Cladocera and chironomids. Comparisons between the proxy data and the instrumental data were based on linear regression analysis with the proxy data treated as response variables and the instrumental data (after smoothing using LOESS regressions) as predictor variables. The results showed few clear or consistent patterns with generally low or very low r² values. Highest values were found when the data were compared after smoothing using a broad span, indicating that some of the proxy data were capturing climate variability but only at a relatively coarse time resolution. Probable reasons for the weak performance of the methods used include inaccurate dating, especially for earlier time periods, the influence of confounding forcing factors at some sites e.g., air pollution, earthquakes, and the insensitivity of some methods to low amplitude climate forcing. Nevertheless, there were trends in some proxy records at a number of sites that had a relatively unambiguous correspondence with the instrumental climate records. These included organic matter and associated variables (C and N) and planktonic diatom assemblages at the majority of sites and chrysophytes and chironomids at a few sites. Overall for longer term studies of the Holocene, these results indicate the need to be cautious in the interpretation of proxy records, the importance of proxy method validation, the continuing need to use reinforcing multi-proxy approaches, and the need for careful site and method selection.