Röntgenmikroanalytische untersuchungen an titanomagnetiten tertiärer eflfusiva zur lösung gesteinsmagnetischer fragen

Zusammenfassung Gesteinsmagnetische Studien haben gezeigt, daß für das Verstandnis des jeweiligen magnetischen Verhaltens von Gesteinen u. a. detaillierte mineralogischoptische und nicht zuletzt chemische Untersuchungen nötig Bind. Zum Studiurim der Verteilung der Elemente im Erzkorn wurde die Röntgenmikroanalyse benutzt.Die Methode der Röntgenmikroanalyse wird beschrieben. Die Ergebnisse der Untersuchungen an Titanomagnetiten tertiärer Effusiva kennzeichnen die Inhomogenität der chemischen Verteilung im Erzkorn und lassen die Klärung von Phänomenen zu, die mit Hilfe der durchschnittlichen chemischen Analyse Bowie magnetothermischen u. a. Untersuchungen nicht möglich war.

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Studies on magnetic rocks have demonstrated that detailed informations on composition within ore-particles are needed in order to understand the respective magnetic behaviour. For studying such compositions microanalytic X-ray methods are used.The applied microanalyser is described.Results, gained on this way with tertiary effusiva, let recognize the inhomogenity of composition e.g. within titanomagnetites. They allow clarifying of phenomena, which cannot be understood on another way.

     

Melting Relationships in the System CaO-MgO-CO2-H2O, with Petrological Applications

Phase relationships on the vapor-saturated liquidus surfacein the system CaO-MgO-CO₂-H₂O have been deduced from data inthe systems CaO CO₂-H₂O, CaO-MgO-CO₂, and MgO-CO₂-H₂O, and frompreliminary experiments in the quaternary system. These areillustrated in composition tetrahedra, and in isobaric sectionsthrough the petrogenetic model. The univariant PT curve forthe beginning of melting lies between 625? C and 600? C in thepressure range 10 bars to 4 kilobars, in the presence of a vaporphase rich in H₂O. The curve is divided into three sectionsby two invariant points, each section having a different primarymagnesian phase involved in the melting reaction. Periclaseoccurs on the low-pressure section (less than about 1 kilobar),and with increasing pressure first brucite and then dolomitebecome stable on the liquidus. The pressure of the second invariantpoint, above which dolomite is stable on the liquidus, is notknown. The effect of FeO as an additional component is considered.Processes of crystallization resulting from changes in temperature,in pressure, and in the composition of the vapor phase are discussed.These processes are applied to the crystallization and differentiationof carbonatite magmas, and the reverse processes involving fusionare applied to the metamorphism of dolomites. Crystallizationdifferentiation of a carbonatite magma could produce the sequenceof intrusion observed at some carbonatite complexes: calcitics?vite, followed by ankeritic s?vite, and finally sideriticcarbonatite. Partial melting may occur during the thermal metamorphismof dolomites, but melting is unlikely during regional metamorphism.     

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Ohne Zusammenfassung     

The volcano-magnetic effect

Summary A geometrically simple volcano is considered, havig a spherical magma chamber of 2.5 km radius centred at 10 km depth. The Curie point isotherm is assumed to be a plane at 20 km depth, except for the spherical volume which is also non-magnetic. The stress pattern in the vicinity of the spherical chamber, due to regional stress of sufficient intensity to cause an eruptions, is used to calculate the change in magnetization which results from the piezomagnetic effect through the volume of solid rock. The consequent magnetic field anomaly at the surface is then obtaied by numerical integration of the dipole law of force over the stressed volume. For rocks of the type found on the volcanic island of St. Vincent (West Indies), this model gives a maximum local volcano-magnet c effect of about 7 gammas.     

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IDENTIFYING AND ASSESSING PROBLEM AREAS IN SOIL EROSION SURVEYS USING AERIAL PHOTOGRAPHS

Gully erosion has for many years been a problem in Rhodesia1s Tribal Trust Lands. This paper describes how Soil Conservation Service staff, with no previous ground knowledge of these areas, used good quality 1/25,000 scale aerial photographs to measure the extent of the gully erosion and to pinpoint erosion “black spots.” This enabled quick and reliable estimates of the cost of reclamation work to be made without the need for time-consuming field survey. The survey method discussed is capable of wide application wherever gully erosion occurs and needs to be brought under control.     

SUPER-WIDE ANGLE PHOTOGRAPHY AND ITS APPLICATION WITH VARIOUS TECHNIQUES

Some of the advantages and disadvantages of super-wide angle photography are discussed. Special reference is made to photography of an area in Bechuanaland, when airborne profile recorder and horizon camera were used in conjunction with aerial photography. Data from these ancillary aids were used in the subsequent adjustment procedure. The paper concludes with an account of analytical bridging using super-wide angle photography and a monocomparator.     

Ion-exchange reactions on clay minerals and cation selective membrane properties as possible mechanisms of economic metal concentration

A series of exploratory experiments on the concentration of base metals through ion exchange reactions on clay minerals show promising results. The extraction of Pb, Zn and Cd from bentonite, illite, kaolinite and montmorillonite was successful and megascopic quantities of PbS, CdS and ZnS could be obtained at specific loci, depending essentially on the flow velocity, and the other cations present. These or similar exchange reactions are tentatively proposed as possible mechanisms of economic metal concentration during diagenesis.

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Zusammenfassung Es werden experimentelle Resultate zur Anreicherung von Schwermetallen durch Tonminerale (Montmorillonite, Illite und Kaolinite) mitgeteilt. Eine erste Anreicherung kann über den Kationenaustausch bewirkt werden. In dem darauffolgenden zweiten, sehr viel wirksameren Schritt werden die Schwermetallionen aus den Tonlagern extrahiert und in deren Nähe als schwerlösliche Sulfide oder Carbonate gefällt. Die Extraktion beruht darauf, daß Tonschichten als Kationen-permeable Membranen wirken können. Sie wird von der Art der Tonminerale und der Kationen, den Lösungsgenossen, den Konzentrationsverhältnissen, dem pH-Wert, der Reaktionstemperatur, dem Porenvolumen und der Porenverteilung im Sediment beeinflußt.