Wind and freshwater influence over hydrocarbon dispersal on Patos Lagoon, Brazil

The two-dimensional barotropic, hydrodynamic and transport model MOHID is applied to the Patos Lagoon system using a nested modelling approach to reproduce both the lagoon and estuary hydrodynamics. A new Lagrangian oil spill model is presented and used to simulate a hypothetical oil spill in the estuary. Hydrodynamic fields are validated and used to force the oil model. Results show that the hydrodynamics of this system is mainly controlled by the wind and freshwater discharge. The dispersion, concentration and thickness evolution of the oil in the first day after the spill is determined by the equilibrium between these two factors. The freshwater discharge is the major factor controlling the oil dispersion for discharges greater than 5000 m3 while the wind assumes control for lower discharge amounts. The results presented are a first step toward a coastal management tool for the Patos Lagoon.     

The spatial focus of U.S. interstate migration flows

"Despite the widespread interest in the changing geographies of national migration regimes, it is somewhat remarkable that no widely accepted measure of the spatial concentration or focus exhibited by such geographies has emerged. We examine four of the most popular indices of inequality in this paper and contrast their performance as measures of spatial focus. Adopting the coefficient of variation as our preferred alternative, we go on to examine the spatial focus of aggregate interstate migration steams in the U.S. over time. Then we consider disaggregations of the migration streams by age, race and nativity, and examine the role of states as national redistributors of these same subpopulations."     

Precipitation of heavy metals in produced water: influence on contaminant transport and toxicity

Produced water undergoes changes in its physical chemistry including precipitation of heavy metals after being discharged and mixed with ambient seawater. Potential impacts of the precipitation of heavy metals on their transport and toxicity were studied using samples from offshore oil production sites on the Scotian Shelf off eastern Canada. Concentrations of aluminum, cadmium, chromium, cobalt, copper, iron, lead, manganese, nickel and zinc were measured in total, particulate and dissolved fractions together with Microtox tests for assessment of toxicity. Heavy metals in produced water were transformed from dissolved to particulate phase in a period of hours under oxygenated conditions, and aggregated to larger particles that settle rapidly (>100 m/day) over a few days. In addition, there was production of buoyant particles comprised of heavy metal precipitates sequestered onto oil droplets that were transported to the surface. The particulate fraction was generally more toxic than the dissolved fraction. This was evident at the mixing interface between produced water and seawater where elevated particulate and toxicity levels were observed. Laboratory studies suggest an increase in the toxicity of discharged produced water over time. Time-series experiments showed a sustained toxic response for more than a week following the oxidation of freshly discharged produced water that initially elicited little or no toxic response in the Microtox test. Chemical processes identified in this study, namely precipitation of heavy metals and consequent settling and rising fluxes of particles, will influence the toxicity, the fate and the transport of potential contaminants in the produced water. Therefore, these processes need to be considered in assessment of the environmental impact associated with offshore oil and gas operations.     

High matrix interference affecting detection of PAH metabolites in bile of Atlantic hagfish (Myxine glutinosa) used for biomonitoring of deep-water oil production

The characteristic biology and wide distribution of hagfish species makes them relevant for use in pollution biomonitoring at great water depths, particularly in regions where deep-water oil production may take place. The exposure of fish to petrogenic contaminants can normally be detected from the level of polycyclic aromatic hydrocarbon (PAH) metabolites in bile fluid. Some of these metabolites are strong fluorophores, allowing analytical detection by means of simple fluorometric techniques such as fixed wavelength fluorescence (FF) and synchronous fluorescence scanning (SFS). In the present study bile from Atlantic hagfish (Myxine glutinosa) collected in pristine areas (Barents Sea and southwestern Norway) displayed strong bile fluorescence levels, suggesting the presence of PAH contaminants. However, gas-chromatography-mass spectrometry (GC-MS) analyses ruled out PAHs as the origin for this fluorescence signal. Rather, the bile of Myxine contains components resulting in unusually strong background fluorescence interfering at the wavelength pairs used for detection of PAH metabolites. Possible background for the observed matrix interference and implications for detection of PAH metabolites in hagfish is discussed.     

粉红色红拟抱球虫在冲绳海槽区的发现及地层意义

近年来,我们在冲绳海槽区进行大量工作.本文就Z14-6孔(27°07′N127°27′E)首次发现粉红色红拟抱球虫,及稳定同位素测定,进行对比研究,证明了Thompson等1979年所提出的粉红色拟抱球虫在印度-太平洋海域灭绝时代在距今120000年左右的观点.     

渤海三维潮流数值模拟

本模型以具有自由面的三维非线性Ｎａｖｉｅｒ－Ｓｒｏｋｅｓ方程为基本方程，经σ坐标变换得到模式方程。基于过程分裂法，将三维流动中的快过程与慢过程劈开，并对每部分选用适合其物理特性和数值行为的计算格式，然后耦联求解。应用本模型详细计算了渤海的三维潮运动。其中，潮波系统模拟获得理想的结果；采用十层模式计算了Ｍ２潮流，以较高的辨率揭示了潮流的空间结构特征。最后本文给出了三维潮流预报的应用实例。