Composition, distribution and sources of polycyclic aromatic hydrocarbons in sediments of the Gulf of Trieste, Northern Adriatic Sea

The composition, distribution and the sources of polycyclic aromatic hydrocarbons (PAHs) in the surficial sediments of the Gulf of Trieste were investigated. To document the spatial PAH input, surficial sediment samples from 17 locations throughout the Gulf were analysed. The total PAH load determined in the surficial sediment samples are between 30 and 600 ng g-1, and were the highest in the immediate vicinity of the Port of Trieste. The PAH contents decline rapidly with increasing distance from the shore. The ratios of methylphenanthrenes/phenanthrene and methylpyrene/pyrene are sensitive indicators of the origin of PAH pollution in the Gulf which is mostly pyrolitic. The phenanthrene/anthracene ratio was used to determine the approximate location and distance from the source of PAH pollution, while 1-methy 1-7-isopropylphenanthrene (retene) was used as indicator for forest fires. A sediment depth profile indicates a major increase in the PAH concentrations after the First World War.     

Hydrocarbon contamination of coastal sediments from the Sfax area (Tunisia), Mediterranean Sea

The coastal area off the city of Sfax (730,000 inhabitants), well-known for fisheries and industrial activities, receives high inputs of organic matter mostly anthropogenic. Eighteen stations were selected in the vicinity of the direct discharge of industrial sewage effluents in the sea in order to study the spatial distribution of the organic contamination. Surface sediments sampled in the shallow shelf were analysed for hydrocarbons by Fourier transform infrared spectroscopy, gas chromatography and gas chromatography/mass spectrometry. Total hydrocarbon distributions revealed high contamination as compared to other coastal Mediterranean sites, with an average concentration of 1865 ppm/dry weight sediment. Gas chromatographic distribution patterns, values of unresolved mixture/n-alkane ratio and distributions of steranes and hopanes confirmed a petroleum contamination of the Arabian light crude oil type. Biogenic compounds were also identified with a series of short-chain carbon-numbered n-alkenes in the carbon range 16-24.     

Hepatic 7-ethoxyresorufin O-deethylase activity in eel (Anguilla anguilla) from the Thames Estuary and comparisons with other United Kingdom Estuaries

Hepatic microsomal 7-ethoxyresorufin O-deethylase (EROD) activities (indicative of exposure to polycyclic aromatic hydrocarbons (PAHs) and polychlorobiphenyls (PCBs)) were measured in eel Anguilla anguilla from the Thames Estuary. Fish were collected from up to 13 sites during November 1997, May and August 1998 and October 1999. Throughout this period no clear seasonal variation could be identified at every site along the Thames. However, during the summer months, fish sampled from sites in the middle to the upper estuary (Woolwich, Greenhithe and West Thurrock) reported up to 3-fold higher EROD activities compared to sites either at the upper reaches (Richmond and Brentford) at the same time of the year, or fish sampled in winter, along the entire length of the estuary. A laboratory exposure experiment demonstrated a 3-fold elevation of EROD activity 2 days after injection with β-naphthoflavone (β-NF). However, higher levels of activity could be determined in fish sampled from the Weston canal near the Merseyside. The lowest levels of A. anguilla EROD activity were observed in fish sampled from the upper reaches of the River Tamar, Devon, and were comparable to activities determined in fish from the Wear and Humber estuaries. A. anguilla sampled along the Thames, Tyne and Tees estuaries reported between 2.5- and 7-fold higher EROD activities compared to fish collected from the Tamar. These results indicate that a low to moderate induction of A. anguilla CYP1A had occurred (indicative of low to moderate exposure to PAHs and planar PCBs) in fish collected from the Thames, Tyne, Wear, Tees, Humber and Tamar estuaries. However, the highest level of EROD activity was observed in fish from the Weston Canal (Merseyside).     

Changes in zoobenthic community structure after pollution abatement from fish farms in the Archipelago Sea (N. Baltic Sea)

Long-term changes in sediment macrofauna communities at two sites affected by fish farming in the Archipelago Sea, south-west Finland have been investigated. Sampling stations in the S?rk?nsalmi Strait and Kaukolanlahti Bay, previously investigated 1982-1991, were revisited in 1994, 1995 and 1998 to detect signs of recovery following a decrease in organic load since 1990 and 1991, respectively. The results indicate a partial recovery in S?rk?nsalmi during post-pollution years, whereas no improvement has taken place in Kaukolanlahti. The improvement in S?rk?nsalmi is shown by a significant increase in the number of species and total abundance, and by the community structures becoming more similar over time. On the other hand, a significantly decreased number of species, abundance and biomass values over time as well as the occurrence of defaunated anoxic sediments, are clear signs of continued deterioration in Kaukolanlahti. Differences in the recovery potential of the two water areas are interpreted as consequences of topography and water exchange patterns causing differences in oxygen saturation.     

Porphyry and Skarn Cu-Mo-Pb-Zn-Ag-Au Metallogeny of the Gangdise Plutonic-Volcanic Arc, Tibet

PORPHYRY AND SKARN Cu-Mo-Pb-Zn-Ag-Au METALLOGENY OF THE GANGDISE PLUTONIC -VOLCANIC ARC, TIBETtheNational973Project“MetallogenicBackgroundandProspectiveEvaluationoftheGangdiseBelt”     

Measurement of a Peak in the Cosmic Microwave Background Power Spectrum from the North American Test Flight of Boomerang

We describe a measurement of the angular power spectrum of anisotropies in the cosmic microwave background (CMB) at scales of 0&fdg;3 to 5 degrees from the North American test flight of the Boomerang experiment. Boomerang is a balloon-borne telescope with a bolometric receiver designed to map CMB anisotropies on a long-duration balloon flight. During a 6 hr test flight of a prototype system in 1997, we mapped more than 200 deg(2) at high Galactic latitudes in two bands centered at 90 and 150 GHz with a resolution of 26&arcmin; and 16&farcm;5 FWHM, respectively. Analysis of the maps gives a power spectrum with a peak at angular scales of 1 degrees with an amplitude 70 μK(CMB).     

Extended Far-Infrared CO Emission in the OMC-1 Core of Orion

We report the discovery of quasi-periodic oscillations (QPOs) at roughly 187 and 150 Hz in the X-ray intensity of X-ray nova XTE J1859+226. The source was observed during a recent outburst with the Rossi X-Ray Timing Explorer. Besides these high-frequency QPOs, we have also detected QPOs (and sometimes their harmonics) at 6-7 Hz and significant broadband variability at low frequencies. These properties, as well as the observed hard X-ray spectrum, make XTE J1859+226 a black hole candidate (BHC). The detection of QPOs at two distinct frequencies greater, similar100 Hz in two observations separated by about 4 hr provide additional insights into the high-frequency QPO phenomenon in BHCs. The importance lies in the proposed interpretations, which invariably involve the effects of strong gravity near a black hole. We compare our results to those of other BHCs and discuss the impact of the observational data on the models in a global context.     

Far-infrared Detection of C3 in Sagittarius B2 and IRC +10216

We report on the detection of nine lines of the nu2 bending mode of triatomic carbon, C3, in the direction of Sagittarius B2. The R(4) and R(2) lines of C3 have been also detected in the carbon-rich star IRC +10216. The abundances of C3 in the direction of Sgr B2 and IRC +10216 are approximately 3x10-8 and approximately 10-6, respectively. In Sgr B2 we have also detected the 23-12 line of NH with an abundance of a few times 10-9. Polyatomic molecules will have a weak contribution from their pure rotational spectrum to the emission/absorption in the far-infrared. We suggest, however, that they could be, through their low-lying vibrational bending modes, the dominant carriers of emission/absorption in the spectrum of bright far-infrared sources.