Solid bitumens: an assessment of their characteristics, genesis, and role in geological processes

Familiar since antiquity, and subject in contemporary times to various characterization schemes, the exact nature of solid bitumen is not yet fully known. Bitumens have ‘random polymer-like’ molecular structures, are mobile as highly viscous fluids or were once fluids but have since turned into solids. Solid bitumens consist mainly of large moieties, of polyclyclic aromatic hydrocarbons, occasionally with finely admixed, fine-grained cryptocrystalline graphite. Solid bitumens are distinguished from kerogen, which is the syngenetic and generally finely dispersed particulate organic matter in sedimentary rock that virtually does not migrate following its deposition. Occurrences of solid bitumens are relevant to petroleum exploration as well as the search for, and evaluation of, a variety of metallic mineral deposits. Genesis of bitumen is in many cases linked to the thermal and hydrothermal history of organic matter in sedimentary rock. Apparently bitumen, or more specifically organic acids generated along with bitumen during diagenesis, may alter porosity of reservoir rocks or otherwise prepare the ground for ore deposition. Bitumen is also relatively sensitive to alteration processes, some of which, such as oxidative weathering, water leaching, biodegradation (contact) metamorphism and ionizing radiation may likewise affect its nature. Elemental composition of bitumen commonly reflects the nature of mineral deposits. Is is possible that in petroleum exploration, trace metal abundances of bitumen may eventually allow prediction of crude oil types and volumes anticipated from a given source rock? Beside transition elements, notably Ni and V, highly anomalous concentrations of U, Pt and Au occur in some solid bitumens. During the generation of petroleum from kerogen, the trend in δ¹³C is toward lighter values. The opposite seems to occur when liquid petroleum is subjected to thermal cracking (and /or related processes) yielding solid bitumen enriched in ¹³C, and isotopically light methane. In fact, except for deasphalting and possibly some irradiation processes, the result of thermal cracking, oxidation, water leaching, inspissation (drying) and bacterial degradation of crude oil is that lower molecular weight hydrocarbons are removed leaving bitumen residues enriched in aromatic hydrocarbons, heteroatomic compounds (NSO) and ¹³C. Such phenomena are relevant to bitumen paragenesis in petroleum reservoir rocks, to certain Phanerozoic occurrences of multiple generations of bitumens, and to bitumens in mineral deposits.     

Historical Changes in the Flood Hazard at Khartoum, Sudan: Lessons and Warnings for the Future

The 1988 floods at Khartoum were frequently described as "unprecedented". However, an examination of evidence for floods caused by the Nile and rain storms during the nineteenth and twentieth centuries leads to the conclusion that neither the Nile flood nor the rain storms nor their coincidence in one season were unprecedented and that similar situations will recur.We argue that most problems were created by complacency, lack of planning and mismanagement. We conclude with some simple suggestions for flood amelioration in the future and warn that complacency is the single most important phenomenon likely to recur to the detriment of Greater Khartoum in the future.     

Equilibria and stability of the restricted photogravitational problem of 2 + 2 bodies

The restricted problem of 2 + 2 bodies when one of the infinitesimal masses is further acted upon by the light pressure of the two primaries, is considered. The stationary solutions of this problem are found out. A short discussion is devoted to the stability of these solutions.     

Perspectives of the ROT 54/32/2.6 in astronomy

Perspectives for the Radio-Optical Telescope 54/32/2.6 are given for scientific research in radioastronomy. Its characteristics and potential scientific fields are summarized in the frame of the present French-Armenian collaboration. A 3-phase upgrade plan including a detailed technical evaluation of the antenna is presented.Published in Astrofizika, Vol. 38, No. 4, pp. 645–648, October–December, 1995.     

A study of the magnetic helicity during eight HELIOS-observed solar proton events

We have studied the influence of the magnetic helicity on solar particle propagation using the IMF data observed by the HELIOS spacecraft in the range 0.31–0.95 AU, during eight solar proton events. For this, we have derived power and helicity spectra of the turbulence of the magnetic field during the time of the events. These are used to compute the particle pitch-angle scattering coefficients according to the quasi-linear theory (QLT) treatment of particle propagation in turbulent magnetic fields. The results show that in all the cases the helicity effects are negligible and the particle's mean free paths deduced from the pitch-angle diffusion coefficients are the same regardless of whether or not helicity effects are included in the calculations. The computed mean free paths are quite different in each case.Deceased 10 April, 1995.     

Radar observations of the Geminid meteoroid stream

Continuous radio-wave monitoring of the Geminid activity in December 1992 and 1993 by using a forward scatter (FS) bistatic radar over the Bologna-Lecce baseline (700 km) in Italy, reveals peculiar structural aspects of the stream in terms of signal amplitude-rate and duration-rate dependence. The observational results of the Geminid display obtained in the two consecutive years with differentiated peak levels of transmitted power, exhibit different time distributions of underdense meteors against the signal received power. Both sets of the data relative to the peak activity in December 12–14, show reflection properties of Geminids which are atypical if compared with echoes from cometary-type showers, with really high echo counts at mid-upper levels of the peak received power. An assymmetric curve of activity of the Geminids complex is evidenced, with the peak flux of smaller particles occurring earlier than that of larger ones.     

An Early Investigation Of The Striated Tail Of Comet Hale-Bopp (C/1995 O1)

The Sekanina-Farrell particle fragmentation model for the striated tails of dust comets is successfully applied to two images of comet Hale-Bopp to study the motions of 12 striae in a time span of March 12–15, 1997. There is evidence for recurring outbursts with a periodicity of 11^h21^m, consistent with results based on analysis of dust jets. The ejecta in all the striae appear to have been released from one source on the nucleus between the end of January and the second half of February 1997, some 60 to 40 days before perihelion. The parent particles were subjected to a radiation pressure acceleration of β_p ≃ 0.55 and their fragmentation lifetimes in 11 of the 12 striae were practically constant and equal to 13–15 days, when normalized to 1 AU from the Sun. Brief analysis of Watanabe et al.'s measurements of striae on their images from March 5–9, 1997 shows even shorter fragmentation lifetimes for the parent particles, mostly about 7–11 days at1 AU. This revised version was published online in July 2006 with corrections to the Cover Date.     

Metamorphic evolution of exhumed middle to lower crustal rocks in the Mojave Extensional Belt, southern California, USA

The Waterman Metamorphic Complex of the central Mojave Desert was exposed as a consequence of early Miocene detachment-dominated extension. However, it has evidence consistent with a more extensive geological history that involves collision of a crustal fragment(s), tectonic thickening by overthrusting and two periods of extension. The metamorphic complex contains granitoid intrusives and felsic mylonitic gneisses as well as polymetamorphic rocks that include marble, calc-silicate, quartzite. mafic granulite, pyribolite, amphibolite, migmatite and biotite schist. The latter group of rocks was affected by an initial series of high-grade metamorphic events (M1 and M2) and a localized lower grade overprint (M3). The initial metamorphism (M1) can be separated into two stages along its high-grade P–T path: M1a, a granulite facies metamorphism at 800–850° C and 7.5–9 kbar and Mlb, an upper amphibolite facies overprint at 750–800° C and 10–12 kbar. M1a developed mineral assemblages and textures consistent with granulite facies conditions at a reduced activity of H₂O and is associated with intense ductile deformation (D1) and minor local partial melting. M1b overprinted the granulite assemblages with a series of hydrous phases under conditions of increasing pressure and H₂O activity and is accompanied by little or no deformation. M2 developed at lower pressures and temperatures (650–750° C, 4.5–5.5 kbar) and is distinguished by a second local overprint of hydrous phases that reflects an input of aqueous fluids probably associated with the intrusion of a series of granitic dykes and veins. Effects of M3 are confined to the Mitchel detachment zone, an anastomosing early Miocene detachment fault, and are characterized by local ductile/brittle deformation (D2) of the pre-existing high-grade rocks and granitoid intrusives and by the production of mylonites and mylonitic gneisses under greenschist facies conditions (300–350° C, 3–5 kbar). The initial overprint (M1a) represents metamorphism, devolatilization and minor partial melting of supracrustal rocks under granulite facies conditions as a consequence of tectonic and, possibly, magmatic thickening. The increasing pressure transition of M1a to M1b reflects a period of continued compressional tectonism, thrusting and influx of H₂O, in part, locally related to crystallization of partial melts. The near isothermal decompression between M1b and M2 probably represents a pre-112-Ma extensional episode that may have been the result of a decompressional readjustment of a thickened crust. Following the initial extensional event, the metamorphic complex remained at depths of 10–17 km for at least 90 Ma until it was uplifted following Miocene extension. M3 develops locally in response to this second extensional period resulting from the early Miocene detachment faulting.