Archean high-Mg monzodiorite–syenite,epidote skarn,and biotite–sericite gold lodes in the Granny Smith–Wallaby district,Australia: U–Pb and Re–Os chronometry of two intrusion-related hydrothermal systems

The Granny Smith (37 t Au production) and Wallaby deposits (38 t out of a 180 t Au resource) are located northeast of Kalgoorlie, in 2.7 Ga greenstones of the Eastern Goldfields Province, the youngest orogenic belt of the Yilgarn craton, Western Australia. At Granny Smith, a zoned monzodiorite–granodiorite stock, dated by a concordant titanite–zircon U–Pb age of 2,665 ± 3 Ma, cuts across east-dipping thrust faults. The stock is fractured but not displaced and sets a minimum age for large-scale (1 km) thrust faulting (D2), regional folding (D1), and dynamothermal metamorphism in the mining district. The local gold–pyrite mineralization, controlled by fractured fault zones, is younger than 2,665 ± 3 Ma. In augite–hornblende monzodiorite, alteration progressed from a hematite-stained alkali feldspar–quartz–calcite assemblage and quartz–molybdenite–pyrite veins to a late reduced sericite–dolomite–albite assemblage. Gold-related monazite and xenotime define a U–Pb age of 2,660 ± 5 Ma, and molybdenite from veins a Re–Os isochron age of 2,661 ± 6 Ma, indicating that mineralization took place shortly after the emplacement of the main stock, perhaps coincident with the intrusion of late alkali granite dikes. At Wallaby, a NE-trending swarm of porphyry dikes comprising augite monzonite, monzodiorite, and minor kersantite intrudes folded and thrust-faulted molasse. The conglomerate and the dikes are overprinted by barren (<0.01 g/t Au) anhydrite-bearing epidote–actinolite–calcite skarn, forming a 600-m-wide and >1,600-m-long replacement pipe, which is intruded by a younger ring dike of syenite porphyry pervasively altered to muscovite + calcite + pyrite. Skarn and syenite are cut by pink biotite–calcite veins, containing magnetite + pyrite and subeconomic gold–silver mineralization (Au/Ag = 0.2). The veins are associated with red biotite–sericite–calcite–albite alteration in adjacent monzonite dikes. Structural relations and the concordant titanite U–Pb age of the skarn constrain intrusion-related mineralization to 2,662 ± 3 Ma. The main-stage gold–pyrite ore (Au/Ag >10) forms hematite-stained sericite–dolomite–albite lodes in stacked D2 reverse faults, which offset skarn, syenite, and the biotite–calcite veins by up to 25 m. The molybdenite Re–Os age (2,661 ± 10 Ma) of the ore suggests a genetic link to intrusive activity but is in apparent conflict with a monazite–xenotime U–Pb age (2,651 ± 6 Ma), which differs from that of the skarn at the 95% confidence level. The time relationships at both gold deposits are inconsistent with orogenic models invoking a principal role for metamorphic fluids released during the main phase of compression in the fold belt. Instead, mineralization is related in space and time to late-orogenic, magnetite-series, high-Mg monzodiorite–syenite intrusions of mantle origin, characterized by Mg/(Mg + Fe_TOTAL) = 0.31–0.57, high Cr (34–96 ppm), Ni (22–63 ppm), Ba (1,056–2,321 ppm), Sr (1,268–2,457 ppm), Th (15–36 ppm), and rare earth elements (total REE: 343–523 ppm). At Wallaby, shared Ca–K–CO₂ metasomatism and Th-REE enrichment (in allanite) link Au–Ag mineralization in biotite–calcite veins to the formation of the giant epidote skarn, implicating a Th + REE-rich syenite pluton at depth as the source of the oxidized hydrothermal fluid. At Granny Smith, lead isotope data and the Rb–Th–U signature of early hematite-bearing wall-rock alteration point to fluid released by the source pluton of the differentiated alkali granite dikes.     

Detailed <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating of geologic events associated with the Mantos Blancos copper deposit,northern Chile

The ⁴⁰Ar/³⁹Ar geochronological method was applied to date magmatic and hydrothermal alteration events in the Mantos Blancos mining district in the Coastal Cordillera of northern Chile, allowing the distinction of two separate mineralization events. The Late Jurassic Mantos Blancos orebody, hosted in Jurassic volcanic rocks, is a magmatic-hydrothermal breccia-style Cu deposit. Two superimposed mineralization events have been recently proposed. The first event is accompanied by a phyllic hydrothermal alteration affecting a rhyolitic dome. The second mineralization event is related to the intrusion of bimodal stocks and sills inside the deposit. Because of the superposition of several magmatic and hydrothermal events, the obtained ⁴⁰Ar/³⁹Ar age data are complex; however, with a careful interpretation of the age spectra, it is possible to detect complex histories of successive emplacement, alteration, mineralization, and thermal resetting. The extrusion of Jurassic basic to intermediate volcanic rocks of the La Negra Formation is dated at 156.3 ± 1.4 Ma (2σ) using plagioclase from an andesitic lava flow. The first mineralization event and associated phyllic alteration affecting the rhyolitic dome occurred around 155–156 Ma. A younger bimodal intrusive event, supposed to be equivalent to the bimodal stock and sill system inside the deposit, is probably responsible for the second mineralization event dated at ca. 142 Ma. Other low-temperature alteration events have been dated on sericitized plagioclase at ca. 145–146, 125, and 101 Ma. This is the first time that two distinct mineralization events have been documented from radiometric data for a copper deposit in the metallogenic belt of the Coastal Cordillera of northern Chile. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Partial crustal melting beneath the Betic Cordillera (SE Spain): The case study of Mar Menor volcanic suite

The Neogene Volcanic Province (NVP) within the Betic Cordillera (SE Spain) consists of three main metapelitic enclave suites (from SW to NE: El Hoyazo, Mazarrón and Mar Menor). Since the NVP represents a singular place in the world where crustal enclaves were immediately quenched after melting, their microstructures provide a “photograph” of the conditions at depth just after the moment of the melting.

The thermobarometric information provided by the different microstructural assemblages has been integrated with the geophysical and geodynamical published data into a model of the petrologic evolution of the Mar Menor enclaves. They were equilibrated at 2–3 kbar, 850–900 °C, and followed a sequence of heating melt producing reactions. A local cooling event evidenced by minor melt crystallization preceded the eruption.

The lower crustal studies presented in this work contribute to the knowledge of: (i) the partial melting event beneath the Mar Menor volcanic suite through a petrologic detailed study of the enclaves; (ii) how the microstructures of fast cooled anatectic rocks play an important role in tracing the magma evolution in a chamber up to the eruption, and how they can be used as pseudothermobarometers; (iii) the past and current evolution of the Alborán Domain (Betic Cordillera) and Mediterranean Sea, and how the base of a metapelitic crust has melted within an active geodynamic setting.     

Sedimentary evolution of a Late Pleistocene temperate red algal reef (Coralligène) on Rhodes,Greece: correlation with global sea‐level fluctuations

Autochthonous red algal structures known as coralligène de plateau occur in the modern warm‐temperate Mediterranean Sea at water depths from 20 to 120 m, but fossil counterparts are not so well‐known. This study describes, from an uplifted coastal section at Plimiri on the island of Rhodes, a 450 m long by 10 m thick Late Pleistocene red algal reef (Coralligène Facies), interpreted as being a coralligène de plateau, and its associated deposits. The Coralligène Facies, constructed mainly by Lithophyllum and Titanoderma, sits unconformably upon the Plio‐Pleistocene Rhodes Formation and is overlain by a Maerl Facies (2 m), a Mixed Siliciclastic‐Carbonate Facies (0·2 m) and an Aeolian Sand Facies (2·5 m). The three calcareous facies, of Heterozoan character, are correlated with established members in the Lindos Acropolis Formation in the north of the island, while the aeolian facies is assigned to the new Plimiri Aeolianite Formation. The palaeoenvironmental and genetic‐stratigraphic interpretations of these mixed siliciclastic‐carbonate temperate water deposits involved consideration of certain characteristics associated with siliciclastic shelf and tropical carbonate shelf models, such as vertical grain‐size trends and the stratigraphic position of zooxanthellate coral growths. Integration of these results with electron spin resonance dates of bivalve shells indicates that the Coralligène Facies was deposited during Marine Isotope Stage 6 to 5e transgressive event (ca 135 to 120 ka), in water depths of 20 to 50 m, and the overlying Maerl Facies was deposited during regression from Marine Isotope Stage 5e to 5d (ca 120 to 110 ka), at water depths of 25 to 40 m. The capping Aeolian Sand Facies, involving dual terrestrial subunits, is interpreted as having formed during each of the glacial intervals Marine Isotope Stages 4 (71 to 59 ka) and 2 (24 to 12 ka), with soil formation during the subsequent interglacial periods of Marine Isotope Stages 3 and 1, respectively. Accumulation rates of about 0·7 mm year^?1 are estimated for the Coralligène Facies and minimum accumulation rates of 0·2 mm year^?1 are estimated for the Maerl Facies. The existence of older red algal reefs in the Plimiri region during at least Marine Isotope Stages 7 (245 to 186 ka) and 9 (339 to 303 ka) is inferred from the occurrence of reworked coralligène‐type lithoclasts in the basal part of the section and from the electron spin resonance ages of transported bivalve shells.     

Cenozoic Eucla Basin and associated palaeovalleys,southern Australia — Climatic and tectonic influences on landscape evolution,sedimentation and heavy mineral accumulation

The Eucla Basin including the vast Nullarbor Plain lies on the margins of the Yilgarn, Musgrave and Gawler cratons in southern Australia and owes its distinctive landscape to a unique set of interactions between eustatic, climatic and tectonic processes over the last ~ 50 Ma. Understanding of the history of the basin and the palaeovalleys that drained from the surrounding cratons are important because they contain major mineral deposits, and the sediments derived from them contain remobilised gold, uranium, and heavy minerals. In particular, a remarkably preserved palaeoshoreline sequence along the north-eastern margin of the Eucla Basin is highly prospective for heavy mineral placer deposits. The record of marine, marginal marine, estuarine, fluvial and lacustrine environments, as constrained mainly by an extensive borehole dataset, reflects major depositional events during the Palaeocene–Early Eocene, Middle–Late Eocene, Oligocene–Early Miocene, Middle Miocene–Early Pliocene and Pliocene–Quaternary. These events reflect the key role of eustatic sea-level variation which, during highstands, inundated the craton margins, flooding palaeovalleys to up to 400 km inboard of the present coastline. However, a systematic eastward migration of the depocentre across the Eucla Basin during the Neogene, together with apparent flow reversals in a number of palaeovalley systems draining the Gawler Craton, suggest that the Eucla Basin has also been subject to differential vertical movements, expressed as a west-side up, east-side down tilting of ~ 100–200 m. This differential movement forms part of a broader north-down–southwest-up dynamic topographic tilting of the Australian continent associated with relatively fast (6–7 cm/yr) northward plate motion since fast spreading commenced in the Southern Ocean at ~ 43 Ma. We suggest that the evolving dynamic topography field has played a key role in facilitating development of placer deposits, largely through multistage, eastward reworking of near-shore sequences during highstand transgressive cycles on a progressively tilting platform under the influence of persistent westerly weather systems.     

A Pliocene mega-tsunami deposit and associated features in the Ranquil Formation,southern Chile

An exceptionally large tsunami affected the coastline of southern Chile during the Pliocene. Its backflow eroded coarse beach and coastal dune sediments and redistributed them over the continental shelf and slope. Sandstone dykes and sills injected from the base of the resulting hyperconcentrated flow into underlying cohesive muds, assisted in plucking up large blocks of the latter and incorporating them into the flow. Locally, the rip-up intraclasts were fragmented further by smaller-scale injections to form a distinct breccia of angular to rounded mudstone clasts within a medium to coarse sandstone matrix. Sandstone sills in places mimic normal sedimentary beds, complete with structures resembling inverse gradation, planar laminae, as well as ripple and trough cross-lamination. These were probably formed by internal sediment flow and shear stress as the semi-liquefied sand was forcefully injected into cracks. In borehole cores, such sills can easily be misinterpreted as normal sedimentary beds, which can have important implications for hydrocarbon exploration.     

The Anarak, Jandaq and Posht-e-Badam metamorphic complexes in central Iran: New geological data, relationships and tectonic implications

The Anarak, Jandaq and Posht-e-Badam metamorphic complexes occupy the NW part of the Central-East Iranian Microcontinent and are juxtaposed with the Great Kavir block and Sanandaj-Sirjan zone. Our recent findings redefine the origin of these complexes, so far attributed to the Precambrian–Early Paleozoic orogenic episodes, and now directly related to the tectonic evolution of the Paleo-Tethys Ocean. This tectonic evolution was initiated by Late Ordovician–Early Devonian rifting events and terminated in the Triassic by the Eocimmerian collision event due to the docking of the Cimmerian blocks with the Asiatic Turan block.

The “Variscan accretionary complex” is a new name we proposed for the most widely distributed metamorphic rocks connected to the Anarak and Jandaq complexes. This accretionary complex exposed from SW of Jandaq to the Anarak and Kabudan areas is a thick and fine grain siliciclastic sequence accompanied by marginal-sea ophiolitic remnants, including gabbro-basalts with a supra-subduction-geochemical signature. New ⁴⁰Ar/³⁹Ar ages are obtained as 333–320 Ma for the metamorphism of this sequence under greenschist to amphibolite facies. Moreover, the limy intercalations in the volcano-sedimentary part of this complex in Godar-e-Siah yielded Upper Devonian–Tournaisian conodonts. The northeastern part of this complex in the Jandaq area was intruded by 215 ± 15 Ma arc to collisional granite and pegmatites dated by ID-TIMS and its metamorphic rocks are characterized by some ⁴⁰Ar/³⁹Ar radiometric ages of 163–156 Ma.

The “Variscan” accretionary complex was northwardly accreted to the Airekan granitic terrane dated at 549 ± 15 Ma. Later, from the Late Carboniferous to Triassic, huge amounts of oceanic material were accreted to its southern side and penetrated by several seamounts such as the Anarak and Kabudan. This new period of accretion is supported by the 280–230 Ma ⁴⁰Ar/³⁹Ar ages for the Anarak mild high-pressure metamorphic rocks and a 262 Ma U–Pb age for the trondhjemite–rhyolite association of that area. The Triassic Bayazeh flysch filled the foreland basin during the final closure of the Paleo-Tethys Ocean and was partly deposited and/or thrusted onto the Cimmerian Yazd block.

The Paleo-Tethys magmatic arc products have been well-preserved in the Late Devonian–Carboniferous Godar-e-Siah intra-arc deposits and the Triassic Nakhlak fore-arc succession. On the passive margin of the Cimmerian block, in the Yazd region, the nearly continuous Upper Paleozoic platform-type deposition was totally interrupted during the Middle to Late Triassic. Local erosion, down to Lower Paleozoic levels, may be related to flexural bulge erosion. The platform was finally unconformably covered by Liassic continental molassic deposits of the Shemshak.

One of the extensional periods related to Neo-Tethyan back-arc rifting in Late Cretaceous time finally separated parts of the Eocimmerian collisional domain from the Eurasian Turan domain. The opening and closing of this new ocean, characterized by the Nain and Sabzevar ophiolitic mélanges, finally transported the Anarak–Jandaq composite terrane to Central Iran, accompanied by large scale rotation of the Central-East Iranian Microcontinent (CEIM). Due to many similarities between the Posht-e-Badam metamorphic complex and the Anarak–Jandaq composite terrane, the former could be part of the latter, if it was transported further south during Tertiary time.     

Petrography and textural development of inorganic and biogenic lithotypes in a relict barite tufa deposit at Flybye Springs, NT, Canada

A relict mound of Holocene barite (BaSO₄) tufa underlies the Flybye Springs, a small, barium‐rich, cold sulphur spring system in the Northwest Territories of Canada. The tufa is composed of relatively pure barite with ≤0·34 wt% Ca²⁺ and ≤0·77 wt% Sr²⁺. The mound is made up of coated bubble, raft, undulatory sheet, stromatolitic, coated grain and detrital conglomerate barite tufa. Although previously unreported in barite, these lithotypes are akin to facies found in many carbonate spring deposits. Raft and ooid‐coated grain tufa was formed via ‘inorganic’ barite precipitation in spring water ponds and tributaries where rapid oxidation of sulphide to sulphate established barite supersaturation. Undulatory sheet tufa may have formed by the reaction of dissolved barium with sulphate derived from the oxidation of extracellular polysaccharide‐rich colloidal sulphur films floating in oxygenated, barite‐saturated spring water ponds. Coated bubble, oncoid‐coated grain and stromatolitic tufa with filamentous microfossils was formed in close association with sulphur‐tolerant microbes inhabiting dysoxic and oxygenated spring water tributaries and ponds. Adsorption of dissolved barium to microbial extracellular polysaccharide probably facilitated the development of these ‘biogenic’ lithotypes. Detrital conglomerate tufa was formed by barite cementation of microdetrital tufa, allochthonous lithoclasts and organic detritus, including caribou hair. Biogenic textures, organic artefacts and microfossils in the Flybye barite tufa have survived diagenetic aggradational recrystallization and precipitation of secondary cements, indicating the potential for palaeoecological information to be preserved in barite in the geological record. Similarities between the Flybye barite tufa and carbonate spring deposits demonstrate that analogous textures can develop in chemical sedimentary systems with distinct mineralogy, biology and physiochemistry.     

Late Quaternary contourites and glaciomarine sedimentation in the Fram Strait

Two sites in the eastern Fram Strait, the Vestnesa Ridge and the Yermak Plateau, have been surveyed and sampled providing a depositional record over the last glacial‐interglacial cycle. The Fram Strait is the only deep‐water connection from the Arctic Ocean to the North Atlantic and contains a marine sediment record of both high latitude thermohaline flow and ice sheet interaction. On the Vestnesa Ridge, the western Svalbard margin, a sediment drift was identified in 1226 m of water. Gravity and multicores from the crest of the drift recovered turbidites and contourites. ¹⁴C dating indicates an age range of 8287 to 26 900 years BP (Early Holocene to Late Weichselian). The Yermak Plateau is characterized by slope sediments in 961 m of water. Gravity and multicores recovered contourites and hemipelagites. ¹⁴C ages were between 8615 and 46 437 years BP (Early Holocene to mid‐Weichselian). Downcore dinoflagellate cyst analyses from both sites provide a record of changing surface water conditions since the mid‐Weichselian, suggesting variable sea ice extent, productivity and polynyas present even during the Last Glacial Maximum. Four layers of ice‐rafted debris were also identified and correlated within the cores. These events occurred ca at 9, 24 to 25, 26 to 27 and 43 ka, asynchronous with Heinrich layers in the wider north‐east Atlantic and here interpreted as reflecting instability in the Svalbard/Barents Ice sheet and the northward advection of warm Atlantic water during the Late Weichselian. The activity of the ancestral West Spitsbergen Current is interpreted using mean sortable silt records from the cores. On the Vestnesa Ridge drift the modern mass accumulation rate, calculated using excess ²¹⁰Pb, is 0·076 g cm^?2 year^?1. On the Yermak Plateau slope the modern mass accumulation rate is 0·053 g cm^?2 year^?1.     

Relationship between footwall composition,crustal contamination,and fluid–rock interaction in the Platreef,Bushveld Complex,South Africa

In the northern limb of the 2.06-Ga Bushveld Complex, the Platreef is a platinum group elements (PGE)-, Cu-, and Ni-mineralized zone of pyroxenite that developed at the intrusion margin. From north to south, the footwall rocks of the Platreef change from Archaean granite to dolomite, hornfels, and quartzite. Where the footwall is granite, the Sr-isotope system is more strongly perturbed than where the footwall is Sr-poor dolomite, in which samples show an approximate isochron relationship. The Nd-isotope system for samples of pyroxenite and hanging wall norite shows an approximate isochron relationship with an implied age of 2.17 ± 0.2 Ga and initial Nd-isotope ratio of 0.5095. Assuming an age of 2.06 Ga, the ɛNd values range from −6.2 to −9.6 (ave. −7.8, n = 17) and on average are slightly more negative than the Main Zone of the Bushveld. These data are consistent with local contamination of an already contaminated magma of Main Zone composition. The similarity in isotope composition between the Platreef pyroxenites and the hanging wall norites suggests a common origin. Where the country rock is dolomite, the Platreef has generally higher plagioclase and pyroxene δ ¹⁸O values, and this indicates assimilation of the immediate footwall. Throughout the Platreef, there is considerable petrographic evidence for sub-solidus interaction with fluids, and the Δ _{plagioclase–pyroxene} values range from −2 to +6, which indicates interaction at both high and low temperatures. Whole-rock and mineral δD values suggest that the Platreef interacted with both magmatic and meteoric water, and the lack of disturbance to the Sr-isotope system suggests that fluid–rock interaction took place soon after emplacement. Where the footwall is granite, less negative δD values suggest a greater involvement of meteoric water. Consistently higher values of Δ _{plagioclase–pyroxene} in the Platreef pyroxenites and hanging wall norites in contact with dolomite suggest prolonged interaction with CO₂-rich fluid derived from decarbonation of the footwall rocks. The overprint of post crystallization fluid–rock interaction is the probable cause of the previously documented lack of correlation between PGE and sulfide content on the small scale. The Platreef in contact with dolomite is the focus of the highest PGE grades, and this suggests that dolomite contamination played a role in PGE concentration and deposition, but the exact link remains obscure. It is a possibility that the CO₂ produced by decarbonation of assimilated dolomite enhanced the process of PGE scavenging by sulfide precipitation.