Collisional excitation of interstellar cyclopropenylidene

Theoretical rotational excitation rates were computed for C3H2 in collisions with He atoms at temperatures from 30 to 120 K. The intermolecular forces were obtained from accurate self-consistent field and perturbation theory calculations, and collision dynamics were treated within the infinite-order sudden approximation. The accuracy of the latter was examined by comparing with the more exact coupled states approximation.     

Velocity-height relation for antimatter meteors

A general velocity-height relation for both antimatter and ordinary matter meteor is derived. This relation can be expressed as % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaWaaSaaaeaacq% aHfpqDdaWgaaWcbaGaamOEaaqabaaakeaacqaHfpqDdaWgaaWcbaGa% eyOhIukabeaaaaGccqGH9aqpcaqGLbGaaeiEaiaabchacaqGGaWaam% WaaeaacqGHsisldaWcaaqaaiaadkeaaeaacaWGHbaaaiaabwgacaqG% 4bGaaeiCaiaabIcacaqGTaGaamyyaiaadQhacaGGPaaacaGLBbGaay% zxaaGaeyOeI0YaaSaaaeaacaWGdbaabaGaamOqaiabew8a1naaBaaa% leaacqGHEisPaeqaaaaakmaacmaabaGaaGymaiabgkHiTiaabwgaca% qG4bGaaeiCamaadmaabaGaeyOeI0YaaSaaaeaacaWGcbaabaGaamyy% aaaacaqGLbGaaeiEaiaabchacaqGOaGaaeylaiaadggacaWG6bGaai% ykaaGaay5waiaaw2faaaGaay5Eaiaaw2haaiaacYcaaaa!64FD!\[\frac{{\upsilon _z }}{{\upsilon _\infty }} = {\text{exp }}\left[ { - \frac{B}{a}{\text{exp( - }}az)} \right] - \frac{C}{{B\upsilon _\infty }}\left\{ {1 - {\text{exp}}\left[ { - \frac{B}{a}{\text{exp( - }}az)} \right]} \right\},\]where _z is the velocity of the meteoroid at height z, its velocity before entrance into the Earth's atmosphere, is the scale-height, and C parameter proportional to the atom-antiatom annihilation cross- section, which is experimentally unknown. The parameter B (B = DA₀/m) is the well known parameter for koinomatter (ordinary matter) meteors, D is the drag factor, ₀ is the air density at sea level, A is the cross sectional area of the meteoroid and m its mass.When the annihilation cross-section is zero — in the case of ordinary meteors — the parameter C is also zero and the above derived equation becomes % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaWaaSaaaeaacq% aHfpqDdaWgaaWcbaGaamOEaaqabaaakeaacqaHfpqDdaWgaaWcbaGa% eyOhIukabeaaaaGccqGH9aqpcaqGLbGaaeiEaiaabchacaqGGaWaam% WaaeaacqGHsisldaWcaaqaaiaadkeaaeaacaWGHbaaaiaabwgacaqG% 4bGaaeiCaiaabIcacaqGTaGaamyyaiaadQhacaGGPaaacaGLBbGaay% zxaaGaaiilaaaa!4CF5!\[\frac{{\upsilon _z }}{{\upsilon _\infty }} = {\text{exp }}\left[ { - \frac{B}{a}{\text{exp( - }}az)} \right],\]which is the well known velocity-height relation for koinomatter meteors.In the case in which the Universe contains antimatter in compact solid structure, the velocity-height relation can be found useful.Work performed mainly at the Nuclear Physics Laboratory of the National University of Athens, Greece.     

Integration error over very long time spans

The main limit to the time span of a numerical integration of the planetary orbits is no longer set by the availability of computer resources, but rather by the accumulation of the integration error. By the latter we mean the difference between the computed orbit and the dynamical behaviour of the real physical system, whatever the causes. The analysis of these causes requires an interdisciplinary effort: there are physical model and parameters errors, algorithm and discretisation errors, rounding off errors and reliability problems in the computer hardware and system software, as well as instabilities in the dynamical system. We list all the sources of integration error we are aware of and discuss their relevance in determining the present limit to the time span of a meaningful integration of the orbit of the planets. At present this limit is of the order of 10⁸ years for the outer planets. We discuss in more detail the truncation error of multistep algorithms (when applied to eccentric orbits), the coefficient error, the method of Encke and the associated coordinate change error, the procedures used to test the numerical integration software and their limitations. Many problems remain open, including the one of a realistic statistical model of the rounding off error; at present, the latter can only be described by a semiempirical model based upon the simpleN ² formula (N=number of steps, =machine accuracy), with an unknown numerical coefficient which is determined only a posteriori.     

The Soviet settlement system--current issues and future prospects

"A survey of current urban issues and trends in the Soviet Union sets the stage for an analysis of the problems of the urban system of the USSR and discussion of recent efforts at planning and policy development for a national settlement system. The General Scheme of Settlement, issued in 1975 and revised in 1982 to guide the development of such a national system, is examined as is the ensuing debate between two opposing schools of thought as to the best approach for restructuring the urban system."     

Multiple windbreaks: An aeolean ensemble

Near-neutral measurements of the turbulent wind field within and above a sequence of 15 parallel windbreaks on a flat pastoral site are presented. The windbreak fences each had a porosity of 60% and were equally-spaced at 6 times their height (h = 2 m). The following conclusions seem justified for wind directions within 10 ° of the normal to the array:

1. Above the windbreaks (2h), mean windspeeds first decreased and then increased asymptotically to a value in equilibrium with the new surface roughness. At 0.5h, windspeeds exhibited a slow increase down the entire array.
2. Reflecting differences in approach flows, the drag on the initial fence was almost twice that on barriers farther downstream. This reduction in momentum extraction per windbreak was associated with an elevation in the zero-plane displacement to a level equal to 0.8h.
3. At positions well-removed from the initial fences, mean windspeeds were reduced throughout the entire region below shelter height. In this region, the flow became increasingly dominated by downward moving air with velocities much greater than the local average. The zone of reduced turbulence was small, extending only 2h downstream of a barrier at a height of 0.25h. This corresponded with the region excluded from smoke trails released at the top of windbreaks.
4. An approximate TKE budget mid-way between windbreaks 7 and 8 suggests that shear and wake production peak near z = h and that production is balanced by dissipation and vertical transport components. Advective and inertial interaction terms are negligible at this midway position but are likely to be major sources of TKE closer to the windbreak. Local equilibrium is attained above z = 1.5h implying the existence of a constant-stress layer.

The measurements show the practical difficulty of simultaneously reducing both mean windspeeds and turbulence levels with repeated windbreaks at conventional spacings for horticultural applications.     

Surface drag and turbulence over an inhomogeneous land surface

Data collected over an inhomogeneous semi-rural area are presented. The data are compared with previous surface-layer data to determine how representative the fixed-point flux measurements are of area averages. Departures from the standard surface-layer results are found to be relatively small (~10–20%), which supports the concept of a blending height above which the flow ceases to respond to variations in the underlying surface and becomes horizontally homogeneous.Effective roughness lengths are derived for different wind directions and the relationship between the effective roughness length and upwind surface is examined in the light of recent ideas on averaging surface roughness lengths. It is found that by averaging drag coefficients, realistic values of the effective roughness length can be calculated which are not very sensitive to the precise choice of the component roughness lengths.     

Diffuse radiation,twilight, and photochemistry — I

A photochemical scheme which includes a detailed treatment of multiple scattering up to solar zenith angles of 96° (developed for use in a GCM) has been used to study partitioning within chemical families. Attention is drawn to the different zenith angle dependence of diffuse radiation for the two spectral regions <310 nm and >310 nm. The effect that this has on the so-called 40 km ozone problem is discussed. The importance of correctly including multiple scattering for polar ozone studies is emphasised.     

A numerical investigation of the destruction of peroxy radical by Cu ion catalysed reactions on atmospheric particles

To determine if Cu mediated reactions on atmospheric particles are important to HO₂ chemistry in the ambient atmosphere, Cu molalities were calculated from measured Cu aerosol particle concentrations, mass and number size distribution data from a site in central Sweden. A comparison of characteristic times indicates that at low relative humidities the reaction is limited by the mass transport of gas phase HO₂ to the particle surface and not by the chemical kinetics of the aqueous reaction. Comparison of half-lives for particle reactions and the gas phase destruction of HO₂ to form H₂O₂ indicate that heterogeneous reactions on aerosol particles may have important consequences on the chemistry of HO₂ and H₂O₂ in the troposphere.     

Annual variation of atmospheric carbonyl sulfide in the marine atmosphere in the Southern Indian Ocean

Measurements of the concentrations of carbonyl sulfide (COS) in the marine atmosphere were made over a period of two years in the southern Indian Ocean (Amsterdam Island, 37°50 S–77°31 E; March 1987–February 1988 and April 1989–February 1990). The mean atmospheric COS concentration for the whole period was 475±48 pptv (n=544). Atmospheric COS concentrations show no significant seasonal variation with a summer to winter ratio of 1.05. Taking into account the observed variability of the atmospheric COS concentration (10%), a value of 1.4 yr is estimated as a lower limit for the atmospheric COS lifetime. A comparison of the COS data at Amsterdam Island with those obtained in the Southern Hemisphere in the past 12 yr does not reveal any significant trend in the tropospheric background COS mixing ratio.