Quantitative analysis of calcite and Mg-calcite by X-ray diffraction: effect of grinding on peak height and peak area

Mineralogical analysis of calcite and Mg-calcite by X-ray diffraction requires that the samples be ground to a powder. Such grinding determines the particle size of the powder and the structural damage of the minerals. Both of these in turn affect the peak intensities recorded by the X-ray machine. Most carbonate sediments are inhomogeneous; they contain both calcite and Mg-calcite which are affected differently by grinding. Such differences cause quantitative analytical results to be inconsistent with the true mineralogical abundance. The two acceptable methods of analysis—(1) measurement of peak height from the base and (2) measurement of the area under the peak—were compared to determine if sample preparation affects the quantitative results. In samples with variable and relatively small amounts of calcite and Mg-calcite the measurement of peak height yields more reproducible results than does the measurement of peak areas. Different proportions of particle size of the mineralogical components in a sample powder, affect proportionally more the peak areas than the peak heights. Extensive grinding causes structural damage of the component minerals which affects much more the peak areas than the peak heights. Thus for quantitative analyses of calcite and Mg-calcite in inhomogeneous carbonate samples which require differing grinding times and have greatly variable amounts of calcite and Mg-calcite, the peak height measurement seems to be a better method than peak area measurement.     

Characterization of Quaternary faults by electric resistivity tomography in the Andean Precordillera of Western Argentina

El río San Juan, situado en la Provincia de San Juan (Argentina) cruza la Precordillera y otras unidades geológicas incluyendo la Depresión de Ullum y la Zona de La Laja, entre las latitudes 31°S y 32°S. El curso del río tiene un cierto caracter antecedente como puede deducirse por sus dos trazas perpendiculares unidas por otra casi paralela a las alineaciones estructurales principales. En la zona de la Precordillera, el valle del río San Juan muestra numerosos abanicos aluviales, situados en las zonas de confluencia entre el río principal y sus tributarios. Las superficies de los abanicos aluviales cuaternarios estan cortadas por una serie de escalones que consideramos como terrazas aluviales generadas por episodios repetitivos de agradación y degradación. El sector estudiado incluye una zona con una importante actividad sísmica reciente(La Laja), otra sin una importante actividad sísmica reciente (Precordillera), y una zona subsidente (Ullum) donde se formó un gran lago natural hace unos 6500 años. El antiguo río San Juan fue capturado por el valle de la Quebrada de Ullum mediante una incisión del orden de 25 m, que implicó una nueva adecuación del gradiente del río mediante los efectos de la erosión remontante. El gradiente del río San Juan muestra algunas irregularidades que, aunque no se presenten relacionadas directamente con las estructuras principales, estan relacionadas con la propia dinámica fluvial que acentúa la diferenciación litológica. La anchura del valle del río principal, la geometria y el gradiente de cada tributario, junto a las litologias del basamento y a las dimensiones de cada area fuente local, son los factores principales que controlan los procesos de la generación de las terrazas aluviales. En la zona de La Laja, donde la terraza mas alta soporta un nivel de travertino, la datación de los depósitos travertínicos proporciona datos como para suponer una tasa de incisión del orden de 0,9–1 mm/año, asociada a la actuación periódica de la falla de La Laja.

Integrated petrographic,mineralogical, and geochemical study of the upper Kaimur Group of rocks,Son Valley,India: Implications for provenance,source area weathering and tectonic setting

The upper Kaimur Group (UKG) of the Vindhyan Supergroup in central India, primarily consists of three rock types-Dhandraul sandstone, Scarp sandstone and Bijaigarh shale. The present study aims to reconstruct the parent rock assemblages, their tectonic provenance, mineralogy, weathering intensity, hydraulic sorting and depositional tectonic setting. Samples from the UKG rocks representing the Dhandraul sandstone, Scarp sandstone and Bijaigarh shale were studied using a combination of petrographic, mineralogical, and geochemical techniques. Texturally, medium to coarse grained UKG sandstones are mature and moderate to well sorted. Deficiency of feldspars in these sandstones indicates that the rocks are extensively recycled from distant sources. Their average modal composition for Scarp (avg. Qt₉₉ F₀.₂L_0.8) and Dhandraul (avg. Qt₉₉ F_0.1L_0.8) sandstones, classifies them as quartz arenite to sub-litharenite types, which is consistent with geochemical study. Major element concentrations revealed that sandstones have high SiO₂, K₂O < Na₂O, and low Fe₂O₃, which are supported by the modal data. On the other hand, sandstone samples are enriched in most trace elements such as Ce, Sr, V, Sc and Zr and depleted in U and Th. The CIA values (43.17–76.48) of the UKG rocks indicate low to moderate weathering, either of the original source or during transport before deposition, which may have related to low-relief and humid climatic conditions in the source area. Further, petrographic and geochemical interpretations indicate that they are derived from craton interior to quartzose recycled sedimentary rocks and deposited in a passive continental margin. Therefore, granitic and low grade metamorphic rocks of Mahakoshal Group and Chotanagpur granite-gneiss, situated on the southern and south-eastern side of the Vindhyan basin are suggested as possible provenance for the UKG rocks.     

Crustal structure beneath Spain from deep seismic sounding experiments

Major tectonic units of Spain have been investigated by deep seismic sounding experiments since 1974 to determine crustal structures and to delineate their differences. These areas are the central part of the Hercynian Meseta, and the Alpine chains: the Betic Cordillera in the south, including the Balearic promontory and the Alboran Sea, and the Pyrenees in the north.The main features of the crust and the upper mantle along a NNE-SSW cross-section from the Pyrenees to the Alboran Sea are described.The crust under the Meseta is typical of Hercynian areas found elsewhere in Europe, with an average thickness of 31 km, whereas the two Alpine regions are characterized by very large lateral inhomogeneities, such as rapid thickening of the crust to 50 and 40 km under the Pyrenees and the Betics, respectively. The deep-reaching E-W-trending North Pyrenean fault has a throw of 10–15 km at the base of the crust. A P_n velocity of 8.1 km s^?1 is found under the entire Iberian Peninsula.In the Alboran Sea, strongly varying thicknesses of sediments, shallow variable depths to the Moho (～ 13 km under the Alboran ridge), and strong variations of P_n velocity between 7.5 and 8.2 km s^?1 have been found.     

New seismic data in the Mozambique Channel

This paper presents seismic reflection and refraction data from the Mozambique Channel, collected between 1971 and 1973. A deep sedimentary basin (up to 5 km of sediments) opens southwards to the Mozambique Basin, and is bounded to the east by the Davie Ridge and beyond by the marginal plateau of Malagasy. A continuous reflector (C), possibly of Cretaceous age, is identified between layers having seismic interval velocities of 2.4–2.8 km/s and 3.1–3.4 km/s. The deepest sediments have velocities of 4.5–4.9 km/s and overlie a layer with velocity 5.5 km/s, which may be volcanic in the north-east of the Channel.The crust occupying most of the Channel is probably pre-Cretaceous in age, and may be largely continental in nature. This is supported by subdued magnetic anomalies and the possibility of a continuous Karroo sedimentary section across the northern Channel. The oceanic crust of the Mozambique Basin may extend as far north as 24°S, into the western Channel only. The problem of the origin of the Mozambique Channel remains unresolved, although a long sedimentary history indicates that Malagasy may have separated from Mainland Africa prior to Karroo times. The Davie Ridge may possibly represent a relict strike-slip fault, which permitted movement along a north-south line.     

The influence of subsurface moisture on rill system evolution

Rill development studies have focused almost exclusively on surface erosion processes and critical threshold hydraulic conditions. Characteristic rill features, such as arcuate headcuts and knickpoints, are morphologically similar to the ‘theatre-headed’ valleys which have been associated with ‘sapping’ processes at various scales. This paper reports on laboratory experiments designed to identify linkages between surface flow hydraulics, subsurface moisture conditions and rill development. Experiments were carried out in a 16·57 m² flume under simulated rainfall with soil samples up to 0·15 m depth in which moisture conditions were monitored by miniature time-domain reflectometer probes. Tests showed complex responses in which some rill incision reflected surface flow conditions, but major rill system development with markedly enhanced sediment yield was closely associated with high soil moisture contents. It was not possible to measure seepage forces directly, but calculation and observation indicate that these were less important than reduction in soil strength with saturation, which resulted in increased effective runoff erosivity. This caused concentrated undercutting along the water table at rill walls, while slightly stronger surface layers above the water table formed microscarps. These retreated along the water table into interrill surfaces, producing residual pediment transport slopes. The microscarps eventually disappeared when the water table reached the surface, eliminating differential soil strength. The experiments showed complex relationships between surface and subsurface erosional processes in evolving rill systems, strongly influenced by soil moisture dynamics. The very small topographic and hydraulic head amplitudes indicate that seepage forces and ‘sapping’ were minimal. The dominant effect of soil moisture was reduction of soil strength with saturation, and increased runoff entrainment. Experimental conditions were not unusual, either for agricultural fields or natural hillslopes, and the intricate interrelationship of surface and subsurface erosion processes observed is probably not uncommon. Attempts to link specific morphologic features at rill scale to dominance of surface or subsurface processes alone are therefore unlikely to be successful or reliable. © 1998 John Wiley & Sons, Ltd.     

Orion: A 1–5 Micron Focal Plane for the 21st Century

The Orion program is a project to develop a 2K × 2K infrared focal plane using InSb p-on-n diodes for detectors. It is the natural follow-up to the successful Aladdin 1K × 1K program started in the early 90's. The work is being done at the Raytheon Infrared Operations Division (RIO, previously known as the Santa Barbara Research Center) by many of the same people who created the Aladdin focal plane. The design is very similar to the successful Aladdin design with the addition of reference pixels, whole array readout (no quadrants), two-adjacent-side buttability, and a packaging design that includes going directly to the ultimate focal plane size of 4K × 4K. So far we have successfully made a limited number of hybrid modules with InSb detectors. In this paper we will describe the design features and test data taken from some of these devices. This revised version was published online in July 2006 with corrections to the Cover Date.     

Global high resolution versus Limited Area Model climate change projections over Europe: quantifying confidence level from PRUDENCE results

Four high resolution atmospheric general circulation models (GCMs) have been integrated with the standard forcings of the PRUDENCE experiment: IPCC-SRES A2 radiative forcing and Hadley Centre sea surface temperature and sea-ice extent. The response over Europe, calculated as the difference between the 2071–2100 and the 1961–1990 means is compared with the same diagnostic obtained with nine Regional Climate Models (RCM) all driven by the Hadley Centre atmospheric GCM. The seasonal mean response for 2m temperature and precipitation is investigated. For temperature, GCMs and RCMs behave similarly, except that GCMs exhibit a larger spread. However, during summer, the spread of the RCMs—in particular in terms of precipitation—is larger than that of the GCMs. This indicates that the European summer climate is strongly controlled by parameterized physics and/or high-resolution processes. The temperature response is larger than the systematic error. The situation is different for precipitation. The model bias is twice as large as the climate response. The confidence in PRUDENCE results comes from the fact that the models have a similar response to the IPCC-SRES A2 forcing, whereas their systematic errors are more spread. In addition, GCM precipitation response is slightly but significantly different from that of the RCMs.     

安徽巢湖地区下三叠统牙形石生物地层分带及其全球对比

安徽巢湖地区早三叠世处于下扬子碳酸盐岩缓坡较深水区域,地层序列完整、清晰,各类化石是区域乃至全球最为丰富、序列最为完整的,是研究国际早三叠世年代地层最经典地区之一．对安徽巢湖平顶山西坡剖面、平顶山北坡剖面、马家山南剖面系统采样和精细的牙形石生物地层研究结果表明,下三叠统至少可以划分为8个牙形石带,建立了在华南具有代表性的下三叠统牙形石生物地层序列,自下而上为（1）Hindeodus typicalis带;（2）Neogondolella krystyni-Neogondolella planata带;（3）Neospathodus kummeli带;（4）Neospathodus dieneri带;（5）Neospathodus iaageni带;（6）Neospathodus pingdingshanensis带;（7）Neospathodus homeri带;（8）Neospathodus anhuinensis带．并与世界其他地区同期地层进行精确对比,为建立下三叠统印度阶与奥伦尼克阶界线的全球层型（GSSP）提供可靠依据．     

Spatially explicit measures of production of young alewives in Lake Michigan: Linkage between essential fish habitat and recruitment

The identification and protection of essential habitats for early life stages of fishes are necessary to sustain fish stocks. Essential fish habitat for early life stages may be defined as areas where fish densities, growth, survival, or production rates are relatively high. To identify critical habitats for young-of-year (YOY) alewives (Alosa pseud oharengus) in Lake Michigan, we integrated bioenergetics models with GIS (Geographic Information Systems) to generate spatially explicit estimates of potential population production (an index of habitat quality). These estimates were based upon YOY alewife bioenergetic growth rate potential and their salmonine predators’ consumptive demand. We compared estimates of potential population production to YOY alewife yield (an index of habitat importance). Our analysis suggested that during 1994–1995, YOY alewife habitat quality and yield varied widely throughout Lake Michigan. Spatial patterns of alewife yield were not significantly correlated to habitat quality. Various mechanisms (e.g., predator migrations, lake circulation patterns, alternative strategies) may preclude YOY alewives from concentrating in areas of high habitat quality in Lake Michigan.