Age refinement of the Messinian salinity crisis onset in the Mediterranean

We propose a revised age calibration of the Messinian salinity crisis onset in the Mediterranean at 5.971 Ma based on the recognition of an extra gypsum cycle in the transitional interval of the Perales section (Sorbas basin, Spain) and the revision of the magnetostratigraphy of the Monticino section (Vena del Gesso basin, Italy). This age re‐calibration allows to state more accurately that: (i) the interval encompassing the MSC‐onset is continuous, thus ruling out any erosional feature or stratigraphic hiatus related to a major sea‐level fall affecting the Mediterranean; (ii) the first gypsum was deposited during the summer insolation peak at 5.969 Ma associated with an eccentricity minimum and roughly coincident with glacial stage TG32; (iii) the MSC‐onset was preconditioned by the tectonically‐driven reduction of the hydrological exchanges with the Atlantic Ocean and finally triggered by glacial conditions in the northern hemisphere and by arid conditions in northern Africa.     

Nitrate transport in the unsaturated zone: a case study of the riverbank filtration system Karany,Czech Republic

Nitrate transport in the unsaturated zone of a riverbank filtration (RBF) system in Karany, Czech Republic, was studied. Previous study of the system estimated RBF recharge as 60% riverbank filtrate and 40% local groundwater contaminated by nitrates. Nitrate concentrations observed in RBF recently cannot be explained by simple groundwater contamination and a new conception of groundwater recharge is suggested. A two‐component model based on water ¹⁸O data modelled recharge of local groundwater. One component of groundwater recharge is rainfall and irrigation water moving through the unsaturated zone of the Quaternary sediments in piston flow. The second component is groundwater from the Cretaceous deposits with a free water table. Both the components of groundwater recharge have different nitrate concentrations, and resulting contamination of groundwater depends on the participation of water from Quaternary and Cretaceous deposits. Nitrates' origins and their mixing in the subsurface were traced by ¹⁵N data. Nitrate transport from the unsaturated zone is important and time variable source of groundwater contamination. Copyright © 2011 John Wiley & Sons, Ltd.     

Relationship between soil CO<Subscript>2</Subscript> flux and volcanic tremor at Mt. Etna: Implications for magma dynamics

Large variations of the CO₂ flux through the soil were observed between November 2002 and January 2006 at Mt. Etna volcano. In many cases, the CO₂ flux was strongly influenced by changes in air temperature and atmospheric pressure. A new filtering method was then developed to remove the atmospheric influences on soil CO₂ flux and, at the same time, to highlight the variations strictly related to volcanic activity. Successively, the CO₂ corrected data were quantitatively compared with the spectral amplitude of the volcanic tremor by cross correlation function, cross-wavelet spectrum and wavelet coherence. These analyses suggested that the soil CO₂ flux variations preceded those of volcanic tremor by about 50 days. Given that volcanic tremor is linked to the shallow (a few kilometer) magma dynamics and soil CO₂ flux related to the deeper (~12 km b.s.l.) magma dynamics, the “delayed similarity” between the CO₂ flux and the volcanic tremor amplitude was used to assess the average speed in the magma uprising into the crust, as about 170–260 m per day. Finally, the large amount of CO₂ released before the onset of the 2004–2005 eruption indicated a deep ingression of new magma, which might have triggered such an eruption.     

Large-eddy Simulation of the Dispersion of Solid Particles in a Turbulent Boundary Layer

A large-eddy simulation (LES) with the dynamic Smagorinsky-Germano subgrid-scale (SGS) model is used to study the dispersion of solid particles in a turbulent boundary layer. Solid particles are tracked in a Lagrangian way. The instantaneous velocity of the surrounding fluid is considered to have a large-scale part (directly computed by the LES) and a small-scale part. The SGS velocity of the surrounding fluid is given by a three-dimensional Langevin model written in terms of SGS statistics at a mesh level. An appropriate Lagrangian correlation time scale is considered in order to include the influences of gravity and inertia of the solid particle. Inter-particle collisions and the influence of particles on the mean flow are also taken into account. The results of the LES are compared with the wind-tunnel experiments of Nalpanis et al. (1993 J Fluid Mech 251: 661–685) and of Tanière et al. (1997 Exp in Fluids 23:463–471) on sand particles in saltation and in modified saltation, respectively.     

On the role of vertical resolution in the analysis of shallow convective fields

Summary The present paper is an attempt to demonstrate the fact that misleading information about the thermodynamic structure of shallow cumulus fields is obtained when standard isobaric level (SIL) data input is used. The 1-D cumulus model serves as the main tool of examination and the reference input data are those of significant levels (SL) in soundings. The computed cloud tops (SIL) exceeded (SL) tops in nearly 80% of the cases and the excesses are more than 1 kilometre in 25% of the cases. Some discrepancies were also found in potential stability analysis. The local changes in equivalent potential temperature may be seriously affected and even falsified. The important role of high resolution in studies of mesoscale phenomena was again accentuated.

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mam mum ¶rt;aam, m u am u¶rt; ¶rt;a unam ¶rt;a ma¶rt;am uauu (SIL), m num uauu m¶rt;uau mm mu n. ¶rt;m, una nu u¶rt;auu, m ¶rt;a ¶rt; aa, a am n ¶rt; au unm ¶rt;a au ¶rt;aa. auma u a ¶rt; SIL n¶rt;m n au 80% a, a 25% a ¶rt;a a 1 . au ma ma nu aau nmua mumu. aQj uu uam nmua mnam m m aum ua. n¶rt;uam aa aua nmu nu uuu u a.

     

Development versus conservation: evaluation of landscape structure changes in Dem?novská Valley,Slovakia

This paper presents the changes of landscape structure in the Dem?novská Valley which ranks among the most valuable protected areas of Slovakia. The area was selected on the basis of changes associated with the rapidly growing tourism industry and the rise of an important destination in the center of Low Tatras National Park, Slovakia. To document any changes, we visually interpreted data from aerial and satellite images in three periods(1949, 2007 and 2013) and for predicting future changes we used land use planning documentation. Interpreted data were analyzed using overlay analysis and landscape metrics. Results showed extensive changes in the landscape structure mainly connected with the development of tourism infrastructure. We also identified long-term changes whose causes stem from the transformation of society and forest management in the past. The dynamics and extent of these changes may increase in the future. We propose to stop future development of ski slopes and expansion of related infrastructure, to focus on sustainability and environmentally friendly operation of the existing ski resort and to invest a substantial portion of profits to support projects aimed to preserve surrounding lands and wildlife.     

Nitrogen Mass Fraction and Stable Isotope Ratios for Fourteen Geological Reference Materials: Evaluating the Applicability of Elemental Analyser Versus Sealed Tube Combustion Methods

Thirteen commercially available silicate reference materials (RM) and one in‐house reference material, eleven of which have no previously published values, were analysed for nitrogen mass fraction and isotopic ratios with an Elemental Analyser (EA), and a Sealed Tube Combustion line, coupled to a continuous flow isotope ratio mass spectrometer (IRMS). These materials ranged from < 10 μg g^?1 to 1% m/m nitrogen mass fractions and δ¹⁵N of ?0.5 to +19.8‰. Existing nitrogen RM BHVO‐2, MS#5 and SGR‐1b were used to assess the accuracy of the data from the sealed tube combustion line, which was found to be in good agreement with existing published values. In contrast, the EA‐IRMS failed to fully liberate nitrogen from all silicate rocks and minerals (achieving a mean of 44 ± 10% nitrogen yield) resulting in kinetic fractionation of isotope values by ?1.4‰ on average. Therefore, sealed tube combustion is better suited for analyses of silicate‐bound nitrogen. The EA worked reliably for organic samples, but care should be taken when using the EA for silicate nitrogen research. Moving forward, it is recommended that BHVO‐2, Biotite‐Fe, FK‐N and UB‐N be used as quality control materials as they appear to be most reproducible in terms of nitrogen mass fraction (relative error < 10%, 1s), and isotopic composition (< 0.6‰, 1s).     

The maximum temperatures and heat waves in Serbia during the summer of 2007

An extraordinary heat wave occurred in Serbia from July 14 to July 24 in 2007. Record values of the maximum temperatures were observed over almost the whole territory of Serbia and in Smederevska Palanka, a temperature of 44.9°C was registered, which was the absolute maximum value ever recorded. The highest increase over the previous absolute maximum temperature, dating back to 1888, of 3.1°C was registered in Belgrade. The Warm Spell Duration Indicator, from which the duration and severity of the heat waves are estimated, was applied to the series of the daily maximum temperatures in Smederevska Palanka. An analysis of the daily maximum temperatures and heat waves during the summer of 2007 revealed significant changes in the trends of anomalies and extreme (90%) quantiles. In addition, the main characteristics of the heat wave and the circulation conditions which caused the heat wave in Serbia during the summer 2007 were analyzed.     

Effect of tidal fluctuations on transient dispersion of simulated contaminant concentrations in coastal aquifers

Variable-density groundwater models require extensive computational resources, particularly for simulations representing short-term hydrologic variability such as tidal fluctuations. Saltwater-intrusion models usually neglect tidal fluctuations and this may introduce errors in simulated concentrations. The effects of tides on simulated concentrations in a coastal aquifer were assessed. Three analyses are reported: in the first, simulations with and without tides were compared for three different dispersivity values. Tides do not significantly affect the transfer of a hypothetical contaminant into the ocean; however, the concentration difference between tidal and non-tidal simulations could be as much as 15%. In the second analysis, the dispersivity value for the model without tides was increased in a zone near the ocean boundary. By slightly increasing dispersivity in this zone, the maximum concentration difference between the simulations with and without tides was reduced to as low as 7%. In the last analysis, an apparent dispersivity value was calculated for each model cell using the simulated velocity variations from the model with tides. Use of apparent dispersivity values in models with a constant ocean boundary seems to provide a reasonable approach for approximating tidal effects in simulations where explicit representation of tidal fluctuations is not feasible.     

Global energy budget changes to high latitude North Atlantic cooling and the tropical ITCZ response

The intertropical convergence zone (ITCZ) in atmospheric general circulation models (coupled to slab ocean) shift southwards in response to northern extratropical cooling. Previous studies have demonstrated the utility of diagnosing the atmospheric energy fluxes in interpreting this teleconnection. This study investigates the nature of global energy flux changes in response to North Atlantic high latitude cooling applied to the Community Atmosphere Model version 3 coupled to a slab ocean, focusing on key local and remote feedbacks that collectively act to alter the energy budget and atmospheric energy transport. We also investigate the relative roles of tropical sea surface temperature (SST) and energy flux changes in the ITCZ response to North Atlantic cooling. Using a radiative kernel technique, we quantify the effects of key feedbacks—temperature, cloud and water vapor, to the top-of-the-atmosphere radiative flux changes. The results show only partial local energy flux compensation to the initial perturbation in the high latitudes, originating from the negative temperature feedback and opposed by positive shortwave albedo and longwave water vapor feedbacks. Thus, an increase in the atmospheric energy transport to the Northern extratropics is required to close the energy budget. The additional energy flux providing this increase comes from top-of-the-atmosphere radiative flux increase over the southern tropics, primarily from cloud, temperature and longwave water vapor feedbacks, and largely as a consequence of increased deep convection. It has been previously argued that the role of tropical SST changes was secondary to the role played by the atmospheric energy flux requirements in controlling the ITCZ shifts, proposing that the SST response is a result of the surface energy budget and not a driver of the precipitation response. Using a set of idealized simulations with the fixed tropical SSTs, we demonstrate that the ITCZ shifts are not possible without the tropical SST changes and suggest that the tropical SSTs are a more suitable driver of tropical precipitation shifts compared to the atmospheric energy fluxes. In our simulations, the ITCZ shifts are influenced mainly by the local (tropical) SST forcing, apparently independent of the actual high latitude energy demand.