High precision triple oxygen isotope composition of small size urban micrometeorites indicating constant influx composition in the early geologic past

In this study, we present a method for high precision Δ′¹⁷O (Δ′¹⁷O_RL = ln(δ¹⁷O + 1) – λ_RL ln(δ¹⁸O + 1)) analysis of small mass silicate and oxide materials. The analyses were conducted by laser fluorination in combination with gas chromatography and continuous flow isotope ratio monitoring gas spectrometry. We could analyze the oxygen isotope composition of samples down to 1 μg, which corresponded to about 13 nmol O₂. The analytical error (we report the 1σ external reproducibility of a single analysis) in δ¹⁸O increases with decreasing sample sizes from ~0.2‰ for ~20 μg samples to ~0.9‰ for 1 μg samples. For Δ′¹⁷O, we achieved an external reproducibility of 0.04‰ for a sample mass range between 1 and 27 μg. The uncertainty in Δ′¹⁷O is smaller than the uncertainty in δ¹⁸O due to the correlated errors in δ¹⁷O and δ¹⁸O. We applied the method to urban micrometeorites, that is, small meteorites (<2 mm) that were sampled from a rooftop in Berlin, Germany. A total of 10 melted micrometeorites (S-type cosmic spherules, masses between 11 and 22 μg) were analyzed. The oxygen isotope compositions are comparable to that of modern Antarctic collections, indicating that the urban micrometeorites sample the same population. No indication for terrestrial weathering had been identified in the studied set of urban micrometeorites making them suitable materials for the study of micrometeorite origins.     

Influence of atmospheric pressure variations on measurements made with Sharpe and Worden gravimeters

Summary The paper deals with the influence of the atmospheric pressure variations on Sharpe gravimeters CG 2 No. 226 and 280 and on the Worden gravimeter No. 978, equipped with a thermostat.Dedicated to RNDr. Jan Pícha, CSc., on his 60th Birthday     

Adriatic seiche decay and energy loss to the Mediterranean

A salient feature of sea level records from the Adriatic Sea is the frequent occurrence of energetic seiches of period about 21 h. Once excited by a sudden wind event, such seiches often persist for days. They lose energy either to friction within the Adriatic, or by radiation through Otranto Strait into the Mediterranean.The free decay time of the dominant (lowest mode) seiche was determined from envelopes of handpassed sea level residuals from three locations (Bakar, Split and Dubrovnik) along the Croatian coast during twelve seiche episodes between 1963 and 1986 by taking into consideration only time intervals when the envelopes decreased exponentially in time, when the modelled effects of along-basin winds were smaller than the error of estimation of decay time from the envelopes and when across-basin winds were small. The free decay time thus obtained was 3.2±0.5 d. This value is consonant with the observed width of the spectral peak.The decay caused by both bottom friction and radiation was included in a one dimensional variable cross section shallow water model of the Adriatic. Bottom friction is parameterized by the coefficient k appearing in the linearized bottom stress term _ρ0u (where u is the along-basin velocity and ρ₀ the fluid density). The coefficient k is constrained by values obtained from linearization of the quadratic bottom stress law using estimates of near bottom currents associated with the seiche, with wind driven currents, with tides and with wind waves. Radiation is parameterized by the coefficient f appearing in the open strait boundary condition ζ =auh/c (where ζ is sea level, h is depth and c is phase speed). This parameterization of radiation provides results comparable to allowing the Adriatic to radiate into an unbounded half plane ocean. Repeated runs of the model delineate the dependence of model free seiche decay time on k and a, and these plus the estimates of k allow estimation of a.The principle conclusions of this work are as follows.

1. (1) Exponential decay of seiche amplitude with time does not necessarily guarantee that the observed decay is free of wind influence.

2. (2) Winds blowing across the Adriatic may be of comparable importance to winds blowing along the Adriatic in influencing apparent decay of seiches; across-basin winds are probably coupled to the longitudinal seiche on account of the strong along-basin variability of across-basin winds forced by Croatian coastal orography.

3. (3) The free decay time of the 21.2 h Adriatic seiche is 3.2±0.5 d.

4. (4) A one dimensional shallow water model of the seiche damped by bottom stress represented by Godin's (1988) approximation to the quadratic bottom friction law ρ₀C_Du|u| using the commonly accepted drag coefficient C_D = 0.0015 and quantitative estimates of bottom currents associated with wind driven currents, tides and wind waves, as well as with the seiche itself with no radiation gives a damping time of 9.46 d; radiation sufficient to give the observed damping time must then account for 66% of the energy loss per period. But independent estimates of bottom friction for Adriatic wind driven currents and inertial oscillations, as well as comparisons between quadratic law bottom stress and directly measured bottom stress, all suggest that the quadratic law with C_D=0.0015 substantially underestimates the bottom stress. Based on these studies, a more appropriate value of the drag coefficient is at least C_D=0. In this case, bottom friction with no radiation leads to a damping time of 4.73 d, radiation sufficient to give the observed damping time then accounts for 32% of the energy loss per period.

     

The onset of the Messinian salinity crisis in the deep Eastern Mediterranean basin

Astronomical tuning of the Messinian pre‐salt succession in the Levant Basin allows for the first time the reconstruction of a detailed chronology of the Messinian salinity crisis (MSC) events in deep setting and their correlation with marginal records that supports the CIESM ( 2008 ) 3‐stage model. Our main conclusions are (1) MSC events were synchronous across marginal and deep basins, (2) MSC onset in deep basins occurred at 5.97 Ma, (3) only foraminifera‐barren, evaporite‐free shales accumulated in deep settings between 5.97 and 5.60 Ma, (4) deep evaporites (anhydrite and halite) deposition started later, at 5.60 Ma and (5) new and published ⁸⁷Sr/⁸⁶Sr data indicate that during all stages, evaporites precipitated from the same water body in all the Mediterranean sub‐basins. The wide synchrony of events and ⁸⁷Sr/⁸⁶Sr homogeneity implies inter‐sub‐basin connection during the whole MSC and is not compatible with large sea‐level fall and desiccation of the Mediterranean.