A complex, Subplinian-type eruption from low-viscosity, phonolitic to tephri-phonolitic magma: the AD 472 (Pollena) eruption of Somma-Vesuvius, Italy

The combined use of field investigation and laboratory analyses allowed the detailed stratigraphic reconstruction of the Pollena eruption (472 AD) of Somma-Vesuvius. Three main eruptive phases were recognized, related either to changes in the eruptive processes and/or to relative changes of melt composition. The eruption shows a pulsating behavior with deposition of pyroclastic fall beds and generation of dilute and dense pyroclastic density currents (PDC). The eruptive mechanisms and transportation dynamics were reconstructed for the whole eruption. Column heights were between 12 and 20 km, corresponding to mass discharge rates (MDR) of 7×10⁶ kg/s and 3.4×10⁷ kg/s. Eruptive dynamics were driven by magmatic fragmentation of a phono-tephritic to tephri-phonolitic magma during Phases I and II, whereas phreatomagmatic fragmentation dominated Phase III. Magma composition varies between phonolitic and tephritic-phonolitic, with melt viscosity likely not in excess of 10³ Pa s. The volume of the pyroclastic fall deposits, calculated by using of proximal isopachs, is 0.44 km³. This increases to 1.38 km³ if ash volumes are extrapolated on a log thickness vs. square root area diagram using one distal isopach and column height.Editorial responsibility: R Cioni     

Geochronology of granulites from the south Itabuna-Salvador-Curaçá Block,São Francisco Craton (Brazil): Nd isotopes and U–Pb zircon ages

This work provides five new U–Pb zircon dating and the corresponding Nd isotope data for felsic granulites from the south Itabuna-Salvador-Curaçá Block (ISCB), in the São Francisco Craton, Brazil. Three major sets of felsic granulites can be recognised. The oldest set is tonalitic in composition and of TTG affinity. It is Archaean in age with magmatic zircon cores dated at 2675 ± 11 Ma by LA-ICPMS and up to ca 2.7–2.9 Ga by SHRIMP on an other sample. It exhibits epsilon Nd values between ?8 and ?11 at 2.1 Ga. This Nd signature is similar to that of granulites found in the western Archaean Jequié Block. Cartographically, this set of Archaean terrains represents at least 50% of the granulites in the studied area. The second set corresponds to a Palaeoproterozoic calc-alkaline tonalitic suite with zircon ages from 2019 ± 19 Ma to 2191 ± 10 Ma and epsilon Nd values between ?3 and ?4 at 2.1 Ga, corresponding partially to a newly formed crust. The third set of granulites is also Palaeoproterozoic. It is shoshonitic to monzonitic in composition and synchronous with the high grade metamorphism dated by metamorphic zircons at 2086 ± 7 Ma (average of five samples). The Nd isotope signature for this alkaline set is similar to that of the Palaeoproterozoic calc-alkaline one. Nd isotopes appear to be a very efficient tool to distinguish Archaean from Palaeoproterozoic felsic protoliths in granulitic suites of the Itabuna-Salvador-Curaçá Block (ISCB). Finally, the southern part of the ISCB is composed of a mixture of Archaean and Palaeoproterozoic protoliths, in similar amounts, suggesting that it was probably an active margin between 2.1 and 2.2 Ga located on the eastern border of the Archaean Jequié Block. A major crustal thickening process occurred at ca 2.09 Ga in the ISCB and seems significantly younger towards the west, in the Jequié granulites, where an average of 2056 ± 9 Ma is determined for the high grade event.     

Chemical and textural equilibration of garnet during amphibolite facies metamorphism: The influence of coupled dissolution–reprecipitation

Metamorphic equilibration requires chemical communication between minerals and may be inhibited through sluggish volume diffusion and or slow rates of dissolution in a fluid phase. Relatively slow diffusion and the perceived robust nature of chemical growth zoning may preclude garnet porphyroblasts from readily participating in low‐temperature amphibolite facies metamorphic reactions. Garnet is widely assumed to be a reactant in staurolite‐isograd reactions, and the evidence for this has been assessed in the Late Proterozoic Dalradian pelitic schists of the Scottish Highlands. The 3D imaging of garnet porphyroblasts in staurolite‐bearing schists reveals a good crystal shape and little evidence of marginal dissolution; however, there is also lack of evidence for the involvement of either chlorite or chloritoid in the reaction. Staurolite forms directly adjacent to the garnet, and its nucleation is strongly associated with deformation of the muscovite‐rich fabrics around the porphyroblasts. “Cloudy” fluid inclusion‐rich garnet forms in both marginal and internal parts of the garnet porphyroblast and is linked both to the production of staurolite and to the introduction of abundant quartz inclusions within the garnet. Such cloudy garnet typically has a Mg‐rich, Mn‐poor composition and is interpreted to have formed during a coupled dissolution–reprecipitation process, triggered by a local influx of fluid. All garnet in the muscovite‐bearing schists present in this area is potentially reactive, irrespective of the garnet composition, but very few of the schists contain staurolite. The staurolite‐producing reaction appears to be substantially overstepped during the relatively high‐pressure Barrovian regional metamorphism reflecting the limited permeability of the schists in peak metamorphic conditions. Fluid influx and hence reaction progress appear to be strongly controlled by subtle differences in deformation history. The remaining garnet fails to achieve chemical equilibrium during the reaction creating distinctive patchy compositional zoning. Such zoning in metamorphic garnet created during coupled dissolution–reprecipitation reactions may be difficult to recognize in higher grade pelites due to subsequent diffusive re‐equilibration. Fundamental assumptions about metamorphic processes are questioned by the lack of chemical equilibrium during this reaction and the restricted permeability of the regional metamorphic pelitic schists. In addition, the partial loss of prograde chemical and textural information from the garnet porphyroblasts cautions against their routine use as a reliable monitor of metamorphic history. However, the partial re‐equilibration of the porphyroblasts during coupled dissolution–reprecipitation opens possibilities of mapping reaction progress in garnet as a means of assessing fluid access during peak metamorphic conditions.     

Coastal Occupations in Tierra del Fuego,Southernmost South America: A Late Holocene Hunter‐Gatherer Context at Marazzi 2

This paper focuses on the late Holocene occupation of hunter‐gatherers at the Marazzi 2 site located on the northwestern steppe of Tierra del Fuego, Chile. Our aim is to understand stratigraphy, formation processes, and pedogenesis with respect to human occupation over the last 3000 years. Based on archaeological excavations on a fluvial terrace of the Torcido River, we integrate soil micromorphology, mineralogy, geochemistry, magnetic susceptibility, and geomorphology, as well as the micro‐ and macrofrequency distributions of archaeological material. A micro‐taphonomical perspective is also applied to anthropogenic components recorded in sedimentary thin sections. We discuss various events in the interplay between soil development and human occupation through time. Marazzi 2 was witness to aggradation and pedogenesis with an episode of surface stability coincident with a phase of more intense human occupation at about 860 BC. Taphonomic analysis suggests that there are multiple occupation events mixed together, probably by biomechanical processes, resulting in a palimpsest with poor temporal resolution.     

Defining the Potential of Nanoscale Re‐Os Isotope Systematics Using Atom Probe Microscopy

Atom probe microscopy (APM) is a relatively new in situ tool for measuring isotope fractions from nanoscale volumes (< 0.01 μm³). We calculate the theoretical detectable difference of an isotope ratio measurement result from APM using counting statistics of a hypothetical data set to be ± 4δ or 0.4% (2s). However, challenges associated with APM measurements (e.g., peak ranging, hydride formation and isobaric interferences), result in larger uncertainties if not properly accounted for. We evaluate these factors for Re‐Os isotope ratio measurements by comparing APM and negative thermal ionisation mass spectrometry (N‐TIMS) measurement results of pure Os, pure Re, and two synthetic Re‐Os‐bearing alloys from Schwander et al. (2015, Meteoritics and Planetary Science, 50, 893) [the original metal alloy (HSE) and alloys produced by heating HSE within silicate liquid (SYN)]. From this, we propose a current best practice for APM Re‐Os isotope ratio measurements. Using this refined approach, mean APM and N‐TIMS ¹⁸⁷Os/¹⁸⁹Os measurement results agree within 0.05% and 2s (pure Os), 0.6–2% and 2s (SYN) and 5–10% (HSE). The good agreement of N‐TIMS and APM ¹⁸⁷Os/¹⁸⁹Os measurements confirms that APM can extract robust isotope ratios. Therefore, this approach permits nanoscale isotope measurements of Os‐bearing alloys using the Re‐Os geochronometer that could not be measured by conventional measurement principles.     

Meridional Motion and Reynolds Stress from Debrecen Photoheliographic Data

The Debrecen Photoheliographic Data catalogue is a continuation of the Greenwich Photoheliographic Results providing daily positions of sunspots and sunspot groups. We analyse the data for sunspot groups focussing on meridional motions and transfer of angular momentum towards the solar equator. Velocities are calculated with a daily shift method including an automatic iterative process of removing the outliers. Apart from the standard differential rotation profile, we find meridional motion directed towards the zone of solar activity. The difference in measured meridional flow in comparison to Doppler measurements and some other tracer measurements is interpreted as a consequence of different flow patterns inside and outside of active regions. We also find a statistically significant dependence of meridional motion on rotation velocity residuals confirming the transfer of angular momentum towards the equator. Analysis of horizontal Reynolds stress reveals that the transfer of angular momentum is stronger with increasing latitude up to about \(40^{\circ}\), where there is a possible maximum in absolute value.     

Geomagnetic Effects of Corotating Interaction Regions

We present an analysis of the geoeffectiveness of corotating interaction regions (CIRs), employing the data recorded from 25 January to 5 May 2005 and throughout 2008. These two intervals in the declining phase of Solar Cycle 23 are characterised by a particularly low number of interplanetary coronal mass ejections (ICMEs). We study in detail how four geomagnetic-activity parameters (the Dst, Ap, and AE indices, as well as the Dst time derivative, \(\mathrm{dDst}/\mathrm{d}t\)) are related to three CIR-related solar wind parameters (flow speed, \(V\), magnetic field, \(B\), and the convective electric field based on the southward Geocentric solar magnetospheric (GSM) magnetic field component, \(\mathit{VB}_{s}\)) on a three-hour time resolution. In addition, we quantify statistical relationships between the mentioned geomagnetic indices. It is found that Dst is correlated best to \(V\), with a correlation coefficient of \(\mathrm{cc}\approx0.6\), whereas there is no correlation between \(\mathrm{dDst}/\mathrm{d}t\) and \(V\). The Ap and AE indices attain peaks about half a day before the maximum of \(V\), with correlation coefficients ranging from \(\mathrm{cc}\approx0.6\) to \(\mathrm{cc}\approx0.7\), depending on the sample used. The best correlations of Ap and AE are found with \(\mathit{VB}_{s}\) with a delay of 3 h, being characterised by \(\mathrm{cc}\gtrsim 0.6\). The Dst derivative \(\mathrm{dDst}/\mathrm{d}t\) is also correlated with \(\mathit{VB}_{s}\), but the correlation is significantly weaker \(\mathrm{cc}\approx 0.4\)?–?0.5, with a delay of 0?–?3 h, depending on the employed sample. Such low values of correlation coefficients indicate that there are other significant effects that influence the relationship between the considered parameters. The correlation of all studied geomagnetic parameters with \(B\) are characterised by considerably lower correlation coefficients, ranging from \(\mathrm{cc}=0.3\) in the case of \(\mathrm{dDst}/\mathrm{d}t\) up to \(\mathrm{cc}=0.56\) in the case of Ap. It is also shown that peak values of geomagnetic indices depend on the duration of the CIR-related structures. The Dst is closely correlated with Ap and AE (\(\mathrm{cc}=0.7\)), Dst being delayed for about 3 h. On the other hand, \(\mathrm{dDst}/\mathrm{d}t\) peaks simultaneously with Ap and AE, with correlation coefficients of 0.48 and 0.56, respectively. The highest correlation (\(\mathrm{cc}=0.81\)) is found for the relationship between Ap and AE.     

Relict sand dredging for beach nourishment in the central Tyrrhenian Sea (Italy): effects on benthic assemblages

The aim of this study is to analyse the effects in space and time of relict sand-dredging activities on macrobenthic assemblages, in an area situated offshore Montalto di Castro (central Tyrrhenian Sea, Italy), and to analyse the recolonisation processes of macrobenthos in the dredged areas. The area in question is characterised by relict sand deposits (Holocenic paleo-beaches), used for beach nourishment along the Latium coast. The effects of sand extraction on benthic assemblages were investigated before, during and after three dredging operations. The sites analysed are located within the dredged areas (inside stations) and in neighbouring, not dredged, areas (outside stations). The results showed that the impact of sand extraction was confined to the dredged stations and to the areas in proximity to the dredged areas. During dredging activities, the structure of benthic assemblages within the impacted stations was characterised by low species richness and diversity. Both the direct removal of sediment and the re-suspension and consequent deposition of fine sediment affected benthic assemblages of the impacted stations. A few months after the dredgings, a recolonisation process was still observed at all the impacted stations. A gradual recolonisation process was observed at those stations affected by only one dredging, whereas a different recolonisation was observed at those stations affected by two dredgings over time. This study suggests that differences of re-colonisation processes of benthic assemblages are related to the intensity of dredging operations in terms of dredging frequency.     

Strato-mesospheric ozone and IMF sector boundary

Summary We find no effect of the interplanetary magnetic field(IMF) sector boundary crossing in ozone at altitudes ranging from the middle stratosphere(10 hPa) to the lower mesosphere(0.4 hPa) at middle latitudes(40°–60° N), based on winter data over the period of December 1979–December 1982.

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Резюме Мы не нaшлu нuкaко о эффекma nересеченuя секmорноŭ рaнuцы межnлaнеmно о мa нumно о nоля в озоне в облaсmu высоm меж?rt;у сре?rt;неŭ сmрamосфероŭ(10 Пa) u нuжнеŭ мезосфероŭ(0,4 Пa) нa сре?rt;нuх шuроmaх(40°–60° с.ш.), nрuменяя зuмнuе ?rt;aнные зa nерuо?rt; ?rt;екaбрь 1979 – ?rt;екaбрь 1982 .