2D geological–geophysical model of the Timok Complex (Serbia,SE Europe): a new perspective from aeromagnetic and gravity data

The study reports new aeromagnetic and gravity data for the northern part of the Timok Magmatic Complex (TMC), East Serbia. The TMC is part of the Tethyan Eurasian metallogenic zone well known for hosting large copper and gold deposits. The complex formed by continuous volcanic activity 90–78 Ma ago, that developed in roughly three phases: Turonian andesites, Santonian–Campanian andesites/basaltic andesites (both mostly volcanic) and Campanian latites/monzonites (mostly shallow intrusive). The aeromagnetic measurements included acquiring total magnetic intensity data that were corrected for diurnal variations, leveling, microleveling, calculated normal field values, calculated anomaly values of total magnetic field intensity and reduction to the pole. The gravity measurements were carried out in an irregular grid with relative gravity values obtained using a Worden gravity meter. 2D modeling reveals that the subsurface extension of the Campanian Valja Str? pluton is ten times larger than it is indicated by its surface outcrops. This implies that the area south and southeast from the pluton can be interesting in terms of finding new porphyry systems. The model indicates that this intrusive body should not be considered as a deeply dissected pluton. This sheds new light onto its potential with respect to epithermal gold mineralization, as well. The model also suggests that there are larger non-exposed bodies of Santonian–Campanian volcanics and near-surface hydrothermally altered rocks than it is inferred from geological maps. The results of our study suggest that further interdisciplinary investigations in the TMC, in particular those integrating geophysics and geology, may have potential of advancing the existing exploration models.     

Seismic performance of masonry walls retrofitted with steel reinforced grout

An innovative solution for the seismic protection of existing masonry structures is proposed and investigated through shake table tests on a natural scale wall assemblage. After a former test series carried out without reinforcement, the specimen was retrofitted using Steel Reinforced Grout. The strengthening system comprises horizontal strips of ultra‐high strength steel cords, externally bonded to the masonry with hydraulic lime mortar, and connectors to transversal walls, applied within the thickness of the plaster layer. In order to assess the seismic performance of the retrofitted wall, natural accelerograms were applied with increasing intensity up to failure. Test results provide a deep understanding of the effectiveness of mortar‐based composites for improving the out‐of‐plane seismic capacity of masonry walls, in comparison with traditional reinforcements with steel tie‐bars. The structural implications of the proposed solution in terms of dynamic properties and damage development under earthquake loads are also discussed.Copyright © 2015 John Wiley & Sons, Ltd.     

Eclogite relics in the Variscan orogenic belt of Bulgaria (SE Europe)

Eclogitic rocks were sampled from two zones in the basement of the Sredna Gora terrane (central western Bulgaria): (1) partially retrogressed eclogites and amphibolites embedded in sillimanite-bearing garnet-micaschists with kyanite relics and migmatites and (2) banded amphibolites associated with muscovite-bearing metagranites within two-mica paragneisses. Rutile relics and oligoclase + green hornblende + epidote ± biotite pseudomorphs after garnet suggest an eclogite facies event. A tholeiitic, transitional affinity was determined for the protoliths, suggesting a continental rift environment, consistent with several eclogite-bearing complexes in the eastern segments of the Variscan belt that arose from the Cambro-Ordovician Gondwana break-up. Decreasing pressure after the eclogite overprint was demonstrated by (a) diopside-albite symplectite, and (b) plagioclase + red–brown to green amphibole kelyphite. The early static re-equilibration, dated to 398 ± 5.2 Ma by ⁴⁰Ar–³⁹Ar technique, was followed by an amphibolite facies foliation, which was pervasive in amphibolites, gneisses and micaschists, and poorly developed in eclogites. The lithospheric PT paths corresponding to higher and lower metamorphic gradients reflect the juxtaposition of crustal and lithospheric mantle units, respectively. In the build-up of the basement of the Balkan orogen, the physical properties of the lithological complexes might have influenced the collisional pattern of involved microplates.     

Forcing mechanisms of a heavy precipitation event in the southeastern Adriatic area

The aim of this study was to identify the main mesoscale features and mechanisms responsible for the generation of an extreme precipitation event as a contribution to improving the modelling of processes that produce HPEs. The event occurred during the morning hours on 22 November 2010 over the Dubrovnik coast in Croatia and the hinterland mountain range of the southern Dinaric Alps and caused severe flash floods and landslides and consequent interruption of traffic and electricity supply as well as other infrastructural damage. The analysis is geographically focused on the southern portion of the eastern Adriatic region, which is prone to relatively frequent heavy precipitation events that occur mostly in autumn. This area is one of the rainiest in Europe with expected annual amounts of precipitation greater than 5,000 mm in the mountainous hinterland. The mechanisms responsible for the formation of convection were analysed using synop measurements, satellite data and numerical experiments performed with the WRF model, which was set up at the convection-permitting resolution in the innermost domain. Satellite data were used to identify the precipitation systems and to estimate the intensity of the precipitation during the period of interest. The development of the precipitation system was connected to a strong large-scale ascent over the southern Italy and southern Adriatic due to the advection of warm air and cyclonic vorticity advection, which increases with height. The numerical simulations highlighted the essential role of a southerly low-level jet stream in the transport of warm and moist air towards the affected area. The convergence of two branches of low-level marine air favoured convection triggered over the coast and sea. Furthermore, numerical sensitivity experiments suggested that the orography of the Dinaric Alps plays an essential role in the precipitation maximum over the mountainous hinterland, but also that the orography was not the crucial factor in the heavy precipitation near Dubrovnik. This study highlights the need for a dense network of observations, especially radar measurements, to validate the simulated mechanisms and improve numerical forecasts via data assimilation.     

Groundwater quality on the territory of Kikinda municipality (Vojvodina,Serbia)

This paper provides insight into the quality of groundwater used for public water supply on the territory of Kikinda municipality (Vojvodina, Serbia) and main processes which control it. The following parameters were measured: color, turbidity, pH, KMnO₄ consumption, TDS, EC, NH₄ ⁺, Cl^?, NO₂ ^?, NO₃ ^?, Fe, Mn, total hardness, Ca²⁺, Mg²⁺, SO₄ ²⁺, HCO₃ ^?, K⁺, Na⁺, As. The correlations and ratios among parameters that define the chemical composition were determined aiming to identify main processes that control the formation of the chemical composition of the analyzed waters. Groundwater from 11 analyzed sources is Na–HCO₃ type. Intense color and elevated organic matter content of these waters originate from humic substances. The importance of organic matter decay is assumed by positive correlation between organic matter content and TDS, HCO₃ content. There is no evidence that groundwater chemistry is determined by the depth of captured aquifer interval. The main processes that control the chemistry of all analyzed water are cation exchange and feldspar weathering.     

Practical evaluation of carbon sources of forest soils in Slovenia from stable and radio-carbon isotope measurements

Carbon sources were estimated by measuring carbon isotope ratios (??¹³C and ??¹⁴C) with accelerator mass spectrometry (AMS) in forest soils of different lithology. Six locations were selected in temperate deciduous and coniferous stands in Slovenia (?irovski vrh, Idrija, Ko?evski Rog, Pohorje, Gori?nica, and Rakitna), where carbonate rocks consisting of limestone and dolomite are abundant as underlying bedrock. Carbon isotope fractionation would not have occurred in two carbonaceous soils, since the values of both ??¹³C and ??¹⁴C changed consistently in these soils after thermal (550°C, 2?h) or chemical (1?M HCl, 24?h) treatments. Organic components were found to be predominant carbon sources (70?C100%) in the uppermost portions (0?C2?cm in depth). In deeper portions at a depth of about 30?C35?cm, soil carbon may be derived completely from underlying carbonate minerals in Idria, western part of Slovenia. The Combination of heat and chemical treatments with AMS provides practical information on soil carbon sources in carbonaceous soils.     

Earth rotation and network geometry optimization for very long baseline interferometers

Very Long Baseline Interferometry (VLBI) is one of the new techniques which will probably dominate geodesy and geophysics in the near future. Its main advantage lies in the fact that it brings the accuracy of direction measurements to a level previously possible only for range measurements. This closes the gap between powerful range determination techniques such as laser ranging and the much less accurate determination of directions through photographic tracking of artificial earth satellites. The technique is geometric in the sense that the relevant observations are independent of the gravity field of the earth. However, the “orbits” of the observed extragalactic radio sources with respect to an earth-fixed system are dominated and perturbed by the rotation of the earth with respect to inertial frame. This allows the determination of polar motion, precession-nutation and length-of-the-day variations, and the technique becomes also “dynamic” in this respect. The capability of determining the geometry of a network of stations within a short time interval and with a centimeter level accuracy also allows the study of the variation of network geometry with time caused by earth tides and other periodic or secular station drifts. The main objective of the present work is the exploration of the capabilities of VLBI for the recovery of earth rotation and network geometry parameters. For this purpose, a number of characteristic experimental designs based on present and candidate for the near future station locations is chosen. The results from the analysis of simulated observations for each particular design are presented in the paper. Presented at IAG International Symposium on “Optimization of Design and Computation of Control Networks”, Sopron, Hungary, 4–10 July 1977.     

A model of oscillatory zoning in solid solutions grown from aqueous solutions: Applications to the (Ba,Sr)SO4 system

Barite-celestite crystals can be synthesized from aqueous solutions during counter-diffusion in a gel column connecting two reservoirs. It is known that such crystals may exhibit oscillatory zoning, whereby the barium composition in the crystal fluctuates more or less regularly from the core of the crystal to its rim. We present here a simple model of oscillatory zoning in such binary solid solutions A₁A₂ grown from aqueous solutions. The model combines diffusive transport of the relevant ions with an autocatalytic growth process. The latter is formulated as a continuous growth in which the probability of finding a kink site on the growing surface depends on the chemical composition of that surface. Thus, an A₁-rich surface favors the growth of A₁ over A₂, as long as A₁ is present in the vicinity of the surface. Precipitation results in a local depletion of A₁ in the aqueous solution, and the system may switch to a A₂ growth mode, until diffusion replenishes the amount of A₁, and so on. We use a dynamical equation for the molar fraction of component A₁ in the crystal, which results from mass conservation across the rough crystal-solution interface. Linear stability analysis and direct numerical solutions show that the system exhibits oscillatory behavior. Using the barite-celestite system as a framework, the scaling is consistent with the experimental observations. We discuss the variety of zoning patterns and textures numerically obtained as the concentrations of reactants in the reservoirs vary. This model might help in understanding the formation of oscillatory zoning in hydrothermal environments.     

Croatia as a Danube country

Among the three principal regional units of Croatia, i.e. the elongated and spacious Adriatic littoral (with numerous islands), the relatively small and narrow mountainous belt (the Croatian transit doorway) and the Pannonian/peri-Pannonian region, the latter is the largest and accounts for 54 percent of the surface area and 66 percent of the population of Croatia (1991 census). It is part of the Pannonian (or Carpathian) basin, or the central Danube basin, so that Croatia is simply by its position a Danube country. Its Danube character is also highlighted by the fact that the Pannonian/peri-Pannonian region of Croatia through the Sava and Drava Rivers is directly linked to the navigable Danube, which is the historical and ethnic eastern boundary of Croatia. Croatia is an old historical Danube nation and country, although it has nominally appeared as a state after the break-up of Yugoslavia, and its international recognition as an independent state (1992).