Evaluation of coal as adsorbent for phosphate removal

This paper reports the adsorption of phosphate ions on coal, charcoal, and coal ash. The influences of factors such as contact time, and initial adsorbate concentration have been studied. Adsorption of phosphate ions on virgin coal was significant compared to charcoal, coal and coal ash evacuated at 200°C. The significant adsorption capability of coal is due to the porosity as well as due to organic carbon and inorganic elements present in coal. The evacuation of coal proved to be ineffective in enhancing its capability for phosphate ions retention. The adsorption behaviors of all the three adsorbent used was conformed using Freundlich’s adsorption model. The results suggest that coal could be used as an efficient adsorbent for removing phosphate ions from wastewater.     

Precursors of Copepod Abundance in the Gulf of Maine in Atmospheric Centers of Action and Sea Surface Temperature

Interannual variations of total copepod abundance in the Gulf of Maine (1961-1991) are analyzed and related to the semi-permanent atmospheric pressure systems: Icelandic Low (IL) and the Azores High (AH). These centers of action dominate atmospheric and oceanic circulation in the North Atlantic. Cross-correlation analysis of zooplankton, sea surface temperature (SST) and the atmospheric characteristics have revealed different (from one to three years) time lags between the above characteristics. A multiple stepwise regression analysis gave a correlation value of 0.7 between observed and predicted interannual changes of total copepod abundance. A discussion is included of possible mechanisms that may contribute to the dynamic links that transfer atmospheric variation into observed changes in zooplankton abundance.     

Surface currents and equatorial thermocline in a coupled upper ocean-atmosphere GCM

The Oregon State University coupled upper ocean-atmosphere GCM is evaluated in terms of the simulated winds, ocean currents and thermocline depth variations. Although the zonal wind velocities in the model are underestimated by a factor of about three and the zonal current velocities are underestimated by a factor of about five, the model is seen to qualitatively simulate the major features of the gyral scale currents, and the phases of the seasonal variation of the principal equatorial currents are in reasonable agreement with observations. The simulated tropical currents are dominated by Ekman transport and the eastern boundary currents do not penetrate far enough equatorward, while the western boundary currents do not penetrate far enough poleward. The subtropical trade wind belt and the mid-latitude westerlies are displaced equatorward of observations; hence, the mid-latitude eastward currents, principally the Kuroshio-North Pacific Drift and the Gulf Stream-North Atlantic Current are displaced equatorward. In spite of these shortcomings the surface current simulation of this two-layer upper ocean model is comparable with that of other ocean GCMs of coarse resolution. The coupled model successfully simulates the deepening of the thermocline westward across Pacific as a consequence of the prevailing Walker circulation. The region of most intense simulated surface forcing is located in the western Pacific due to a southwestward displacement of the northeast trade winds relative to observations; hence the equatorial Pacific is dominated by eastward propagation of thermocline depth variations. The excessively strong Ekman divergence and upwelling in the western Pacific cools the local warm pool, while incorrectly simulated westerlies in the eastern Pacific suppress upwelling and inhibit cooling from below. These features reduce the simulated trans-Pacific sea-surface temperature gradient, weakening the Walker circulation and the anomalies associated with the simulated Southern Oscillation. Offprint requests to: KR Sperber     

Wind waves and sediment transport regime off the south-central Kerala coast,India

Wind waves in the innershelf of the south-central Kerala coast, south-west India were measured at four locations during different seasons. Simultaneously, numerical models were developed to simulate the wave and sediment transport regime of the innershelf. Strong monsoonal influence is seen in the wave characteristics with greater amplitudes, lower periods and switch-over from SW to SWW–W direction. The net annual longshore sediment transport is southerly in the innershelf and northerly in the surf zone. These counter-directional transports are linked by seasonally reversing the cross-shore transports. In the locations where the transports in the longshore and cross-shore directions are balanced, stable beaches prevail. Erosion/accretion tendency prevails in locations where these transports are not balanced. The southern and northern parts of the coast where onshore transports are predominant could be accreting zones. The erosion/accretion pattern deduced from the sediment transport model corresponds well with the long-term erosion/accretion trend for this coast.     

A study of the monsoonal beach processes around Alleppey,Kerala

The responses of a sandy beach to the southwest monsoonal waves are studied based on biweekly observations. The onslaught of the first spell of monsoonal breakers causes maximum erosion in the sub-aerial section of the beach. However, further spells of high breakers do not affect this zone significantly. The erosion in the sub-aerial zone is followed by accretion in the nearshore zone and vice versa. Whereas the sub-aerial zone has a net erosion the total section of the beach including the nearshore zone shows near equilibrium condition. It is concluded that in spite of erosion or accretion of the sub-aerial zone, equilibrium conditions may be found in the total section of the beach.     

Biodegradation of starch blended polyvinyl chloride films by isolated Phanerochaete chrysosporium PV1

The accumulation of plastics in the environment is raising great concerns with respect to long-term environmental, economic and waste management problems. The aim of the present research was to investigate the biodegradability of starch blended polyvinyl chloride films in soil burial and controlled laboratory experiments using selective fungal isolates. Clear surface aberrations as color change and minor disintegration in polyvinyl chloride films were observed after 90 days and later confirmed through scanning electron microscopy. The fungal strains showing prominent growth and adherence on plastic films were isolated. One of the strains showing maximum activity was selected and identified as Phanerochaete chrysosporium PV1 by rDNA sequencing. Fourier transform infrared spectroscopy and nuclear magnetic resonance analyses indicated considerable structural changes and transformation in films in terms of appearance of new peaks at 3,077 cm^?1 (corresponding to alkenes) and decrease in intensity of peaks at 2,911 cm^?1 (C–H stretching). It was supported with a significant decrease in the molecular weight of polymer film from 80,275 to 78,866 Da (treated) through Gel permeation chromatography in shake flask experiment. Moreover, the biodegradation of starch blended polyvinyl chloride films was confirmed through release of higher CO₂ (7.85 g/l) compared to control (2.32 g/l) in respirometric method. So fungal strain P. chrysosporium PV1 has great potential for use in bioremediation of plastic waste.     

Use of treated wastewater for managed aquifer recharge in highly populated urban centers: a case study in Addis Ababa,Ethiopia

Fast population growth and rapid industrialization, on one hand, and lack of sewerage network and poor living condition, on the other, have led to the deterioration of surface and ground water quality in the city of Addis Ababa. The urban wastewater is discharged largely into streams that drain the city. Only less than 3% join the wastewater treatment facilities. Due to sporadic rainfall that causes shortage in groundwater recharge, managed aquifer recharge (MAR) experiment was tested on soil column collected from Akaki Well Field which is located in the southern part of the city using water from the Big Akaki River that crosses the same well field and effluent from Kaliti Wastewater Treatment Plant. Water quality analysis for 17 different parameters was done for both the inflow and outflow water samples and soils were tested for electrical conductivity and cation exchange capacity. The results indicate improved water quality as a result of higher attenuation/filtration capacity of the vadose zone in the well field due to the presence of vertisols. The main geochemical processes that have acted in the soil column could be cation exchange, dissolution, precipitation, oxidation, nitrification, die off etc. that are responsible for the effectiveness of vadose zone for MAR.