Middle Miocene to Pleistocene magneto-biostratigraphy of ODP Sites 1150 and 1151, northwest Pacific: Sedimentation rate and updated regional geological timescale

Abstract Shipboard and shore‐based investigation on siliceous and calcareous microfossil biostratigraphy, magneto‐stratigraphy and tephrostratigraphy identified numerous datum events from the sedimentary sequences of Sites 1150 and 1151 drilled on the forearc basin of northern Japan by the Ocean Drilling Program Leg 186. Some 83 datum events were selected to construct new age–depth models for the sites. Based on the reliable magneto‐stratigraphy from the Pleistocene to the Upper Miocene, which were correlated to the standard geomagnetic polarity timescale, and on excellent records of diatom and radiolarian biostratigraphy throughout the sequences, the shipboard age model was revised. Major revisions referred to stratigraphic position of the Miocene–Pliocene boundary that has been shifted more than 200 m downward in each sequence. The age–depth relations of the forearc sites represent drastic changes in the sedimentation rate—extremely high (40 cm/k.y. on average) in the Early Pliocene and low (less than 2 cm/k.y. on average) in the Middle Miocene—and several hiatuses exist throughout the sequence. The drastic changes can be related mostly to changes in diatom sedimentation and the tectonics of the Japanese Island Arc. Local ages for some foraminiferal, calcareous nannofossil and radiolarian bioevents are estimated from the age–depth models at each site. These newly calibrated bioevents and biozones as well as established diatom biostratigraphy are incorporated into the updated magneto‐biochronologic timescale, which will contribute to an improvement in biochronologic accuracy of Neogene sediments in northern Japan and adjacent areas.     

Thermal expansion of single-crystal tephroite

The thermal expansion of tephroite (Mn₂SiO₄) at temperatures between 25 and 850°C has been determined by a dilatometric technique. The analysis of data in terms of Grüneisen's theory yields the Grüneisen's parameter γ=1.04, and the pressure derivative of rigidity (?G/?P)=0.7.     

Chaos in cosmic ray air showers

Unexpected chaotic features are found in time series of arrival time intervals of successive air showers with (E > 3 × 10¹⁴ eV). Over 99 % of air shower arrival time intervals obey the Poisson distribution law representing stochastic behaviors, but occasionally there are air showers showing real chaotic behaviors as distinguished from both random and colored noises. With two systems of the Kinki university installations, we found 13 cases showing chaotic time series in 3.36 yr with the system-1 and the 1.37 yr with the system-2. Five out of 10 chaotic air showers of the Kinki installation are detected during the same time zone also by the Osaka City university installation which is at 115 km distance from the Kinki one. In a remarkable example of September 19, 1991, the correlation dimension was observed to have dropped from about 4 to the minimum of 1.3 and recovered smoothly in about 38 h. The chaos structure in this case is detected in nearly the same time zone at the Ohya station of the Institute for Cosmic Ray Research, University of Tokyo, which is separated from the Kinki one by 460 km. Formation of chaos structure due to energetic cosmic ray dust particles is suggested. Progress of cosmic ray physics may be expected with the study of air showers marked with chaos.     

Light utilization efficiency of phytoplankton in the Western Subarctic Gyre of the North Pacific during summer

We investigated the water-column light utilization efficiency (Ψ) of phytoplankton photosynthesis in the Western Subarctic Gyre (WSG) of the North Pacific during summer 2008. The Ψ values (0.64–1.86 g C [g Chl a]^?1 [mol photon]^?1 m²) obtained were observed to increase significantly with decreasing daily photosynthetic available radiation (PAR) and were generally higher than those of previous studies, not only from the subarctic Pacific but also from the world’s oceans. To examine the effect of iron availability on Ψ in the WSG, Ψ values were estimated from the data of two in situ iron fertilization experiments: the Subarctic Pacific Iron Experiment for Ecosystem Dynamics Study I (SEEDS-I) and II (SEEDS-II). We found that iron availability did not affect Ψ values. Overall, this study revealed that Ψ values changed remarkably in the WSG during the summer, and that higher values were found at the stations where moderate PAR levels (ca. 10–30 mol photons m^?2 day^?1) were observed and where autotrophic flagellates predominated in the phytoplankton assemblages.     

Carbon-14 age and chemical evolution of Ca(HCO3)2-type groundwater of age less than 8,000 years in a confined sandy and muddy Pleistocene aquifer, Japan

The Pleistocene Kimitsu aquifer was selected for examination of the relationship between groundwater age and chemical evolution of Ca(HCO₃)₂-type groundwater. For the most part, the aquifer is confined and composed mainly of quartz and feldspar with a small amount of calcite. The groundwater ages calculated by ¹⁴C were adjusted by using a carbon mass-balance method and corrected for effects of ¹⁴C diffusion. Groundwater ages in the Kimitsu aquifer vary from modern (upgradient) to approximately 2,400 years at 4.4 km from the edge of the recharge area. The ¹⁴C age was verified by groundwater velocity calculated from the hydraulic gradient and hydraulic conductivity. The confined groundwater evolved to Ca(HCO₃)₂-type around 50 years after recharge and this has been maintained for more than 8,300 years due to low chemical reactivity, derived from equilibrium with calcite, kaolinite and Ca-montmorillonite. In addition, high pH prevents the dissolution of Fe and Mn. Consequently, the rate of increase in electrical conductivity ranges from 10 to 30 μS/cm per 1,000 years. On the other hand, leakage from the deep region, which is recognized from high Cl^– levels, causes remarkable increases in CH₄ and HCO₃ ^– concentrations, resulting in an apparent sulfidic zone at 500-m depth in most downgradient regions.     

Photoluminescence spectra of S<Subscript>2</Subscript><Superscript><Emphasis Type="Bold">−</Emphasis></Superscript> center in natural and heat-treated scapolites

The emission and excitation spectra of yellow luminescence due to S₂ ⁻ in scapolites (#1 from Canada and #2 from an unknown locality) were observed at 300, 80 and 10 K. Emission and excitation bands at 10 K showed vibronic structures with a series of maxima spaced 15–30 and 5–9 nm, respectively. The relative efficiency of yellow luminescence from scapolite #2 was increased up to 117 times by heat treatment at 1,000°C for 2 h in air. The enhancement of yellow luminescence by heat treatment was ascribed to the alteration of SO₃ ²⁻ and SO₄ ²⁻ to S₂ ⁻ in scapolite.