Sediment Yield During Late Glacial and Holocene periods in the Lac Chambon Watershed,Massif Central,France

A sediment budget for the Late Glacial and Holocene periods was calculated for the Lac Chambon watershed which is located in a formerly glaciated temperate crystalline mountain area. It appears that over 15 500 years: (1) 69 per cent of eroded particles have been displaced by gravity processes and then stored within the watershed, compared to 31 per cent that have been displaced by running water and evacuated outward; (2) the mean mechanical erosion due to gravity processes on the slopes amounted to 16·1 ±6 m and only developed on a quarter of the watershed surface, whereas the mean mechanical erosion due to running water amounted 1·24 ± 0·37 m and involved the whole watershed surface. The mean sediment yields due to gravity processes on slopes were 2300 ± 1360, 1770 ± 960 and 380 ± 100 m³ km⁻³ a⁻¹, respectively, for basalts, and basic and acidic trachyandesites. Values of sediment yield due to running water were 49±15, 120±36 and 79±24 m³ km⁻² a⁻¹, respectively, during the Bôlling–Allerôd, the Younger Dryas and the Pre-Boreal–Boreal periods. They were 56±17 and 166±50 m³ km⁻² a⁻¹ during the Sub-Atlantic period before and after 1360 a BP , respectively. These values reflect variations in the natural environment and the impact of human-induced deforestation. © 1997 by John Wiley & Sons, Ltd.     

Crude Oil Metabolites in Groundwater at Two Spill Sites

Two groundwater plumes in north central Minnesota with residual crude oil sources have 20 to 50 mg/L of nonvolatile dissolved organic carbon (NVDOC). These values are over 10 times higher than benzene and two to three times higher than Diesel Range Organics in the same wells. On the basis of previous work, most of the NVDOC consists of partial transformation products from the crude oil. Monitoring data from 1988 to 2015 at one of the sites located near Bemidji, MN show that the plume of metabolites is expanding toward a lakeshore located 335 m from the source zone. Other mass balance studies of the site have demonstrated that the plume expansion is driven by the combined effect of continued presence of the residual crude oil source and depletion of the electron accepting capacity of solid phase iron oxide and hydroxides on the aquifer sediments. These plumes of metabolites are not covered by regulatory monitoring and reporting requirements in Minnesota and other states. Yet, a review of toxicology studies indicates that polar metabolites of crude oil may pose a risk to aquatic and mammalian species. Together the results suggest that at sites where residual sources are present, monitoring of NVDOC may be warranted to evaluate the fates of plumes of hydrocarbon transformation products.     

Arsenic Cycling in Hydrocarbon Plumes: Secondary Effects of Natural Attenuation

Monitored natural attenuation is widely applied as a remediation strategy at hydrocarbon spill sites. Natural attenuation relies on biodegradation of hydrocarbons coupled with reduction of electron acceptors, including solid phase ferric iron (Fe(III)). Because arsenic (As) adsorbs to Fe‐hydroxides, a potential secondary effect of natural attenuation of hydrocarbons coupled with Fe(III) reduction is a release of naturally occurring As to groundwater. At a crude‐oil‐contaminated aquifer near Bemidji, Minnesota, anaerobic biodegradation of hydrocarbons coupled to Fe(III) reduction has been well documented. We collected groundwater samples at the site annually from 2009 to 2013 to examine if As is released to groundwater and, if so, to document relationships between As and Fe inside and outside of the dissolved hydrocarbon plume. Arsenic concentrations in groundwater in the plume reached 230 µg/L, whereas groundwater outside the plume contained less than 5 µg/L As. Combined with previous data from the Bemidji site, our results suggest that (1) naturally occurring As is associated with Fe‐hydroxides present in the glacially derived aquifer sediments; (2) introduction of hydrocarbons results in reduction of Fe‐hydroxides, releasing As and Fe to groundwater; (3) at the leading edge of the plume, As and Fe are removed from groundwater and retained on sediments; and (4) downgradient from the plume, patterns of As and Fe in groundwater are similar to background. We develop a conceptual model of secondary As release due to natural attenuation of hydrocarbons that can be applied to other sites where an influx of biodegradable organic carbon promotes Fe(III) reduction.     

High-pressure behaviour of serpentine minerals: a Raman spectroscopic study

Four main serpentine varieties can be distinguished on the basis of their microstructures, i.e. lizardite, antigorite, chrysotile and polygonal serpentine. Among these, antigorite is the variety stable under high pressure. In order to understand the structural response of these varieties to pressure, we studied well-characterized serpentine samples by in situ Raman spectroscopy up to 10 GPa, in a diamond-anvil cell. All serpentine varieties can be metastably compressed up to 10 GPa at room temperature without the occurrence of phase transition or amorphization. All spectroscopic pressure-induced changes are fully reversible upon decompression. The vibrational frequencies of antigorite have a slightly larger pressure dependence than those of the other varieties. The O–H-stretching modes of the four varieties have a positive pressure dependence, which indicates that there is no enhancement of hydrogen bonding in serpentine minerals at high pressure. Serpentine minerals display two types of hydroxyl groups in the structure: inner OH groups lie at the centre of each six-fold ring while outer OH groups are considered to link the octahedral sheet of a given 1:1 layer to the tetrahedral sheet of the adjacent 1:1 layer. On the basis of the contrasting behaviour of the Raman bands as a function of pressure, we propose a new assignment of the OH-stretching bands. The strongly pressure-dependent modes are assigned to the vibrations of the outer hydroxyl groups, the less pressure-sensitive peaks to the inner ones.     

Influence of the warm pool and cold tongue El Niños on the following Caribbean rainy season rainfall

Caribbean rainfall and associated regional-scale ocean–atmosphere anomalies are analyzed during and after warm pool (WP) and cold tongue (CT) El Niño (EN) events (i.e. from the usual peak of EN events in boreal winter to next summer from 1950 to 2011). During and after a CT event, a north–south dipolar pattern with positive (negative) rainfall anomalies over the northern (southern) Caribbean during the boreal winter tends to reverse in spring, and then to vanish in summer. On the contrary, during and after a WP event, weak rainfall anomalies during the boreal winter intensify themselves from spring, with anomalous wet conditions over most of the Caribbean basin observed during summer, except over the eastern coast of Nicaragua and Costa Rica. The Caribbean rainfall anomalies associated with WP and CT events are shaped by competition between at least four different, but interrelated, mechanisms; (1) the near-equatorial large-scale subsidence anomaly over the equatorial Atlantic linked to the zonal adjustment of the Walker circulation; (2) the extra-tropical wave-like train combining positive phase of the Pacific/North American mode and negative phase of the North Atlantic Oscillation; (3) the wind-evaporation-sea surface temperature (SST) positive feedback coupling warmer-than-normal SST with weaker-than-normal low level easterlies over the tropical North Atlantic; and (4) the air-sea coupling between the speed of low level easterlies, including the Caribbean low level jet, and the SST anomaly (SSTA) gradient between the Caribbean basin and the eastern equatorial Pacific. It seems that Caribbean rainfall anomalies are shaped mostly by mechanisms (1–3) during CT events from the boreal winter to spring. These mechanisms seem less efficient during WP events when the atmospheric response seems driven mostly by mechanism (4), coupling positive west-east SSTA gradient with weaker-than-normal low level easterlies, and secondary by mechanism (3), from the boreal spring to summer.     

Urban hydrologic trend analysis based on rainfall and runoff data analysis and conceptual model calibration

Urban stormwater is a major cause of urban flooding and natural water pollution. It is therefore important to assess any hydrologic trends in urban catchments for stormwater management and planning. This study addresses urban hydrological trend analysis by examining trends in variables that characterize hydrological processes. The original and modified Mann‐Kendall methods are applied to trend detection in two French catchments, that is, Chassieu and La Lechere, based on approximately 1 decade of data from local monitoring programs. In both catchments, no trend is found in the major hydrological process driver (i.e., rainfall variables), whereas increasing trends are detected in runoff flow rates. As a consequence, the runoff coefficients tend to increase during the study period, probably due to growing imperviousness with the local urbanization process. In addition, conceptual urban rainfall‐runoff model parameters, which are identified via model calibration with an event based approach, are examined. Trend detection results indicate that there is no trend in the time of concentration in Chassieu, whereas a decreasing trend is present in La Lechere, which, however, needs to be validated with additional data. Sensitivity analysis indicates that the original Mann‐Kendall method is not sensitive to a few noisy values in the data series.     

Quaternary thermokarst and thermal erosion features in northern France: origin and palaeoenvironments

A thermokarst is a collapse feature resulting from the thawing of ice‐rich permafrost or of massive ice of various origins. Little attention has been paid to the sedimentary fabric resulting from this type of collapse, except for glaciotectonic features. In western Europe, two palaeo‐forms are commonly studied: lithalsas and ice‐wedge casts. Collapsed pingos are much rarer. Very few papers have compiled present‐day and fossil data. Here, field data collected from quarries in the eastern Paris Basin were analysed, providing useful records of thermokarst collapses in alluvial calcareous silts, sands, and gravels. These forms have a circular shape when viewed on satellite images. Permafrost is attested regionally by the recurrent occurrence of meter‐sized pattern grounds at the surface of the chalk and of ice‐wedge casts. Traces of segregation and reticulate ice are common. These features are primarily connected to a major interstadial, c. 150 ka BP, orbitally forced and commonly associated with a major glacial retreat. They occur both in drained and waterlogged situations, resulting in a specific pattern of deformation. They are controlled by the brittle and plastic behaviour of sediments and resemble passive glaciotectonism. Normal and reverse faults, with the offset decreasing downward, are common, and those with local shear are reported. Lithalsas, seasonal frost blisters, spring frost blisters and perhaps pingos seem to have formed. Most of these deformations correspond to thermokarst sinkholes bordered by gravitational collapse faults. The offset of these faults increases towards the surface, and the faults have been recurrently confused with neotectonism triggered by palaeo‐earthquakes. However, there are no faults beneath the observed deformation features, and the region lacks recorded seismic activity over the last century. Our data may be helpful in interpreting similar structures elsewhere.     

Information content of snow hydrological signatures based on streamflow,precipitation and air temperature

Hydrological signatures that represent snow processes are valuable to gain insights into snow accumulation and snow melt dynamics. We investigated five snow signatures. Considering inter-annual average of each calendar day, two slopes derived from the relation between streamflow and air temperature for different periods and streamflow peak maxima are used as signatures. In addition, two different approaches are used to compute inter-annual average and yearly snow storage estimates. We evaluated the ability of these signatures to characterize average (a) snow melt dynamics and (b) snow storage. They were applied in 10 Critical Zone Observatory catchments of the Southern Sierra mountains (USA) characterized by a Mediterranean climate. The relevance and information content of the signatures are evaluated using snow depth and snow water equivalent measurements as well as inter-catchment differences in elevation. The slopes quantifying the relations between streamflow and air temperature and the date of streamflow peak were found to characterize snow melt dynamics in terms of snow melt rates and snow melt affected areas. Streamflow peak dates were linked to the period of highest snow melt rates. Snow storage could be estimated both on average, considering all years, and for each year. Snow accumulation dynamics could not be characterized due to the lack of streamflow response during the snow accumulation period. The signatures were found potentially valuable to gain insights into catchment scale snow processes. In particular, when comparing catchments or observed and simulated data, they could provide insights into differences in terms of (a) snow melt rate and/or snow melt affected area over the snow melt season and (b) average or yearly snow storage. Requiring only widely available data, these hydrological signatures can be valuable for snow processes characterization, catchment comparison/classification or model development, calibration or evaluation.     

Local and controlled prestack depth migration in complex areas

Prestack depth migrations based on wavefield extrapolation may be computationally expensive, especially in 3D. They are also very dependent on the acquisition geometry and are not flexible regarding the geometry of the imaging zone. Moreover, they do not deal with all types of wave, considering only primary reflection events through the model. Integral approaches using precalculated Green's functions, such as Kirchhoff migration and Born-based imaging, may overcome these problems. In the present paper, both finite-difference traveltimes and wavefront construction are used to obtain asymptotic Green's functions, and a generalized diffraction tomography is applied as an example of Born-based acoustic imaging. Target-orientated imaging is easy to perform, from any type of survey and subselection of shot/receiver pairs. Multifield imaging is possible using Green's functions that take into account, for instance, reflections at model boundaries. This may help to recover parts of complex structures which would be missing using a paraxial wave equation approach. Finally, a numerical evaluation of the resolution, or point-spread, function at any point of the depth-migrated section provides valuable information, either at the survey planning stage or for the interpretation.