Evidence for a warmer period during the 12th and 13th centuries AD from chironomid assemblages in Southampton Island, Nunavut, Canada

This study presents the Late-Holocene evolution of a northern Southampton Island (Nunavut, Canada) lake, using fossil chironomids supported by sedimentological evidences (XRF, grain size and CNS). All proxies revealed a relatively stable environment during the last millennium with short-lived events driving changes in the entire lake ecosystem. The chironomid-based paleotemperatures revealed variations of significant amplitude coincident with changes in the sediment density and chemical composition of the core. Higher temperature intervals were generally correlated to lower sediment density with higher chironomid concentration and diversity. Higher temperatures were recorded from cal yr AD 1160 to AD 1360, which may correspond to the Medieval Warm Period. Between cal yr AD 1360 and AD 1700, lower temperatures were probably related to a Little Ice Age event. This study presents new information on the timing of known climatic events which will refine our knowledge of the paleoclimate and climatic models of the Foxe Basin region. It also provides a new framework for the evolution of such freshwater ecosystems under the “Anthropocene” and underlines the importance of including sedimentological proxies when interpreting chironomid remains as this combined approach provides an extended overview of the past hydrological and geochemical changes and their impacts on lake biota.     

The junction of Fensch and Moselle rivers,France; mineralogy and composition of river materials

The Moselle river flows in the north-east of France, from Vosges Mountains to neighboring countries Luxembourg and Germany. One of its tributaries, the Fensch river, drains a highly industrialized watershed, strongly impacted by mining, smelting and surfacing activities. The objective of this work, part of a general research program on Moselle watershed (Zone Atelier Moselle) was to assess the impact of the polluted Fensch river on the global quality of the Moselle river. For that purpose, water, sediments and suspended particulate matter were sampled in both rivers, upstream and downstream the junction. Four main sampling campaigns were carried out, in winter during a flood event and in spring at low water level. On a first step, mineralogical analyses (XRD and FTIR) and chemical analyses (ICP-MS, ICP-AES), were performed on sediments, suspended particulate matters and filtered waters. Major and trace elements concentrations were obtained on two different granulometric fractions (0–2 mm and 0–50 μm) revealing the enrichment in heavy metals of fine particles. From one collecting campaign to another, seasonal variations could be evidenced on suspended matter composition even though major minerals (calcite, quartz and kaolinite) were always present. Furthermore, spatial variations were evidenced for Fensch and Moselle downstream sediments. Thus, very fine-grained sediments, poorly crystallized, displaying at the same time higher metal concentrations and higher organic matter content than in Fensch river material, were collected downstream, in a low hydrodynamic conditions zone, assumed as a preferential sedimentary zone or even as a placer. Strong correlations could be revealed between iron content and contaminant concentrations, confirming the origin of polluted material.     

A simple method for calculating growth rates of petroleum hydrocarbon plumes

Consumption of aquifer Fe(III) during biodegradation of ground water contaminants may result in expansion of a contaminant plume, changing the outlook for monitored natural attenuation. Data from two research sites contaminated with petroleum hydrocarbons show that toluene and xylenes degrade under methanogenic conditions, but the benzene and ethylbenzene plumes grow as aquifer Fe(III) supplies are depleted. By considering a one-dimensional reaction front in a constant unidirectional flow field, it is possible to derive a simple expression for the growth rate of a benzene plume. The method balances the mass flux of benzene with the Fe(III) content of the aquifer, assuming that the biodegradation reaction is instantaneous. The resulting expression shows that the benzene front migration is retarded relative to the ground water velocity by a factor that depends on the concentrations of hydrocarbon and bioavailable Fe(III). The method provides good agreement with benzene plumes at a crude oil study site in Minnesota and a gasoline site in South Carolina. Compared to the South Carolina site, the Minnesota site has 25% higher benzene flux but eight times the Fe(III), leading to about one-sixth the expansion rate. Although it was developed for benzene, toluene, ethylbenzene, and xylenes, the growth-rate estimation method may have applications to contaminant plumes from other persistent contaminant sources.     

A Syringe and Cartridge Method for Down-Hole Sampling for Trace Organics in Ground Water

A newly developed technique which allows the down-hole sampling and subsequent analysis of ground water for trace organic contaminants was tested during an investigation of contaminant migration at an inactive landfill site in Burlington, Ontario, Canada. The sampling device, which is lowered down piezometers with a tube, consists of a small cylindrical cartridge of sorbent material attached to a syringe. Vacuum or pressure applied at the surface controls the movement of the plunger in the syringe. The volume of the syringe determines the volume of sample water that passes through the cartridge. The cartridge is removed from the syringe at the surface. One cartridge is used for each sampling; the syringe is reusable. The residual water in the cartridge is removed in the laboratory, and the cartridge is desorbed to a fused silica capillary column for analysis by gas chromatography (GC). The analyses discussed here were performed on a GC/mass spectrometer/data system (GC/MS/DS). Of the many organic compounds that were identified in the samples, three compounds were clearly landfill-related: 1,1,1-trichloroethane, chlorobenzene, and para-dichlorobenzene. The three compounds were found at levels substantially above blank levels in 9, 5, and 5 piezometers, respectively. The average concentrations were 14., 5.3, and 0.88μg/1 (ppb), respectively. The pooled coefficients of variation for the analyses for the three compounds were 27., 6.9, and 6.4%, respectively. The volatility of 1,1,1-trichloroethane was probably the cause of the greater variability in its analytical data. The main advantages of the technique over most conventional sampling methods include: (1) down-hole sampling in a manner which minimizes the potential for volatilization losses; (2) avoidance of passage of the sample through long sections of tubing that may contaminate the sample or cause adsorptive losses; (3) convenience of sample handling, storage, and shipping; and (4) high sensitivity.     

Incremental growth of normal faults: Insights from a laser-equipped analog experiment

We conducted a laser-equipped analog experiment aimed at quasi-continuously monitoring the growth of a dense population of normal faults in homogeneous conditions. To further understand the way geological faults progressively gain in slip and length as they accumulate more strain, we measured with great precision the incremental slip and length changes that the analog faults sustain as they grow. These measurements show that the analog faults share common features with the natural ones. In particular, during their growth, the faults develop and maintain cumulative slip profiles that are generally triangular and asymmetric. The growth takes place through two distinct phases: an initial, short period of rapid lateral lengthening, followed by a longer phase of slip accumulation with little or no lengthening. The incremental slip is found to be highly variable in both space (along the faults) and time, resulting in variable slip rates. In particular, ‘short- and long-term’ slip rates are markedly different. We also find that slip measurements at local points on fault traces do not contain clear information on the slip increment repeat mode. Finally, while the fault growth process is highly heterogeneous when considered at the scale of a few slip events, it appears homogeneous and self-similar at longer time scales which integrate many slip increments. This is likely to be the result of a feedback between stress heterogeneities and slip development. The long-term scale homogeneity also implies that the long-term faulting process is primarily insensitive to the short-term heterogeneities that are rapidly smoothed or redistributed. We propose a new conceptual scenario of fault growth that integrates the above observations and we suggest that faults grow in a bimodal way as a result of a self-driven and self-sustaining process.     

Instability structures, synsedimentary faults and turbidites, witnesses of a Liassic seismotectonic activity in the Dauphiné Zone (French Alps): A case example in the Lower Pliensbachian at Saint-Michel-en-Beaumont

Instability structures, synsedimentary faults and turbidites have been studied in the Lower Pliensbachian succession of Saint-Michel-en-Beaumont, belonging to the Taillefer block, an ancient half-graben emplaced during the Liassic Tethyan rifting. Geometrical and mechanical analyses demonstrate that the instability structures occurred thanks to movements along spineless synsedimentary normal faults, when the turbiditic and limestone layers were already case-hardened and partly fractured by tension gashes even when the mudstones were still unlithified. Both the tension gashes and the synsedimentary faults are homogeneous in strike with the major regional faults and are in good agreement with the regional direction of extension for this period. The characters of the turbiditic beds, with erosive base, graded bedding, and incomplete Bouma sequence, are in favour of a seismic origin. Instability structures, spineless synsedimentary faults and turbiditic inflows are thus considered as seismites and interpreted as the result of high seismicity periods including some events with M > 5 in the general extensive ambiance of the Liassic Tethyan rifting. The analysis of the geometrical relationships between all these sedimentary features allows to distinguish the successive stage of occurrence of an instability structure, from the sedimentation of alternating marls and limestones, and sudden turbiditic inflows, then early case-hardening of the turbidites, until the important seismotectonic event generating the spineless normal faults, themselves triggering the fall of indurated blocks and locally the forming of breccias. The Ornon Fault, which constitutes the border of the Taillefer block, 15 km eastward, played a major role during the Liassic sedimentation and may represent the major seismic fault related to the seismites occurrence in the Beaumont basin.     

Petrography of alluvial sands as a past and present environmental indicator: Case of the Loire River (France)

Four sample sets of the Upper and Middle Loire river sands were analyzed in order to study the impact of natural and anthropogenic factors on their petrographic composition in space (on an 800 km stretch) and time. Composition was determined by modal analysis of three sand-size fractions using a polarizing optical microscope and calculated for each sample (“standard sand” = Sst). The watershed is composed mainly of endogenic (Massif Central) and sedimentary (southern Parisian Basin) rocks. B-set sands collected in channels for different water flows in 1996 show that Sst compositions vary by only 5 %. Present-day sands in the Upper Loire and Middle Loire have very high petrographic immaturity comparing to others worldwide fluvial sands, although bio-climatic conditions favor sand maturation by source-rock weathering in the watershed. This shows the strong impact of the Massif Central on sediment yield due to relief rejuvenation as a consequence of the formation of the Alps during the Quaternary. Fluvial sands stored during the Weichselian and the Holocene in the Middle Loire floodplain, although partly weathered since their deposition, show higher inputs from the endogenic rocks of the Massif Central than present-day deposits. This can be explained by Weichselian periglacial conditions and the development of crop farming since the Neolithic, which favored mechanical erosion, particularly in the Massif Central which is characterized by a cold, humid climate and steep slopes. The upstream-downstream change in the composition of presently deposited sand is low in the diked area. It shows however that basalt and some heavy mineral grains are vulnerable to abrasion during transport and indicates a marked sediment yield from ancient sediment stored in the floodplain. This is in line with the high incision of the river bed over the last 150 years partly due to dam construction and aggregate mining.