Spatiotemporal changes in cadmium contamination in the Seine estuary (France)

Cadmium (Cd) is among the major contaminants in the Seine estuary. In the biota, the RNO (Réseau National d’Observation, the French Mussel-Watch) has shown that Cd concentrations in mussels living at the mouth of the estuary are related to changes in inputs to this area of phosphogypsum, a calcium sulphate that is a by-product of the phosphoric acid naturally enriched with Cd. In the water column, Cd concentrations at several key estuary sites show a very marked trend toward decreased contamination in the particles as well as in the dissolved phase. The behavior of Cd in the estuary has been studied between 1991 and 1998 in the framework of the scientific program Seine-Aval. This program has highlighted punctual Cd inputs in the estuarine water column. The partition of Cd between the dissolved and the particulate phase, previously described in various estuaries, is characterized by an intense phenomenon of solubilization in the mixing zone freshwater-seawater, but the colloidal Cd fraction remains low along the whole salinity gradient, about 5% to 10% of the apparent dissolved fraction. Although the decrease of inputs induced a fall of Cd concentrations in the water column, laboratory experiments show that the estuarine particles are far from being exhausted in Cd. Despite continuous efforts to reduce the urban and industrial inputs into the estuarine and coastal waters, the Seine estuary still remains very contaminated by Cd.     

Volume contents

Volume Contents

Volume contents     

Joint NANCAY RADIOHELIOGRAPH AND LASCO OBSERVATIONS OF CORONAL MASS EJECTIONS – II. The 9 July 1996 Event

The development of a coronal mass ejection on 9 July 1996 has been analyzed by comparing the observations of the LASCO/SOHO coronagraphs with those of the Nancay radioheliograph. The spatial and temporal evolution of the associated radioburst is complex and involves a long-duration continuum. The analysis of the time sequence of the radio continuum reveals the existence of distinct phases associated with distinct reconnection processes and magnetic restructuring of the corona. Electrons are accelerated in association with these reconnection processes. An excellent spatial association is found between the position and extension of the radio source and the CME seen by LASCO. Furthermore, it is shown that the topology and evolution of the source of the radio continuum involve successive interactions between two systems of loops. These successive interactions lead to magnetic reconnection, then to a large scale coronal restructuring. Thus electrons of coronal origin may have access to the interplanetary medium in a large range of heliographic latitudes as revealed by the Ulysses observations.     

The Interaction Between Coronal Mass Ejections and Streamers: A Statistical View over 15 Years (1996 – 2010)

We report on the statistical analysis of the interaction between coronal mass ejections (CMEs) and streamers based on 15 years (from 1996 to 2010 inclusive) of observation of the solar corona with the LASCO-C2 coronagraph. We used synoptic maps and improved the method of analysis of past investigations by implementing an automatic detection of both CMEs and streamers. We identified five categories of interaction based on photometric and geometric variations between the pre- and post-CME streamers: “brightening”, “dimming”, “emergence”, “disappearance”, and “deviation”. A sixth category, “no change”, included all cases where none of the above variations is observed. A “global set” of 21?242 CMEs was considered as well as a subset of the 10 % brightest CMEs (denoted “top-ten”) and three typical periods of solar activity: minimum, intermediate, and maximum. We found that about half of the global population of CMEs are not associated with streamers, whereas 93 % of the 10 % brightest CMEs are associated. When there is a CME-streamer association, approximately 95 % of the streamers experience a change, either geometric or radiometric. The “no change” category therefore amounts to approximately 5 %, but this percentage varies from 1?–?2 % during minimum to 7?–?8 % during intermediate periods of activity; values of 3?–?5 % are recorded during maximum. Emergences and disappearances of streamers are not dominant processes; they constitute 16?–?17 % of the global set and 23 % (emergence) and 28 % (disappearance) of the “top-ten” set. Streamer deviations are observed for 57 % and 70 % of, respectively, the global set and “top-ten” CMEs. The cases of dimming and brightening are roughly equally present and each case constitutes approximately 30?–?35 % of either set, global or “top-ten”.     

Calibration of the Soho/Lasco C3 White Light Coronagraph

We present a detailed review of the calibration of the LASCO C3 coronagraph on the SOHO satellite. Most of the calibration has been in place since early in the mission and has been utilized to varying degrees as required by specific analysis efforts. However, using observational data from the nearly decade-long database of LASCO images, we have re-evaluated and improved many aspects of the calibration. This includes the photometric calibration, vignetting function, geometric distortion, stray light, and exposure and observation times. Using this comprehensive set of corrections we have generated and made available a set of calibrated coronal images along with a set of periodic background images to ease the accessibility and use of the LASCO database. Deceased     

A simple method for calculating growth rates of petroleum hydrocarbon plumes

Consumption of aquifer Fe(III) during biodegradation of ground water contaminants may result in expansion of a contaminant plume, changing the outlook for monitored natural attenuation. Data from two research sites contaminated with petroleum hydrocarbons show that toluene and xylenes degrade under methanogenic conditions, but the benzene and ethylbenzene plumes grow as aquifer Fe(III) supplies are depleted. By considering a one-dimensional reaction front in a constant unidirectional flow field, it is possible to derive a simple expression for the growth rate of a benzene plume. The method balances the mass flux of benzene with the Fe(III) content of the aquifer, assuming that the biodegradation reaction is instantaneous. The resulting expression shows that the benzene front migration is retarded relative to the ground water velocity by a factor that depends on the concentrations of hydrocarbon and bioavailable Fe(III). The method provides good agreement with benzene plumes at a crude oil study site in Minnesota and a gasoline site in South Carolina. Compared to the South Carolina site, the Minnesota site has 25% higher benzene flux but eight times the Fe(III), leading to about one-sixth the expansion rate. Although it was developed for benzene, toluene, ethylbenzene, and xylenes, the growth-rate estimation method may have applications to contaminant plumes from other persistent contaminant sources.     

Outgassing-induced effects in the rotational state of comet 67P/Churyumov—Gerasimenko during the Rosetta mission

The new target of the Rosetta mission is comet 67P/Churyumov-Gerasimenko (hereafter 67P/C-G). In order to support the planning of the mission, in particular the strategy during the mapping and landing phases, we have performed numerical simulations of the rotational evolution of a comet in the orbit of 67P/C-G. In these simulations, the currently known observational constraints have been taken into account and a large set of initial conditions were considered. For most of the simulations, we observe that the sublimation-induced torques produce significant changes in the rotational parameters of a 67P/C-G-like comet. Typical rates of change for the spin period from the rendezvous up to the end of the nominal mission range from 0.001 to depending on different circumstances as described in the text. At perihelion, rates of change of the orientation of the angular momentum vector amount to about 0.01-. These simulations suggest that a specific strategy should be defined in order to monitor likely variations of the rotational parameters. As an example we show a possible optimized schedule for observations with the OSIRIS instrument to determine the rotational parameters of comet 67P/C-G and their possible evolution.