Fluid flow in cataclastic thrust fault zones in sandstones, Sub-Andean Zone, southern Bolivia

The Bolivian Sub-Andean Zone (SAZ) corresponds to a Neogene thrust system that affects an about 10-km thick Palaeozoic to Neogene siliciclastic succession. The analysis of macro and microstructures and cement distribution in thrust fault zones shows that they are sealed by quartz at depths >3 km, due to local silica transfer by pressure-solution/precipitation activated at temperatures >70–90 °C. At shallower depths, faults have remained open and could be preferential drains for lateral flow of carbonate-bearing fluids, as shown by the occurrence of carbonate cements in fractures and their host-sandstone. Due to decreasing burial, resulting from foothill erosion during fault activity, critically buried fault segments can be affected by non-quartz-sealed structures that post-date initial quartz-sealed structures. The integration of textural, fluid inclusion and isotopic data shows that carbonates precipitated at shallow depth (<3 km), low temperature (<80 °C) and relatively late during the thrusting history. Isotopic data also show that precipitation occurred from the mixing of gravity-driven meteoric water with deeper formation water bearing carbonate carbon derived from the maturation of hydrocarbon source rocks (Silurian and Devonian shales). The combined microstructural and isotopic analyses indicate that: (i) fluid flow in fault zones often occurred with successive pulses derived from different or evolving sources and probably related to episodic fault activity, and (ii) at a large-scale, the faults have a low transverse permeability and they separate thrust sheets with different fluid histories.     

Assessing green gentrification in historically disenfranchised neighborhoods: a longitudinal and spatial analysis of Barcelona

To date, little is known about the extent to which the creation of municipal green spaces over an entire city addresses social or racial inequalities in the distribution of environmental amenities – or whether such an agenda creates contributes to green gentrification. In this study, we evaluate the effects of creating 18 green spaces in socially vulnerable neighborhoods of Barcelona during the 1990s and early 2000s. We examined the evolution over time of six socio-demographic gentrification indicators in the areas close to green spaces in comparison with the entire districts. Our results indicate that new parks in the old town and formerly industrialized neighborhoods seem to have experienced green gentrification. In contrast, most economically depressed areas and working-class neighborhoods with less desirable housing stock and more isolated from the city center gained vulnerable residents as they became greener, indicating a possible redistribution and greater concentration of vulnerable residents through the city.     

Holocene environmental change at Lake Njulla (999 m a.s.l.), northern Sweden: a comparison with four small nearby lakes alongan altitudinal gradient

We assess Holocene environmental change at alpine Lake Njulla(68°22N, 18°42E, 999 m a.s.l.) innorthernmost Sweden using sedimentary remains of chironomid head capsules anddiatoms. We apply regional calibration sets to quantitatively reconstruct meanJuly air temperature (using chironomids and diatoms) and lake-water pH(using diatoms). Both chironomids and diatoms infer highest temperatures(1.7–2.3°C above present-day estimates, includinga correction for glacio-isostatic land up-lift by0.6°C) during the early Holocene (c.9,500–8,500 cal. yrs BP). Diatoms suggest a decreasing lake-waterpH trend (c. 0.6 pH units) since the early Holocene. Usingdetrended canonical correspondence analysis (DCCA), we compare the Holocenedevelopment of diatom communities in Lake Njulla with four other nearby lakes(Lake 850, Lake Tibetanus, Vuoskkujávri, Vuolep Njakajaure) locatedalong an altitudinal gradient. All five lakes show similar initial DCCA scoresafter deglaciation, suggesting that similar environmental processes such ashigh erosion rates and low light availability associated with high summertemperature appear to have regulated the diatom community, favouring highabundances of Fragilaria species. Subsequently, the diatomassemblages develop in a directional manner, but timing and scale ofdevelopment differ substantially between lakes. This is attributed primarily todifferences in the local geology, which is controlling the lake-waterpH. Imposed on the basic geological setting, site-specific processessuch as vegetation development, climate, hydrological setting andin-lake processes appear to control lake development in northernSweden.     

From spatial-continuous electrical resistivity measurements to the soil hydraulic functioning at the field scale

The aim of this article is to present a strategy to interpret the hydraulic functioning of a small field area by using measurements of the soil electrical resistivity. The spatial soil electrical resistivity was recorded at a high resolution on a 2 ha area by the MultiContinous Electrical Profiling (MuCEP) device at two dates. These apparent electrical resistivity measurements were firstly interpreted in terms of local electrical resistivity by 1D inverse modelling to estimate the real resistivity of the soil. These interpreted electrical resistivity data were then transformed into soil water content values and soil water potential values by the use of independent punctual data of water content and the use of the water retention curve determined by laboratory data. Our analysis has permitted us to describe the spatial variability and temporal evolution of the hydraulic functioning at high resolution from electrical resistivity data. The interpretation of the water content and matric potential maps demonstrated that some soil hydraulic processes, such as lateral overland flow, can occur in the studied zone. They would never have been detected by local measurements of soil characteristics or by the use of the soil map.     

Role of permeability barriers in alluvial hydromorphic palaeosols: The Eocene Pondaung Formation,Myanmar

This study examines the lateral distribution of hydromorphy in the fine‐grained alluvial deposits of the Eocene Pondaung Formation, central Myanmar. Through detailed outcrop analysis and using a combined sedimentological and pedological approach, this study proposes a reconstruction of Pondaung overbank floodplain palaeoenvironments. The variations of hydromorphic features in the different overbank sub‐environments are then discussed and used to build a model of hydromorphic variability in alluvial deposits. Two main architectural associations with distinctive lithofacies and pedogenic features were identified, corresponding to different sub‐environments: heterolithic deposits and extensive mudstone successions. The heterolithic deposits display variegated fine‐grained lithofacies and contain poorly developed palaeosols with gley and vertic features, which are interpreted to reflect a seasonal wetlands landscape, developed in actively aggrading avulsion belts. Extensive mudstone successions with Vertisols that locally exhibit mukkara‐style pseudogley features are interpreted to represent a distal open‐forested environment. The palaeosols of both sub‐environments display dense local hydromorphic variations they are also characterized by a gradual shift from gley‐dominated to pseudogley‐dominated features with increasing distance from the avulsion belt. The clay‐dominated lithology of the floodplain parent material, which forms numerous subsurface permeability barriers, is shown to have acted as a fundamental control in limiting water‐table dynamics in coarse‐grained parts of the succession, thereby favouring hydromorphic variability. Palaeosol sequences of the Pondaung Formation contrast with the soil‐landscape associations described in other studies and provide an alternative model with which to account for the hydromorphic variability in poorly drained, alluvial soils. The model proposed as an outcome of this study demonstrates that hydromorphic variations can be dramatic in floodplains where permeability barriers are numerous. Further, the model stresses the importance of undertaking detailed lateral palaeosol analyses prior to making interpretations regarding hydromorphic variability.     

Interferometric calibrations and astronomical calibrators

This chapter gives some indications on the selection of suitable astronomical calibrators for interferometric observations. After an introduction to interferometric calibrations, we will focus on the criteria, steps and tools developed by ESO to prepare VLTI observations and to select calibrators. Although the tools described here are focused on VLTI, the problem of astronomical calibrators is the same for the other interferometers and can be approached in the same way.     

Evaluating the sulfur isotopic composition of biodegraded petroleum: The case of the Western Canada Sedimentary Basin

The sulfur isotopic composition (δ³⁴S) of petroleum is believed to be affected mainly by sulfur incorporation reactions into the sedimentary organic matter during the early diagenesis. However, secondary processes could affect the original δ³⁴S of oil under the effect of thermal maturity or of the microbial activity of biodegraded reservoirs. In this study, the different processes that may affect the δ³⁴S of in-reservoir oils were assessed based on the sulfur content and isotopes of a series of oil and core samples coming from various reservoirs of the Lower Cretaceous Mannville Group, Western Canada Sedimentary Basin (WCSB). Based on the molecular study, these samples appear to have reached various levels of maturity and biodegradation, ranging from 0 to 6.5 on the biodegradation scale of Peters and Moldowan. In addition, mixing of organic matter coming from different source rocks was identified based on the comparison with extensive correlation studies performed in the WCSB.Investigation of the δ³⁴S shows a trend that seems a priori correlated to the level of biodegradation. However, a careful interpretation of molecular and sulfur isotope data leads to the conclusion that the observed δ³⁴S variations have rather to be ascribed to contributions of oils generated by various source rocks. Alternatively, variations of δ³⁴S could neither be related to maturity differences nor to kinetic effects during organic sulfur compounds biodegradation. In the case of some specific core samples showing a common origin based on biomarker study, δ³⁴S variations might not be related to different sources but to secondary sulfur incorporation/exchange processes occurring within the reservoir. These processes would involve reduced sulfur species from bacterial sulfate reduction formed in situ or migrated into Mannville reservoirs. This hypothesis is supported by laboratory experiments showing sulfur exchange/incorporation under plausible conditions for shallow reservoirs.     

Dust in Hydrogen-Poor Stellar Winds, from Theory to Observations

We review the nature of dust in hydrogen-deficient stellar winds, in particular cool, carbon-rich Wolf-Rayet (WC) stars, and present new observations of WC objects taken with the Short Wavelength Spectrometer on board of the ISO satellite. Predictions from theoretical models of grain precursor formation are also presented and future directions in both observational and theoretical studies are outlined. This revised version was published online in September 2006 with corrections to the Cover Date.     

Effect of the environment on the hydrochemical characteristics of an alluvial aquifer following an exceptional multiyear drought (Mediterranean seashore,herault, France): Part II— Climatology and agronomy

The hydrochemical evolution of an alluvial groundwater located along the Mediterranean seashore is analyzed with respect to its agricultural and climatic environment, including degree of saturation of the soil; types of cultures, chemical fertilizers and phytosanitary treatments; selective irrigations of the cultivated areas; precipitations. It is shown that the environmental effect on the groundwater's vulnerability depends on two groups of factors:

Numerical modelling of direct current electrical resistivity for the characterisation of cracks in soils

Fractures or cracks in rocks and soils are thin planar features of high resistivity, embedded in a more conductive bulk volume. In soils, several processes, particularly swelling and shrinkage of clays, result in cracks and can regenerate macroporosity. Their detection and the assessment of their evolution necessitate the use of non-invasive techniques. Although cracks have a major influence on the electrical resistivity of bulk material their complete geometrical characterisation achieved through the use of electrical resistivity measurements remains difficult due to the lack of appropriate inversion models. An inversion model based on the method of moments (MoM) has been developed, and is presented here. Direct simulations demonstrate the model's ability to reconstruct real experimental data. The influence of various object parameters on the model's accuracy was tested, showing that the model is sensitive to all the geometric characteristics of a crack. The inversion of both simulated and experimental data has demonstrated the model's ability to calculate the initial position, width and depth of several different cracks.