Mercury flux to estuarine sediments, derived from Pb-210 and Cs-137 geochronologies (Guaratuba Bay, Brazil)

A sediment core from Guaratuba Bay was used to indicate possible Hg modifications to this coastal environment brought about by growing agricultural activity. Sedimentation rates were estimated to be 6.1 mm/year and 5.2 mm/year through 210Pb and 137Cs geochronologies, respectively. Mercury concentrations and organic matter ratios in the surface layers are greater than in the older sediments, supporting the hypothesis of anthropogenic enrichment. Results show that the Hg flux has raised more than twofold during the second half of the 20th century. These results point to the need for further studies to substantiate the hypothesis of anthropogenic enrichment and to quantify point sources of Hg to this estuary.     

Fast water infiltration: a mechanism for fracture formation during land subsidence

A mechanism for fracture generation and for triggering land subsidence is presented. Infiltration through a pre-existing fracture zone into a two-layered system, as well as the deformation of unconsolidated sediments on the land surface, was numerically investigated. The numerical simulation of infiltration is based on a two-phase flow-model concept for porous media, and for the deformation, it is based on a Mohr-Coulomb model concept. Different studies with variations of the fracture parameter and infiltration conditions have been carried out. The infiltration results show that fast infiltration in a partially saturated aquifer leads to land subsidence, extension of pre-existing fractured zones and the generation of new cracks. If the water column is only on the fracture, the clay layer acts like a barrier and inhibits the infiltration through the fracture. If the water column covers the entire surface, the barrier effect is overcome; the infiltration intensity depends on the height of the water column, the fracture permeability and the fracture width. The deformation results show that a strong rainfall event of 2 h leads to deformations that are about 30 % of the vertical and 70 % of the horizontal annual land-subsidence rates.     

Plastic Pollution at a Sea Turtle Conservation Area in NE Brazil: Contrasting Developed and Undeveloped Beaches

Sea turtles are highly susceptible to plastic ingestion and entanglement. Beach debris were surveyed along the most important sea turtle nesting beaches in Brazil (Costa dos Coqueiros, Bahia State). No significant differences among developed and undeveloped beaches were observed in terms of total number of items. Local sources (tourism activities) represented 70% of debris on developed beaches, where cigarette butts, straws, paper fragments, soft plastic fragments, and food packaging were the most abundant items. Non-local sources (domestic and fishing activities) accounted for about 70% of debris on undeveloped beaches, where the most abundant items were rigid plastic fragments, ropes, soft plastic fragments, caps, and polystyrene. The projected surface area of beach debris did not vary among developed and undeveloped beaches. Overseas containers accounted for about 25% of regional plastic pollution, implying that international pollution prevention agreements are not being respected off the Brazilian coast.     

Role of minerals in the thermal alteration of organic matter—I: Generation of gases and condensates under dry condition

Pyrolysis experiments were carried out on Monterey formation kerogen and bitumen and Green River formation kerogen (Type II and I, respectively), in the presence and absence of montmorillonite, illite and calcite at 200 and 300°C for 2–2000 hours. The pyrolysis products were identified and quantified and the results of the measurements on the gas and condensate range are reported here.A significant catalytic effect was observed for the pyrolysis of kerogen with montmorillonite, whereas small or no effects were observed with illite and calcite, respectively. Catalytic activity was evident by the production of up to five times higher C₁–C₆ hydrocarbons for kerogen with montmorillonite than for kerogen alone, and by the dominance of branched hydrocarbons in the C₄–C₆ range (up to 90% of the total amount at any single carbon number). This latter effect in the presence of montmorillonite is attributed to cracking via a carbonium-ion [carbocation] intermediate which forms on the acidic sites of the clay. No catalytic effect, however, was observed for generation of methane and C₂ hydrocarbons which form by thermal cracking. The catalysis of montmorillonite was significantly greater during pyrolysis of bitumen than for kerogen, which may point to the importance of the early formed bitumen as an intermediate in the production of low molecular weight hydrocarbons. Catalysis by minerals was also observed for the production of carbon dioxide.These results stress the importance of the mineral matrix in determining the type and amount of gases and condensates forming from the associated organic matter under thermal stress. The literature contains examples of gas distributions in the geologic column which can be accounted for by selective mineral catalysis, mainly during early stages of organic matter maturation.     

To Move or not to Move: Community Members’ Reaction to Surface Mining Activities in the Upper West Region of Ghana

Abstract

Despite the impact of mining-induced environmental change on community livability, we know little about how disparities in knowledge of health risks associated with mining influence residents’ response, especially in an already environmentally stressed context. Guided by theoretical insights from solastalgia, we examined residents’ decision to relocate due to increasing gold mining activities in the fragile Northern Savannah Ecological Zone of Ghana. Fitting complementary log-log regression models to cross-sectional data from the Upper West Region (UWR) of Ghana, we found that residents with limited knowledge of potential health impacts of mining and those who believe mining activities were not meeting environmental standards were more likely to consider relocating. Given the centrality of land in community health and wellbeing in the UWR, Ghana’s mining guidelines should promote local participation in the regulation of mining activities and guarantee the rights of indigenes to livable native lands.     

Comparisons of Snowfall Measurements in Complex Terrain Made During the 2010 Winter Olympics in Vancouver

Solid precipitation (SP) intensity ( $ R_{\text{s}} $ ) using four automatic gauges, Pluvio, PARSIVEL (PArticle, SIze and VELocity), FD12P and POSS, and radar reflectivity factor ( $ Z $ ) using the POSS and PARSIVEL were measured at a naturally sheltered station (VOA) located at high level (1,640 m) on the Whistler Mountain in British Colombia, Canada. The R _s and other standard meteorological parameters were collected from March 2009, and from November 2009, to February 2010. The wind speed (ws) measured during this period ranged from 0 to 4.5 ms^?1, with a mean value of 0.5 ms^?1. The temperature varied from 4 to ?17 °C. The SP amount reported by the PARSIVEL was higher than that reported by the Pluvio by more than a factor of 2, while the FD12P and POSS measured relatively smaller amounts, but much closer to that reported by the Pluvio and manual measurements. The dependence of R _s from the PARSIVEL on wind speed was examined, but no significant dependence was found. The PARSIVEL’s precipitation retrieval algorithm was modified and tested using three different snow density size relationships (ρ _s–D) reported in literature. It was found that after modification of the algorithm, the derived R _s amounts using the raw data agreed reasonably well with the Pluvio. Statistical analysis shows that more than 95 % of $ Z_{{h_{\text{poss}} }} $ data measured by POSS appears to correlates well with the reflectivity factors determined using the three ρ _s–D relationships. The automated Pluvio accumulation and manually determined daily SP amount (SPm) measured during five winter months were compared. The mean ratio (MR) and the mean difference (MD), and the correlation coefficient (r) calculated using the data collected using the two methods, were found to be 0.96, 0.4 and 0.6 respectively, indicating respectable agreement between these two methods, with only the Pluvio underestimating the amount by about 4 %.     

Mid-Mountain Clouds at Whistler During the Vancouver 2010 Winter Olympics and Paralympics

A comprehensive study of mid-mountain clouds and their impacts on the Vancouver 2010 Winter Olympics and Paralympics is presented. Mid-mountain clouds were frequently present on the Whistler alpine venue, as identified in an extensive archive of webcam images over a 45-day period from February 5 to March 21, 2010. These clouds posed serious forecast challenges and had significant impacts on some Olympic and Paralympic alpine skiing competitions. Under fair weather conditions, a diurnal upslope (anabatic) flow can work in concert with a diurnal temperature inversion aloft to produce a localized phenomenon known as “Harvey’s Cloud” at Whistler. Two detailed case studies in this paper suggest that mid-mountain clouds can also develop in the area as a result of a moist valley flow interacting with a downslope flow descending from the mountaintop. A southerly inflow through the Sea-to-Sky corridor can be channeled by the local topography into a westerly upslope flow toward Whistler Mountain, resulting in orographic clouds on the alpine venue. Under favorable circumstances, these clouds are trapped to the mid-mountain zone by the leeward subsidence of an elevated southerly flow. The presence of the downslope subsidence was manifested by a distinguished dry layer observed on the top of the mid-mountain clouds in both cases. It is the subsidence-induced adiabatic warming that imposes a strong buoyant suppression to trap the mid-mountain cloud. On the other hand, the subsidence-induced dry layer has the potential to trigger evaporative instability to periodically breakup the mid-mountain cloud.