Types of Pyrophyllite Deposits in Foldbelts

Abstract. Pyrophyllite deposits can be divided into five types on the basis of geology and genesis. The first two types are associated with hydrothermally altered rocks in felsic and intermediate volcanogenic suites. They are characterized by their metasomatites and their subsequent mineralogic transformations under varying volcanic conditions. The third type includes deposits and occurrences of metamorphic-metasomatic genesis, which is caused by transformations of terrigenous-sedimentary interbeds in felsic volcanics under greenschist facies conditions. The fourth type is associated with low and mid-temperature stages of hydrothermal vein formation at the limits of volcanogenic and metamorphic strata. The fifth type comprises pyrophyllite occurrences in weathering crusts on metamorphic strata and metasomatite.
The formation conditions and distribution of raw pyrophyllite deposits were influenced by the geodynamic situations and geochemical conditions, such as character of tectonic dislocations, volcanism and chemical composition of hydrothermal solutions.     

A multiproxy environmental investigation of Holocene wood from a submerged conifer forest in Lake Huron, USA

Remains of a Holocene drowned forest in southern Lake Huron discovered in 12.5 m of water (164 m above sea level), 4.5 km east of Lexington, Michigan USA (Sanilac site), provided wood to investigate environment and lake history using several proxies. Macrofossil evidence indicates a forest comprised primarily of conifers equivalent to the modern “rich conifer swamp” community, despite generally low regional abundance of these species in pollen records. Ages range from 7095 ± 50 to 6420 ± 70 ¹⁴C yr BP, but the clustering of stump dates and the development of 2 floating tree-ring chronologies suggest a briefer forest interval of no more than c. 400 years. Dendrochronological analysis indicates an environment with high inter-annual climate variability. Stable-carbon isotope composition falls within the range of modern trees from this region, but the stable-oxygen composition is consistent with warmer conditions than today. Both our tree-ring and isotope data provide support for a warmer environment in this region, consistent with a mid-Holocene thermal maximum. This drowned forest also provides a dated elevation in the Nipissing transgression at about 6420 ¹⁴C yr BP (7350 cal yr BP) in the southern Lake Huron basin, a few hundred years before reopening of the St. Clair River drainage.     

Economic,institutional and technological uncertainties of emissions trading—a system dynamics modeling approach

System dynamics models are employed for analyzing the impact of different uncertainties on carbon emission trading–both on national and business levels. Economic, institutional and technological uncertainties significantly influence any country's benefits from emission permit trading. If a country participates in trading on the international market then the possible price range becomes the source of additional uncertainty. In the case of business investment decisions for implementing resource‐saving technology, our system dynamics model shows that the first‐mover investor will get significantly fewer advantages than his followers, which leads to delay in primary investment to the sector.     

Mineralogy, geochemistry and stratigraphy of the Maslovsky Pt–Cu–Ni sulfide deposit, Noril’sk Region, Russia

We report new data on the stratigraphy, mineralogy and geochemistry of the rocks and ores of the Maslovsky Pt–Cu–Ni sulfide deposit which is thought to be the southwestern extension of the Noril’sk 1 intrusion. Variations in the Ta/Nb ratio of the gabbro-dolerites hosting the sulfide mineralization and the compositions of their pyroxene and olivine indicate that these rocks were produced by two discrete magmatic pulses, which gave rise to the Northern and Southern Maslovsky intrusions that together host the Maslovsky deposit. The Northern intrusion is located inside the Tungusska sandstones and basalt of the Ivakinsky Formation. The Southern intrusion cuts through all of the lower units of the Siberian Trap tuff-lavas, including the Lower Nadezhdinsky Formation; demonstrating that the ore-bearing intrusions of the Noril’sk Complex post-date that unit. Rocks in both intrusions have low TiO₂ and elevated MgO contents (average mean TiO₂ <1 and MgO?=?12?wt.%) that are more primitive than the lavas of the Upper Formations of the Siberian Traps which suggests that the ore-bearing intrusions result from a separate magmatic event. Unusually high concentrations of both HREE (Dy+Yb+Er+Lu) and Y (up to 1.2 and 2.1?ppm, respectively) occur in olivines (Fo_79.5 and 0.25% NiO) from picritic and taxitic gabbro-dolerites with disseminated sulfide mineralization. Thus accumulation of HREE, Y and Ni in the melts is correlated with the mineral potential of the intrusions. The TiO₂ concentration in pyroxene has a strong negative correlation with the Mg# of both host mineral and Mg# of host rock. Sulfides from the Northern Maslovsky intrusion are predominantly chalcopyrite–pyrrhotite–pentlandite with subordinate and minor amounts of cubanite, bornite and millerite and a diverse assemblage of rare precious metal minerals including native metals (Au, Ag and Pd), Sn–Pd–Pt–Bi–Pb compounds and Fe–Pt alloys. Sulfides from the Southern Maslovsky intrusion have δ ³⁴S?=?5–6‰ up to 10.8‰ in two samples whereas the country rock basalt have δ ³⁴S?=?3–4‰, implying there was no in situ assimilation of surrounding rocks by magmas.     

Method of negative saturations for flow with variable number of phases in porous media: extension to three-phase multi-component case

Various EOR methods lead to the appearance of specific macroscopic surfaces called interfaces of phase transition (IPT) such that the number of phases on two sides of an IPT is different, and fluids separated by an IPT are in non-equilibrium. Therefore, the flow equations are also different on two sides of an IPT and cannot be deduced from each other by a continuous degeneration, which imposes difficulties in numerical modelling. To describe such systems, we developed a new conceptual mathematical method based on the replacement of the real single-phase fluid by an imaginary multi-phase multi-component continuum having fictitious properties. As the result, the fluid over all zones becomes multi-phase and can be described by uniform multi-phase hydro- and thermodynamic equations, which allows applying the direct numerical simulation. The equivalence principle determines the physical properties of the fictitious multi-phase fluid, as well as the structure of the uniform multi-phase equations. It also proves that the saturation of each phase becomes an extended function negative or higher than unity in non-equilibrium zones, which becomes the efficient method of tracking the interfaces, the number of phases at any point, and their degree of disequilibrium. The method was developed in [1, 2] for the two-phase case. In the present paper, the new version of the method is developed for the three-phase case with gravity, diffusion, and capillarity. We have obtained the new equivalent uniform multi-phase equations which contain additional non-classical terms responsible for the diffusion and gravity across an IPT. The comparison with classical method is presented. The presentation is illustrated by several examples of simulation by means of the code developed by the research group; their concern: EOR by miscible methods and CO ₂ bubble raising in aquifer.     

Determination of REE, Y, Nb, Zr, Hf, Ta, Th and U in Geological Reference Materials LSHC-1 and Amf-1 by Solution and Laser Ablation ICP-MS

This paper presents data on REE and Y, Nb, Zr, Hf, Ta, Th and U abundances for two candidate reference materials (RMs), spinel lherzolite LSHC-1 and amphibole Amf-1, being currently developed at the Institute of Geochemistry SB RAS, Irkutsk. To determine the contents of these elements inductively coupled plasma-mass spectrometry was applied with: (i) solution nebulisation (solution ICP-MS) and (ii) laser ablation (LA-ICP-MS) of fused glass disks. The precision of results obtained by both techniques was better than 6% RSD for most elements. Accuracy was assessed by using the geochemical RMs JB-2, JGb-1 (GSJ) and MAG-1 (USGS). The trace element results by solution ICP-MS for JGb-1 and JB-2 agree with reference values presented by Imai et al. (1995, this Journal) within 1–10%. Significant differences were found for Nb and Ta determinations. The accuracy of LA-ICP-MS results evaluated by RM MAG-1 was within 4%, except for Eu (about 10%). The analytical results obtained for LSHC-1 and Amf-1 by solution ICP-MS and LA-ICP-MS were in good agreement with each other and with INAA and XRF data presented for the certification of these RMs. They can be considered as the indicative values for assigning certified values to the above-mentioned RMs.