Potentially harmful metals,and health risk evaluation in groundwater of Mardan,Pakistan: Application of geostatistical approach and geographic information system

This study investigates the values of pH, total dissolved solids (TDS), elevation, oxidative reduction potential (ORP), temperature, and depth, while the concentrations of Br, and potentially harmful metals (PHMs) such as Cr, Ni, Cd, Mn, Cu, Pb, Co, Zn, and Fe in the groundwater samples. Moreover, geographic information system (GIS), XLSTAT, and IBM SPSS Statistics 20 software were used for spatial distribution modeling, principal component analysis (PCA), cluster analysis (CA), and Quantile-Quantile (Q-Q) plotting to determine groundwater pollution sources, similarity index, and normal distribution reference line for the selected parameters. The mean values of pH, TDS, elevation, ORP, temperature, depth, and Br were 7.2, 322 mg/L, 364 m, 188 mV, 29.6 °C, 70 m, 0.20 mg/L, and PHMs like Cr, Ni, Cd, Mn, Cu, Pb, Co, Zn, and Fe were 0.38, 0.26, 0.08, 0.27, 0.36, 0.22, 0.04, 0.43 and 0.86 mg/L, respectively. PHMs including Cr (89%), Cd (43%), Mn (23%), Pb (79%), Co (20%), and Fe (91%) exceeded the guideline values set by the world health organization (WHO). The significant R² values of PCA for selected parameters were also determined (0.62, 0.67, 0.78, 0.73, 0.60, 0.87, ?0.50, 0.69, 0.70, 0.74, ?0.50, 0.70, 0.67, 0.79, 0.59, and ?0.55, respectively). PCA revealed three geochemical processes such as geogenic, anthropogenic, and reducing conditions. The mineral phases of Cd(OH)_2, Fe(OH)_3, FeOOH, Mn₃O_4, Fe₂O_3, MnOOH, Pb(OH)_2, Mn(OH)_2, MnO_2, and Zn(OH)₂ (?3.7, 3.75, 9.7, ?5.8, 8.9, ?3.6, 2.2, ?4.6, ?7.7, ?0.9, and 0.003, respectively) showed super-saturation and under-saturation conditions. Health risk assessment (HRA) values for PHMs were also calculated and the values of hazard quotient (HQ), and hazard indices (HI) for the entire study area were increased in the following order: Cd>Ni>Cu>Pb>Mn>Zn>Cr. Relatively higher HQ and HI values of Ni, Cd, Pb, and Cu were greater than one showing unsuitability of groundwater for domestic, agriculture, and drinking purposes. The long-term ingestion of groundwater could also cause severe health concerns such as kidney, brain dysfunction, liver, stomach problems, and even cancer.     

Trace elements in groundwater of Hindon-Yamuna interfluve region, Baghpat district, Western Uttar Pradesh

The present study was carried out in parts of Hindon-Yamuna interfluve region to evaluate the concentration of trace elements (Al, Cr, Mn, Fe, Ni, Co, Cu, Zn, As, Se, Cd, B and Pb) in groundwater. Pre-monsoon groundwater samples were collected in 2007 from 22 locations distributed throughout the study area, and were analyzed using Inductive Coupled Plasma Mass-Spectrophotometer (ICPMS). Trace element analyses show high concentration levels for Al and Cr in almost all groundwater samples. Relatively high values are also reported for Pb, Se, Fe and Mn (as per B.I.S (1991) standard for drinking water) in few samples. These high concentrations of metal ions in groundwater were probably due to discharge of untreated effluents from Textile, dyeing and other industries. As far as Al is concerned, its source is rather enigmatic.     

Is shrinking groundwater resources leading to socioeconomic and environmental degradation in Central Ganga Plain,India?

In India, agriculture is a source of livelihood for over 64 % of the country's population. Indo-Gangetic Plains of North India support good cultivation and provides livelihood to several hundred million people. The climatic change studies have documented changes in precipitation pattern which can alter the flow pattern discharge to the reservoirs and availability of water for agriculture. The reduction in groundwater recharge through reduced rainfall and irregularity in surface water availability has increased dependence on groundwater resources causing its overexploitation. Consequently, pumping from deeper groundwater conditions need more energy and pump efficiency for abstraction which ultimately requires huge capital investment. Moreover, volatile fuel prices make the agricultural society vulnerable to economic losses. The repercussions of water level decline are likely to disseminate an additional economic burden to the groundwater user community. To cope with higher energy demands, increase in fuel consumption has led to environmental degradation through higher carbon emission. Thus, the groundwater depletion is likely to have far-reaching socioeconomic and environmental impacts which are not confined to the Central Gangetic Plain. In the present study, attempts have been made to analyze the effect of groundwater depletion as a commodity in the social framework of the region.     

Noether gauge symmetry approach in quintom cosmology

In literature usual point like symmetries of the Lagrangian have been introduced to study the symmetries and the structure of the fields. This kind of Noether symmetry is a subclass of a more general family of symmetries, called Noether gauge symmetries (NGS). Motivated by this mathematical tool, in this paper, we study the generalized Noether symmetry of quintom model of dark energy, which is a two component fluid model with quintessence and phantom scalar fields. Our model is a generalization of the Noether symmetries of a single and multiple components which have been investigated in detail before. We found the general form of the quintom potential in which the whole dynamical system has a point like symmetry. We investigated different possible solutions of the system for diverse family of gauge function. Specially, we discovered two family of potentials, one corresponds to a free quintessence (phantom) and the second is in the form of quadratic interaction between two components. These two families of potential functions are proposed from the symmetry point of view, but in the quintom models they are used as phenomenological models without clear mathematical justification. From integrability point of view, we found two forms of the scale factor: one is power law and second is de-Sitter. Some cosmological implications of the solutions have been investigated.     

Artificial neural network prediction of sulfate and SAR in an unconfined aquifer in southeastern Turkey

In many rural communities, groundwater is used to meet the water demand of the community and for the irrigation of cultivating areas. The quality of groundwater can be adversely affected by agricultural activities and finally groundwater quality may become unsuitable for human consumption and irrigation, as in the Harran Plain. Hence, monitoring groundwater quality by cost-effective techniques is necessary, as especially unconfined aquifers are vulnerable to contamination. This study presents an artificial neural network model predicting sodium adsorption ratio (SAR) and sulfate concentration in the unconfined aquifer of the Harran Plain. Samples from 24 observation wells were analyzed monthly for 1?year. Electrical conductivity, pH, groundwater level, temperature, total hardness and chloride were used as input parameters in the predictions. The best back-propagation (BP) algorithm and neuron numbers were determined for the optimization of the model architecture. The Levenberg?CMarquardt algorithm was selected as the best of 12 BP algorithms and optimal neuron number was determined as 20 for both parameters. The model tracked the experimental data very closely both for SAR (R?=?0.96) and sulfate (R?=?0.98). Hence, it is possible to manage groundwater resources in a more cost-effective and easier way with the proposed model application.     

Climate links and recent extremes in antarctic sea ice, high-latitude cyclones, Southern Annular Mode and ENSO

In this article, we study the climate link between the Southern Annular Mode (SAM) and the southern sea-ice extent (SIE), and discuss the possible role of stationary waves and synoptic eddies in establishing this link. In doing so, we have used a combination of techniques involving spatial correlations of SIE, eddy streamfunction and wind anomalies, and statistics of high-latitude cyclone strength. It is suggested that stationary waves may be amplified by eddy anomalies associated with high latitude cyclones, resulting in more sea ice when the SAM is in its positive phase for most, but not all, longitudes. A similar association is observed during ENSO (La Ni?a years). Although this synergy in the SAM/ENSO response may partially reflect preferential areas for wave amplification around Antarctica, the short extent of the climate records does not allow for a definite causality connection to be established with SIE. Stronger polar cyclones are observed over the areas where the stationary waves are amplified. These deeper cyclones will break up and export ice equatorward more efficiently, but the near-coastal regions are cold enough to allow for a rapid re-freeze of the resulting ice break-up. We speculate that if global warming continues this same effect could help reverse the current (positive) Antarctic SIE trends once the ice gets thinner, similarly to what has been observed in the Northern Hemisphere.     

Mapping groundwater vulnerable zones using modified DRASTIC approach of an alluvial aquifer in parts of central Ganga plain,Western Uttar Pradesh

A detailed hydrogeological and hydrochemical study was carried out in Yamuna-Krishni sub-basin which is a part of the vast central Ganga plain. Groundwater is the major source of water supply for agricultural, domestic and industrial uses. The excess use of groundwater has resulted in depletion of water levels. The groundwater quality, too, has deteriorated in areas dominated by industrial activity. This has led to the preparation of a groundwater vulnerability map in relation to contamination. Groundwater vulnerability maps are valuable derivative maps that show, quantitatively or qualitatively, certain characteristics of the sub-surface environment that determine vulnerability of groundwater to contamination. The modified DRASTIC method was used to prepare vulnerability map. The parameters like depth to water, net recharge, aquifer media, soil media, impact of vadose zone, hydraulic conductivity and land use pattern, owing to its bearing on groundwater regime, were considered to prepare vulnerability map. The vulnerability index is computed as the sum of the products of weight and rating assigned to each of the input considered as above. The vulnerability index ranges from 140 to 180, and is classified into four classes i.e. 140–150, 150–160, 160–170 and 170–180 corresponding to low, medium, high and very high vulnerability zones respectively. Using this index, a groundwater vulnerability potential map was generated which shows that 7%, 40% and 53% of the study area falls in low, medium and high to very high vulnerability zones respectively. The map, thus generated, can be used as a tool for protection and management of aquifers from contamination.     

A Periglacial Palaeoenvionment in the Upper Carboniferous–Lower Permian Tobra Formation of the Salt Range, Pakistan

The Upper Carboniferous—Lower Permian(Upper Pennsylvanian-Asselian) Tobra Formation is exposed in the Salt and Trans Indus ranges of Pakistan.The formation exhibits an alluvial plain(alluvial fan-piedmont alluvial plain) facies association in the Salt Range and Khisor Range.In addition,a stream flow facies association is restricted to the eastern Salt Range.The alluvial plain facies association is comprised of clast-supported massive conglomerate(Gmc),diamictite(Dm)facies,and massive sandstone(Sm) Hthofacies whereas the stream flow-dominated alluvial plain facies association includes fine-grained sandstone and siltstone(Fss),fining upwards pebbly sandstone(Sf),and massive mudstone(Fm) Hthofacies.The lack of glacial signatures(particularly glacial grooves and striatums) in the deposits in the Tobra Formation,which are,in contrast,present in their timeequivalent and palaeogeographically nearby strata of the Arabian peninsula,e.g.the AI Khlata Formation of Oman and Unayzah B member of the Saudi Arabia,suggests a pro-to periglacial,i.e.glaciofluvial depositional setting for the Tobra Formation.The sedimentology of the Tobra Formation attests that the Salt Range,Pakistan,occupied a palaeogeographic position just beyond the maximum glacial extent during Upper Pennsylvanian-Asselian time.     

Characterization of locally available soil as a liner material for solid waste landfills in Sri Lanka

This study aimed to develop a low-cost and effective clay liner material for solid waste landfills in Sri Lanka. A locally available clayey soil and its admixtures with 5 and 10% bentonite were examined for this purpose. Laboratory experiments to determine soil plasticity and swell index were carried out on the tested samples. Hydraulic conductivity (k) tests were carried out in the laboratory using water and an aqueous solution of CaCl₂ on unconsolidated samples prepared by either dry or slurry packing and pre-consolidated samples with five different consolidation pressures (p) from 10 to 200 kPa. Measured liquid limits for tested admixtures increased with increasing bentonite contents and correlated well with measured values of the swell index. The difference in permeant solutions had little effect on measured k values for both unconsolidated and pre-consolidated samples. The hydraulic conductivities were highly affected by changing p, i.e., the k values decreased on two orders of magnitude as p increased from 10 to 200 kPa. The Kozeny–Carman equation, a theoretical permeability model that expresses the k-porosity relationship, was applied to measured data including reported values. Results showed the Kozeny–Carman equation captured well the porosity-dependent k values for tested soils and their admixtures with bentonite under a wide range of void ratios, suggesting that the Kozeny–Carman equation is a useful tool to estimate the magnitude of k values for differently compacted soil and its bentonite admixtures.     

Length-weight relationship of eleven species of marine catfishes from the northern Arabian Sea coast of Pakistan

This study records length-weight relationships(LWRs)for eleven commercially important marine catfi sh species of the family Ariidae(sea catfi shes)and Plotosidae(eel catfi shes)from the northern Arabian Sea coast of Pakistan.The specimens were sampled from December 2014 to November 2015,using bottom trawls with various mesh sizes by commercial vessels.The species were Nemapteryx caelatus,Sciades sona,Arius gagora,Batrachocephalus mino,Netuma thalassina,N.bilineata,Osteogeneiosus militaris,Plicofollis dussumieri,P.tenuispinis,Plotosus limbatus,and P.lineatus.Of the eleven species,two species A.gagora and N.bilineata were recorded for the fi rst time and LWRs for four species A.gagora,N.bilineata,S.sona,and B.mino still have no data in the Fish Base database.In addition,new maximum length for each of the three species N.bilineata,O.militaris and B.m ino was also found.