THUNDERSTORM CLIMATOLOGY BASED ON LIGHTNING DETECTOR DATA,MANITOBA, CANADA

Comparisons are made between thunderstorm data collected from a lightning detector network and from conventional climatic stations for the province of Manitoba, Canada. The greater resolution in time and space of lightning detector (direction finder) data makes it a valuable source of thunderstorm information and lends itself to some important applications. Data were collected for the forest fire season of 1985 using a network of 7 lightning direction finders distributed throughout the province. Some 67,912 cloud-to-ground lightning strikes were recorded by time and location during 122 thunderstorm days. July was the most active month with 27,260 strikes over 28 days. Two regions of the province had the greatest concentration of lightning strikes, indicating some influence by topography and position of large lakes. Case studies are presented of the most active lightning storms of 1985 and 1986. These storms are exclusively frontal storms, with most having similar synoptic weather patterns to those of large hailstorms and tornadoes in Manitoba. Relationships between meteorological parameters and lightning strike distribution are presented. These relationships may prove useful in the suppression of lightning-caused forest fires, especially in remote areas of the province. [Key words: lightning, thunderstorm, synoptic climatology, natural hazards, fire prevention.]     

A Crustal Model for the Eastern Alps Region and a New Moho Map in Southeastern Europe

In the last two decades, south-central Europe and the Eastern Alps have been widely explored by many seismic refraction experiments (e.g., CELEBRATION 2000, ALP 2002, SUDETES 2003). Although quite detailed images are available along linear profiles, a comprehensive, three-dimensional crustal model of the region is still missing. This limitation makes this region a weak spot in continental-wide comprehensive representations of crustal structure. To improve on this situation, we select and collect 37 published active-source seismic lines in this region. After geo-referencing each line, we sample them along vertical profiles—every 50?km or less along the line—and derive P-wave velocities in a stack of homogeneous layers (separated by discontinuities: depth of crystalline basement, top of lower crust, and Moho). We finally merge the information using geostatistical methods, and infer S-wave velocity and density using empirical scaling relations. We present here the resulting crustal model for a region encompassing the Eastern Alps, Dinarides, Pannonian basin, Western Carpathians and Bohemian Massif, covering the region within $45^{\circ}\text{--}51^{\circ}\hbox{N}$ and $11^{\circ} \text{--} 22^{\circ}\hbox{E}$ with a resolution of $0.2^{\circ} \times 0.2^{\circ}.$ We are also able to extend and update the map of Moho depth in a wider region within $35^{\circ}\text{--}51^{\circ}\hbox{N}$ and $12^{\circ}\text{--}45^{\circ}\hbox{E},$ gathering Moho values from the collected seismic lines, other published dataset and using the European plate reference EPcrust as a background. All the digitized profiles and the resulting model are available online.     

Holocene evolution of a rock‐bounded barrier‐lagoon system,Cíes Islands,northwest Iberia

Coastal geomorphology results from the combined effects of contemporary dynamics, sea‐level rise and the inherited geological framework, yet the relative importance of these driving mechanisms may change throughout the evolutionary history of coastal deposits. In this contribution, we analyse the depositional history of the Cíes Islands barrier‐lagoon system, based on lithofacies, radiocarbon ages, and pollen analysis. Our results reveal a sedimentary sequence that provides evidence for striking changes in the dynamical functioning of this complex since the mid‐Holocene. The sedimentary sequence commenced about 7700 cal years bp by fresh‐water ponding of an upland depression located about 4 m below present mean sea‐level. Fresh‐water ponds were infilled by aeolian sediments following a gradual lowering of the water‐table 4000 cal years bp . Post‐3600 cal years bp sea‐level rise allowed water oscillations to reach the elevation of the bedrock causing the inundation of fresh‐water ponds and subsequent lagoonal and marine sedimentation. Subsequently, landward and upward migration of a sand‐barrier led to overwash and deposition of sand in the newly formed lagoon. The resultant sedimentary sequence suggests that climatic conditions played an important role controlling the sedimentation regime during the entire history of the basin; changing water‐table levels during early stages of evolution and increasing storminess during more recent times. In addition, background sea‐level rise related to the Holocene transgression was a key factor in controlling the evolution of the system, yet its influence depended to an extent on the relative elevation of the bedrock topography. Copyright © 2009 John Wiley & Sons, Ltd.     

Atmospheric inorganic aerosol of a non-industrial city in the centre of an industrial region of the North of Spain,and its possible influence on the climate on a regional scale

Mineral particles could have influenced on the climate of Oviedo, a non-industrial city situated in the centre of an industrial zone of the North of Spain, increasing the temperature and the precipitations, in spite of the fact that “greenhouse gases” concentrations have diminished in this city in recent years. The directive (1999/30/EC) of the European Commission began to be applied in Oviedo in the year 2003. In agreement with this norm, our first aim was the identification of the inorganic particulate matter of the PM10 and PM2.5 fractions sampled in this city. X-ray diffraction and scanning electron microscopy coupled with X-ray dispersive energy spectrometry were used. The percentages of the different mineral phases of the PM were obtained by a Rietveld refinement of powder X-ray diffraction data. The compositions of the PM10 and PM2.5 fractions of this city are similar. Sulphates are the most abundant particles in the both fractions. Most sulphates, nitrates and sal-ammoniac would have formed by reaction between solid, liquid and/or gas particles and they could be associated with the power stations near to the city and traffic. Wüstite and haematites come from the iron and steel industries of Gijón and Avilés. The main natural sources of halite and carbonates and silicates are sea spray and soil resuspension by the wind, respectively.     

Biomarker lipids of the freshwater fern Azolla and its fossil counterpart from the Eocene Arctic Ocean

Eocene sediments recovered from the Lomonosov Ridge in the central Arctic Ocean during Integrated Ocean Drilling Program Expedition 302 contain high amounts of fossil remains of the free floating freshwater fern Azolla. Both extant Azolla and the sediments from the Arctic Azolla interval were found to contain relatively high quantities of compounds identified as 1,ω20 C₃₀–C₃₆ diols. Furthermore, structurally related mid-chain hydroxy fatty acids, long chain n-alkanols and keto-ols were discovered. The different series have a common feature: there is always a hydroxy group at the ω20 position. In addition, structurally related C₂₉ ω20,ω21 diols, C₂₉ 1,20,21 triols, C₂₉ dihydroxy fatty acids as well as a series of wax esters containing these mono- and dihydroxy lipids are reported. Selective extraction of Azolla surface lipids revealed that these compounds are most likely present in the leaf waxes of the fern. The suite of long-chain, mid-chain ω20 hydroxy wax constituents is described for the first time. As they are well preserved in the Eocene sediments, these lipids may serve as palaeo-environmental indicators of the Arctic Azolla interval and as markers for the past occurrence of Azolla in general.     

Future emissions of marine halogenated very-short lived substances under climate change

Halogenated Very Short-lived Substances (VSLS), such as bromoform, dibromomethane and methyl iodide, are naturally produced in the oceans and are involved in ozone depletion in the troposphere and the stratosphere. The effect of climate change on the oceanic emissions of these compounds is not well quantified. Based on present-day observed global oceanic and atmospheric concentrations, and historic and future data from three CMIP5 models, past and future sea-to-air fluxes of these VSLS are calculated. The simulations are used to infer possible effects of projected changes of physical forcing on emissions in different oceanic regimes. CMIP5 model output for 1979–2100 from the historical scenario and the RCP scenarios 2.6 and 8.5 are used as input data for the emission calculations. Of the parameters that have the main influence on the sea-to-air fluxes, the global sea surface temperatures show a steady increase during the twenty-first century, while the projected changes of sea surface wind speed is very small. The calculated emissions based on the historical CMIP5 model runs (1979–2005) increased over the 26 year period and agree well with the emissions based on ERA-Interim data. The future sea-to-air fluxes of VSLS generally increase during the twenty-first century under the assumption of constant concentration fields in the ocean and atmosphere. The multi-model mean global emissions of bromoform increase by 29.4% (9.0%) between 1986 and 2005 and 2081–2100 under RCP 8.5 (2.6) and dibromomethane and methyl iodide emissions increase by 23.3% (6.4%) and 5.5% (1.5%), respectively. Uncertainties of the future emission estimates, driven by ongoing environmental changes such as changing oceanic productivity (not considered in this study) are discussed.     

The Energy Balance Experiment EBEX-2000. Part I: overview and energy balance

An overview of the Energy Balance Experiment (EBEX-2000) is given. This experiment studied the ability of state-of-the-art measurements to close the surface energy balance over a surface (a vegetative canopy with large evapotranspiration) where closure has been difficult to obtain. A flood-irrigated cotton field over uniform terrain was used, though aerial imagery and direct flux measurements showed that the surface still was inhomogeneous. All major terms of the surface energy balance were measured at nine sites to characterize the spatial variability across the field. Included in these observations was an estimate of heat storage in the plant canopy. The resultant imbalance still was 10%, which exceeds the estimated measurement error. We speculate that horizontal advection in the layer between the canopy top and our flux measurement height may cause this imbalance, though our estimates of this term using our measurements resulted in values less than what would be required to balance the budget. The National Center for Atmospheric Research is supported by the National Science Foundation     

Quantitative antimony speciation in shooting-range soils by EXAFS spectroscopy

The Sb speciation in soil samples from Swiss shooting ranges was determined using Sb K-edge X-ray absorption spectroscopy (XAS) and advanced statistical data analysis methods (iterative transformation factor analysis, ITFA). The XAS analysis was supported by a spectral data set of 13 Sb minerals and 4 sorption complexes. In spite of a high variability in geology, soil pH (3.1-7.5), Sb concentrations (1000-17,000 mg/kg) and shooting-range history, only two Sb species were identified. In the first species, Sb is surrounded solely by other Sb atoms at radial distances of 2.90, 3.35, 4.30 and 4.51 Å, indicative of metallic Sb(0). While part of this Sb(0) may be hosted by unweathered bullet fragments consisting of PbSb alloy, Pb L_III-edge XAS of the soil with the highest fraction (0.75) of Sb(0) showed no metallic Pb, but only Pb²⁺ bound to soil organic matter. This suggests a preferential oxidation of Pb in the alloy, driven by the higher standard reduction potential of Sb. In the second species, Sb is coordinated to 6 O-atoms at a distance of 1.98 Å, indicative of Sb(V). This oxidation state is further supported by an edge energy of 30,496-30,497 eV for the soil samples with <10% Sb(0). Iron atoms at radial distances of 3.10 and 3.56 Å from Sb atoms are in line with edge-sharing and bidentate corner-sharing linkages between Sb(O,OH)₆ and Fe(O,OH)₆ octahedra. While similar structural units exist in tripuhyite, the absence of Sb neighbors contradicts formation of this Fe antimonate. Hence the second species most likely consists of inner-sphere sorption complexes on Fe oxides, with edge and corner-sharing configuration occurring simultaneously. This pentavalent Sb species was present in all samples, suggesting that it is the prevailing species after weathering of metallic Sb(0) in oxic soils. No indication of Sb(III) was found.