Geochemistry and tectonic development of Cenozoic magmatism in the Carpathian–Pannonian region

This review considers the magmatic processes in the Carpathian–Pannonian Region (CPR) from Early Miocene to Recent times, as well as the contemporaneous magmatism at its southern boundary in the Dinaride and Balkans regions. This geodynamic system was controlled by the Cretaceous to Neogene subduction and collision of Africa with Eurasia, especially by Adria that generated the Alps to the north, the Dinaride–Hellenide belt to the east and caused extrusion, collision and inversion tectonics in the CPR. This long-lived subduction system supplied the mantle lithosphere with various subduction components. The CPR contains magmatic rocks of highly diverse compositions (calc-alkaline, K-alkalic, ultrapotassic and Na-alkalic), all generated in response to complex post-collisional tectonic processes. These processes formed extensional basins in response to an interplay of compression and extension within two microplates: ALCAPA and Tisza–Dacia. Competition between the different tectonic processes at both local and regional scales caused variations in the associated magmatism, mainly as a result of extension and differences in the rheological properties and composition of the lithosphere. Extension led to disintegration of the microplates that finally developed into two basin systems: the Pannonian and Transylvanian basins. The southern border of the CPR is edged by the Adria microplate via Sava and Vardar zones that acted as regional transcurrent tectonic areas during Miocene–Recent times.Major, trace element and isotopic data of post-Early Miocene magmatic rocks from the CPR suggest that subduction components were preserved in the lithospheric mantle after the Cretaceous–Miocene subduction and were reactivated especially by extensional tectonic processes that allowed uprise of the asthenosphere. Changes in the composition of the mantle through time support geodynamic scenarios of post-collision and extension processes linked to the evolution of the main blocks and their boundary relations. Weak lithospheric blocks (i.e. ALCAPA and western Tisza) generated the Pannonian basin and the adjacent Styrian, Transdanubian and Z?rand basins which show high rates of vertical movement accompanied by a range of magmatic compositions. Strong lithospheric blocks (i.e. Dacia) were only marginally deformed, where strike–slip faulting was associated with magmatism and extension. At the boundary of Adria and Tisza–Dacia strike–slip tectonics and core complex extension were associated with small volume Miocene magmatism in narrow extensional sedimentary basins or granitoids in core-complex detachment systems along older suture zones (Sava and Vardar) accommodating the extension in the Pannonian basin and afterward Pliocene–Quaternary inversion. Magmas of various compositions appear to have acted as lubricants in a range of tectonic processes.     

Environmental Impact Assessment of High Pressure Water Scrubbing Biogas Upgrading Technology

The aim of this work was to assess the burdens of a process in terms of environmental and health impacts, resource depletion issues, and energy demand based on the ability of the Life Cycle Assessment methodology to link the environmental impacts with the mass and energy flows. The analysis was done in terms of process and environmental performances of high pressure water scrubbing (HPWS) system applied for biogas upgrading. The application of process simulation based on the Aspen Plus® software has been considered as supportive for the calculation of mass and energy balances. Data processed using GaBi 4: Software showed that global warming, acidification, and human toxicity potentials were the main impact categories associated with the HPWS process. These indicators are largely related to the exhaust gas from the desorption column and the indirect emissions generated during energy consumption. The life cycle inventory study resulted in the development of a database with a vast inventory of data regarding HPWS technology. A basis for assessing potential improvements in the environmental performance of the system is provided. Future studies in this area will address the economical evaluation of the HPWS technology, so as to maximize economic efficiency and minimize environmental impacts.     

Geoelectrical investigations by means of resistivity methods in karst areas in Romania

The applicability of resistivity methods to ground water investigations is well recognized. As water-saturated rock formations have a lower electrical resistivity than dry ones, an electrical resistivity survey should result in low resistivity anomalies. Normally, such anomalies are interpreted to indicate areas of potentially significant ground water flows. In karst areas, however, interpretation may not be as straightforward: for example, large electrically conductive domains can represent water bearing zones, whose fluid-permeability may be poor; alternatively, fast flow conduits, which may be unsaturated, occur as slender objects, and not as clear anomalous features. In order to deal with such extreme heterogeneities, resistivity investigations require some specific adjustments. One example is the so-called “mise à la masse” method. In Romania, it was used to trace the cold karst water inflows that detrimentally affected the commercial exploitation of a thermal spring, Hercules at Baile Herculane. Conventional geoelectrical approaches––such as using resistivity highs to detect air-filled cave passages, are proved to be less efficient in the considered karst investigations.     

Note on the evolution of a Miocene composite volcano in an extensional setting, Zârand Basin (Apuseni Mts., Romania)

Bontâu is a major eroded composite volcano filling the Miocene Zârand extensional basin, near the junction between the Codru-Moma and Highi?-Drocea Mountains, at the tectonic boundary between the South and North Apuseni Mountains. It is a quasi-symmetric structure (16–18 km in diameter) centered on an eroded vent area (9×4 km), buttressed to the south against Mesozoic ophiolites and sedimentary deposits of the South Apuseni Mountains. The volcano was built up in two sub-aerial phases (14–12.5 Ma and 11–10 Ma) from successive eruptions of andesite lava and pyroclastic rocks with a time-increasing volatile budget. The initial phase was dominated by emplacement of pyroxene andesite and resulted in scattered individual volcanic lava domes associated marginally with lava flows and/or pyroclastic block-and-ash flows. The second phase is characterized by amphibole-pyroxene andesite as a succession of pyroclastic eruptions (varying from strombolian to subplinian type) and extrusion of volcanic domes that resulted in the formation of a central vent area. Numerous debris flow deposits accumulated at the periphery of primary pyroclastic deposits. Several intrusive andesitic-dioritic bodies and associated hydrothermal and mineralization processes are known in the volcano vent complex area. Distal epiclastic deposits initially as gravity mass flows and then as alluvial volcaniclastic and terrestrial detritic and coal filled the basin around the volcano in its western and eastern part. Chemical analyses show that lavas are calc-alkaline andesites with SiO₂ ranging from 56–61%. The petrographical differences between the two stages are an increase in amphibole content at the expense of two pyroxenes (augite and hypersthene) in the second stage of eruption; CaO and MgO contents decrease with increasing SiO₂. In spite of a ～4 Ma evolution, the compositions of calc-alkaline lavas suggest similar fractionation processes. The extensional setting favored two pulses of short-lived magma chamber processes.     

On the orbital eccentricity on an eclipsing binary system

A new method is presented to precisely deduce the orbital eccentricity of an eclipsing binary from observed epochs of its light minima. Application to the system V526 Sagittarii givese=0.2220±0.0016.     

Equipotential surfaces in close binary systems: Remarks on the time-dependent potential function

By use of the mass-point model, the equations of the equipotential surfaces are reviewed. A difference between the time-dependent potential function and zero relative velocity surfaces is put in evidence. A drawback in the time-dependent transformation between (, , ) and (x, y, z) coordinate systems is underlined.     

Late Miocene–Quaternary volcanism, tectonics and drainage system evolution in the East Carpathians, Romania

Middle Miocene (Sarmatian) convergence created the fold and thrust belt of the Eastern Carpathians of Romania, which subsequently experienced post-collisional crustal deformation combined with calc-alkaline and alkalic-basaltic volcanism in late Miocene–Quaternary time. This deformation led to the rise of the Cǎlimani–Gurghiu–Harghita volcanic mountains and to the subsidence of the N–S-oriented intramontane Borsec/Bilbor–Gheorgheni–Ciuc and Braşov pull-apart basins, and the E-oriented monocline-related Fǎgǎraş basin. The regional drainage network is the composite of:

(1) Older E-, SE- and S-flowing rivers, which cross the Carpathians, radiate towards the foreland and were probably established during the Middle Miocene (Sarmatian) collision event.

(2) A more recent drainage system related to the contemporaneous development of the volcanoes and intramontaneous basins, which generally drains westward into the Transylvanian Basin since late Miocene time and has been capturing the older river system.

The older river drainage system has also been modified by Late Pliocene–Quaternary folding, thrusting and monoclinal tilting along the Pericarpathian orogenic front and by reactivated transverse high angle basement faults, which cross the Eastern Carpathian foreland.