A Synthetic Germanium-Bismuth Glass for the Coarse Mass Calibration of SIMS Instruments

This short technical note describes a simple technique for synthesising an optimised binary glass for performing coarse mass table calibrations of secondary ion mass spectrometers. A Ge-Bi glass doped with five selected trace elements was used to anchor the entire mass table up to m/z ≥ 209 at an accuracy of < 0.5 dalton. Using this material it has been possible to calibrate coarsely the mass table of a Cameca ims 6f instrument in less than five minutes, thereby greatly simplifying the switch from low mass range to high mass range measurements. Although not suitable for the quantification of geological materials, the ease of synthesis and its utility for rapidly performing what is an otherwise time consuming process makes this material a useful tool for SIMS instruments which offer a multiple mass range capability.     

Reply to “Oxygen isotope heterogeneity of the mantle beneath the Canary Islands: a discussion of the paper of Gurenko et al.”

The comment by Day et al. (Contrib Mineral Petrol, 2012) (1) discusses the validity of the previously obtained oxygen isotope data for El Hierro and La Palma (Canary Island) olivines, (2) questions the approach by Gurenko et al. (Contrib Mineral Petrol 162:349–363, 2011) of using weakly correlated variations of δ¹⁸O_olivine values with X _px (proportion of pyroxenite-derived melt in the parental magma), and (3) provides reasons why oxygen isotope data by secondary ion mass spectrometry (SIMS) “offer sensitive means for detecting melt-crust interactions.” We respond these comments and report a new set of oxygen isotope measurements performed by SIMS and single-grain laser fluorination methods. These measurements confirm our previous data and conclusions and demonstrate the ability of the SIMS technique to analyze O isotopes in terrestrial samples with 2-sigma uncertainty better than ±0.25 ‰.     

3D inversion of gravity data by separation of sources and the method of local corrections: Kolarovo gravity high case study

We present a novel methodology for 3D gravity/magnetic data inversion. It combines two algorithms for preliminary separation of sources and an original approach to 3D inverse problem solution. The first algorithm is designed to separate sources in depth and to remove the shallow ones. It is based on subsequent upward and downward data continuation. For separation in the lateral sense, we approximate the given observed data by the field of several 3D line segments. For potential field data inversion we apply a new method of local corrections. The method is efficient and does not require trial-and-error forward modeling. It allows retrieving unknown 3D geometry of anomalous objects in terms of restricted bodies of arbitrary shape and contact surfaces. For restricted objects, we apply new integral equations of gravity and magnetic inverse problems. All steps of our methodology are demonstrated on the Kolarovo gravity anomaly in the Danube Basin of Slovakia.     

Influence of background heterogeneity on traveltime shifts for compacting reservoirs

Compaction induced by pore‐pressure decrease inside a reservoir can be monitored by measuring traveltime shifts of reflection events on time‐lapse seismic data. Recently we introduced a perturbation‐based formalism to describe traveltime shifts caused by the 3D stress‐induced velocity field around a compacting reservoir. Application of this method to homogeneous background models showed that the offset variation of traveltime shifts is controlled primarily by the anisotropic velocity perturbations and can provide valuable information about the shear and deviatoric stresses. Here, we model and analyse traveltime shifts for compacting reservoirs whose elastic properties are different from those of the surrounding medium. For such models, the excess stress is influenced primarily by the contrast in the rigidity modulus μ across the reservoir boundaries. Synthetic examples demonstrate that a significant (25% or more) contrast in μ enhances the isotropic velocity perturbations outside the reservoir. Nevertheless, the influence of background heterogeneity is mostly confined to the reservoir and its immediate vicinity and the anisotropic velocity changes are still largely responsible for the offset dependence of traveltime shifts. If the reservoir is stiffer than the host rock, the background heterogeneity reduces anisotropic velocity perturbations inside the reservoir but increases them in the overburden. As a result, in this case, the magnitude of the offset variation of traveltime shifts is generally higher for reflections from interfaces above the reservoir. We also study compaction‐induced stress/strain and traveltime shifts for a stiff reservoir embedded in a softer layered model based on velocity profiles from the Valhall Field in the North Sea. Despite producing discontinuities in strain across medium interfaces, horizontal layering does not substantially alter the overall behaviour of traveltime shifts. The most pronounced offset variation of traveltime shifts is observed for overburden events recorded at common midpoints close to the reservoir edges. On the whole, prestack analysis of traveltime shifts should help better constrain compaction‐induced velocity perturbations in the presence of realistic background heterogeneity.     

An Anisotropic Cosmic-Ray Enhancement Event on 07-June-2015: A Possible Origin

A usual event, called anisotropic cosmic-ray enhancement (ACRE), was observed as a small increase (\({\leq}\,5\%\)) in the count rates of polar neutron monitors during 12?–?19 UT on 07 June 2015. The enhancement was highly anisotropic, as detected only by neutron monitors with asymptotic directions in the southwest quadrant in geocentric solar ecliptic (GSE) coordinates. The estimated rigidity of the corresponding particles is \({\leq}\,1\) GV. No associated detectable increase was found in the space-borne data from the Geostationary Operational Environmental Satellite (GOES), the Energetic and Relativistic Nuclei and Electron (ERNE) on board the Solar and Heliospheric Observatory (SOHO), or the Payload for Antimatter Matter Exploration and Light-nuclei Astrophysics (PAMELA) instruments, whose sensitivity was not sufficient to detect the event. No solar energetic particles were present during that time interval. The heliospheric conditions were slightly disturbed, so that the interplanetary magnetic field strength gradually increased during the event, followed by an increase of the solar wind speed after the event. It is proposed that the event was related to a crossing of the boundary layer between two regions with different heliospheric parameters, with a strong gradient of low-rigidity (\({<}\,1\) GV) particles. It was apparently similar to another cosmic-ray enhancement (e.g., on 22 June 2015) that is thought to have been caused by the local anisotropy of Forbush decreases, with the difference that in our case, the interplanetary disturbance was not observed at Earth, but passed by southward for this event.     

Origin and Evolution of Silicic Magmatism at Yellowstone Based on Ion Microprobe Analysis of Isotopically Zoned Zircons

The origin of large-volume Yellowstone ignimbrites and smaller-volumeintra-caldera lavas requires shallow remelting of enormous volumesof variably ¹⁸O-depleted volcanic and sub-volcanic rocks alteredby hydrothermal activity. Zircons provide probes of these processesas they preserve older ages and inherited ¹⁸O values. This studypresents a high-resolution, oxygen isotope examination of volcanismat Yellowstone using ion microprobe analysis with an averageprecision of ± 0·2 and a 10 µm spot size.We report 357 analyses of cores and rims of zircons, and isotopeprofiles of 142 single zircons in 11 units that represent majorYellowstone ignimbrites, and post-caldera lavas. Many zirconsfrom these samples were previously dated in the same spots bysensitive high-resolution ion microprobe (SHRIMP), and all zirconswere analyzed for oxygen isotope ratios in bulk as a functionof grain size by laser fluorination. We additionally reportoxygen isotope analyses of quartz crystals in three units. Theresults of this work provide the following new observations.(1) Most zircons from post-caldera low-¹⁸O lavas are zoned,with higher ¹⁸O values and highly variable U–Pb ages inthe cores that suggest inheritance from pre-caldera rocks exposedon the surface. (2) Many of the higher-¹⁸O zircon cores in theselavas have U–Pb zircon crystallization ages that postdatecaldera formation, but pre-date the eruption age by 10–20kyr, and represent inheritance of unexposed post-caldera sub-volcanicunits that have ¹⁸O similar to the Lava Creek Tuff. (3) Youngand voluminous 0·25–0·1 Ma intra-calderalavas, which represent the latest volcanic activity at Yellowstone,contain zircons with both high-¹⁸O and low-¹⁸O cores surroundedby an intermediate-¹⁸O rim. This implies inheritance of a varietyof rocks from high-¹⁸O pre-caldera and low-¹⁸O post-calderaunits, followed by residence in a common intermediate-¹⁸O meltprior to eruption. (4) Major ignimbrites of Huckleberry Ridge,and to a lesser extent the Lava Creek and Mesa Falls Tuffs,contain zoned zircons with lower-¹⁸O zircon cores, suggestingthat melting and zircon inheritance from the low-¹⁸O hydrothermallyaltered carapace was an important process during formation ofthese large magma bodies prior to caldera collapse. (5) The¹⁸O zoning in the majority of zircon core–rim interfacesis step-like rather than smoothly inflected, suggesting thatprocesses of solution–reprecipitation were more importantthan intra-crystalline oxygen diffusion. Concave-downward zirconcrystal size distributions support dissolution of the smallercrystals and growth of rims on larger crystals. This study suggeststhat silicic magmatism at Yellowstone proceeded via rapid, shallow-levelremelting of earlier erupted and hydrothermally altered Yellowstonesource rocks and that pulses of basaltic magma provided theheat for melting. Each post-caldera Yellowstone lava representsan independent homogenized magma batch that was generated rapidlyby remelting of source rocks of various ages and ¹⁸O values.The commonly held model of a single, large-volume, super-solidus,mushy-state magma chamber that is periodically reactivated andproduces rhyolitic offspring is not supported by our data. Rather,the source rocks for the Yellowstone volcanism were cooled belowthe solidus, hydrothermally altered by heated meteoric watersthat caused low ¹⁸O values, and then remelted in distinct pocketsby intrusion of basic magmas. Each packet of new melt inheritedzircons that retained older age and ¹⁸O values. This interpretationmay have significance for interpreting seismic data for crustallow-velocity zones in which magma mush and solidified areasexperiencing hydrothermal circulation occur side by side. Newbasalt intrusions into this solidifying batholith are requiredto form the youngest volcanic rocks that erupted as independentrhyolitic magmas. We also suggest that the Lava Creek Tuff magmawas already an uneruptable mush by the time of the first post-calderaeruption after 0·1 Myr of the climactic caldera-formingeruption. KEY WORDS: Yellowstone; oxygen isotopes; geochronology; isotope zoning; zircon; U–Pb dating; caldera; rhyolite; ion microprobe     

Magmatic Differentiation at an Island-arc Caldera: Okmok Volcano, Aleutian Islands, Alaska

Okmok volcano is situated on oceanic crust in the central Aleutianarc and experienced large (15 km³) caldera-forming eruptionsat 12 000 years BP and 2050 years BP. Each caldera-forming eruptionbegan with a small Plinian rhyodacite event followed by theemplacement of a dominantly andesitic ash-flow unit, whereaseffusive inter- and post-caldera lavas have been more basaltic.Phenocryst assemblages are composed of olivine + pyroxene +plagioclase ± Fe–Ti oxides and indicate crystallizationat 1000–1100°C at 0·1–0·2 GPain the presence of 0–4% H₂O. The erupted products followa tholeiitic evolutionary trend and calculated liquid compositionsrange from 52 to 68 wt % SiO₂ with 0·8–3·3wt % K₂O. Major and trace element models suggest that the moreevolved magmas were produced by 50–60% in situ fractionalcrystallization around the margins of the shallow magma chamber.Oxygen and strontium isotope data (¹⁸O 4·4–4·9,⁸⁷Sr/ ⁸⁶Sr 0·7032–0·7034) indicate interactionwith a hydrothermally altered crustal component, which led toelevated thorium isotope ratios in some caldera-forming magmas.This compromises the use of uranium–thorium disequilibria[(²³⁰Th/ ²³⁸U) = 0·849–0·964] to constrainthe time scales of magma differentiation but instead suggeststhat the age of the hydrothermal system is 100 ka. Modellingof the diffusion of strontium in plagioclase indicates thatmany evolved crystal rims formed less than 200 years prior toeruption. This addition of rim material probably reflects theremobilization of crystals from the chamber margins followingreplenishment. Basaltic recharge led to the expansion of themagma chamber, which was responsible for the most recent caldera-formingevent. KEY WORDS: Okmok; caldera; U-series isotopes; Sr-diffusion; time scales; Aleutian arc     

Complex coastal change in response to autogenic basin infilling: An example from a sub‐tropical Holocene strandplain

Thick bay‐fill sequences that often culminate in strandplain development serve as important sedimentary archives of land–ocean interaction, although distinguishing between internal and external forcings is an ongoing challenge. This study employs sediment cores, ground‐penetrating radar surveys, radiocarbon dates, palaeogeographic reconstructions and hydrodynamic modelling to explore the role of autogenic processes – notably a reduction in wave energy in response to coastal embayment infilling – in coastal evolution and shoreline morphodynamics. Following a regional 2 to 4 m highstand at ca 5·8 ka, the 75 km² Tijucas Strandplain in southern Brazil built from fluvial sediments deposited into a semi‐enclosed bay. Holocene regressive deposits are underlain by fluvial sands and a Pleistocene transgressive–regressive sequence, and backed by a highstand barrier‐island. The strandplain is immediately underlain by 5 to 16 m of seaward‐thickening, fluvially derived, Holocene‐age, basin‐fill mud. Several trends are observed from the landward (oldest) to the seaward (youngest) sections of the strandplain: (i) the upper shoreface and foreshore become finer and thinner and shift from sand‐dominated to mud‐dominated; (ii) beachface slopes decrease from >11° to ca 7°; and (iii) progradation rates increase from 0·4 to 1·8 m yr^?1. Hydrodynamic modelling demonstrates a correlation between progressive shoaling of Tijucas Bay driven by sea‐level fall and sediment infilling and a decrease in onshore wave‐energy transport from 18 to 4 kW m^?1. The combination of allogenic (sediment supply, falling relative sea‐level and geology) and autogenic (decrease in wave energy due to bay shoaling) processes drove the development of a regressive system with characteristics that are rare, if not unique, in the Holocene and rock records. These findings demonstrate the complexities in architecture styles of highstand and regressive systems tracts. Furthermore, this article highlights the diverse internal and external processes and feedbacks responsible for the development of these intricate marginal marine sedimentary systems.     

A new Early–Middle Weichselian palaeoenvironmental record from a lacustrine sequence at Svirkanciai,Lithuania

The Middle Weichselian (OIS 4‐3) and the transition from Early to Middle Weichselian are the most problematic and disputed time intervals of the Late Pleistocene with regard to the palaeogeography of the Fennoscandian glaciations. The number of sites with sediments of Middle Weichselian age in the Baltic region is very limited. An extensive area (77 km²) of lacustrine sediments (sand, clay, silt with humus and interlayers of peat), under the relief‐forming Upper Weichselian till, was discovered in the vicinity of the Venta settlement, northwestern Lithuania, and named the Venta Palaeolacustrine Basin. The Svirkanciai outcrop (56°18′05″N, 22°53′00″E) (15 m in height) of this palaeobasin is composed of two sediment complexes of different genesis and age. The lower part consists of silt and very fine‐grained sand of lacustrine origin. According to palynological data, the lacustrine sediments accumulated under boreo‐arctic climatic conditions. The pollen records suggest that local vegetation was sparse forest with open areas. An Optically Stimulated Luminescence (OSL) date of the lacustrine sand yielded an age of >79±6 ka, which indicates that lacustrine conditions may have occurred during part of the Early Weichselian Odderade Interstadial (Jonionys 2). However, the palynological data from Svirkanciai suggest a Middle Weichselian age, possibly correlating with the Oerel Interstadial (Jonionys 3) 55 ka ago. No traces of early Middle Weichselian Schalkholz (Nemunas 2a) stadial glacial advance have been found in the Venta sections. This also suggests a Middle Weichselian age for the Svirkanciai lacustrine sediments.