Some Statistics of the Temperature Structure Parameter in the Convective Boundary Layer Observed by Sodar

The characteristics of the temporal and height variations of the temperature structure parameter $C_\mathrm{T}^{2}$ in strongly convective situations derived from the sodar echo-signal intensity measurements were analyzed for the first 100 m. It was corroborated that the probability density function (pdf) of the logarithm of $C_\mathrm{T}^{2}$ in the lower convective boundary layer is markedly non-Gaussian, whereas turbulence theory predicts it to be normal. It was also corroborated that the sum of two weighted Gaussians, which characterize the statistics of $C_\mathrm{T}^{2}$ within convective plumes and in their environment and the probability of plume occurrence, well approximates the observed pdfs. It was shown that the height behaviour of the arithmetic mean of $ C_\mathrm{T}^{2}$ (both total and within plumes) follows well a power law $C_\mathrm{T}^{2} (z) \sim z^{-q}$ with the exponent $q$ close to the theoretically predicted value of 4/3. But for the geometrical means of $C_\mathrm{T}^{2}$ (both total and within the plumes), $q$ is close to 1. The difference between arithmetically and geometrically averaged $C_\mathrm{T}^{2}$ profiles was analyzed. The vertical profiles of the standard deviation, skewness and kurtosis of $\hbox {ln}C_\mathrm{T}^{2}$ pdfs were analyzed to show their steady behaviour with height. The standard deviations of the logarithm of $C_\mathrm{T}^{2}$ within the plumes and between them are similar and are 1.5 times less than the total standard deviation. The estimate of the variability index $F_\mathrm{T}$ and its height behaviour were obtained, which can be useful to validate some theoretical and modelling predictions. The vertical profiles of the skewness and kurtosis show the negative asymmetry of pdfs and their flatness, respectively. The spectra of variations in $\hbox {ln}C_\mathrm{T}^{2}$ are shown to be satisfactorily fitted by the power law $f^{-\gamma } $ in the frequency range 0.02 and 0.2 Hz, with the average exponent $\approx $ 1.27  $\pm $  0.22.     

Monitoring a Marine Coastal Area: Use of Mytilus galloprovincialis and Mullus barbatus as Bioindicators

Abstract. Samples of Mytilus galloprovincialis and Mullus barbatus were collected in eight coastal sites along the South Adriatic and Ionic coasts of Italy in spring 2000 for a survey of coastal pollution in the Mediterranean basin. Specimens were analysed using an integrated approach based on residue analysis of common aquatic pollutants like organochlorines such as hexachlorobenzene (HCB), DDTs and polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), heavy metals and nonylphenols (NPnE) and biomarker responses such as acetylcholinesterase (AChE) activity, and the two specific P450 activities benzo(a)pyrene monooxygenase (BPMO) and 7-ethoxyre-sorufin-(9-deethylase (EROD). Biological and morphological parameters like somatic liver index (SLI), gonadosomatic index (GSI) and gonadal and gamete histology (eggs and sperms) were also evaluated in red mullet samples. A contamination gradient in which several hot spots occur were revealed in this study. The hot spots account for high levels of organochlorines in both species near incinerators and of PAHs in harbour areas. Levels of both NPnE and AChE activity were highest in two protected marine areas and were within detectable limits in others. This finding was confirmed by P450 activities, in which maximum levels were detected in harbours and protected marine areas. No morphological alterations of male and female gonads were observed on the histological level.     

Spatial variability of Posidonia oceanica (L.) Delile epiphytes around the mainland and the islands of Sicily (Mediterranean Sea)

This paper investigates patterns of variability in epiphytes of Posidonia oceanica leaves at various spatial scales around Sicily, including geographical differences among the Mediterranean basins, differences between the small islands and mainland, and the variability among and within replicated meadows in each of the previous conditions. Data on percentage cover of the most common epiphytic organisms were analysed by univariate techniques. Encrusting red algae, encrusting brown algae, filamentous algae, encrusting bryozoans, erect bryozoans, hydroids and Foraminifera were the most abundant taxa. Significant differences in the abundance of taxa were detected among geographical regions, while no significant differences were found between the islands and mainland. At smaller scales, variability was concentrated mostly among leaves 100s of centimetres apart and among meadows a few kilometres apart. These results suggest that both geographical and local processes are important in structuring the epiphytes of P. oceanica leaves in this area of the Mediterranean.     

The growth of “black crusts” on calcareous building stones in Palermo (Sicily): a first appraisal of anthropogenic and natural sulphur sources

Chemical, mineralogical and isotopic composition (³⁴S/³²S) analyses were carried out on “black crusts” developed on the old buildings of Palermo (Sicily) with the aim to distinguish between natural and anthropogenic sulphur sources. Furthermore individual samples of total suspended particulate (TSP) were collected and analysed in order to estimate the influence of air pollution on the decay process of calcareous stones in a typical southern Mediterranean coastal environment. SEM/EDS analysis, X-ray diffractometry, IR spectroscopy and liquid chromatography led to the compositional characterization of “black crusts” and airborne particulate matter in the city. Sulphur isotopic compositions of gypsum-bearing crusts showed a prevailing contribution of anthropogenic sources (vehicle exhaust and other combustion processes). Natural sulphur and/or sulphate sources (biogenic and/or sea-spray) were shown to play a secondary role. These data can be considered a starting point for the determination of the rate of growth of “black crusts” in a coastal Mediterranean urban environment like Palermo. In the future, they might be useful to local authorities for planning more efficient maintenance action in order to slow as much as possible the rate of decay of the monumental heritage of the city.     

Self-standing bent silicon crystals for very high efficiency Laue lens

Silicon mono-crystals have been bent thanks to a series of parallel superficial indentations on one of the largest faces of the crystals. This technique relies on irreversible compression of the crystal beneath and beside the indentations. This latter causes deformation with no need for external device, resulting in a uniform self-standing curvature within the crystal. Indented Si crystals have been characterized at European Synchrotron Radiation Facility using a monochromatic beam ranging from 150 to 700 keV. Crystals exhibited very high diffraction efficiency over a broad range of energy, peaking 95% at 150 keV. Measured angular spread of the diffracted beam was always very close to the morphological curvature of the sample under investigation, proving that the energy passband of bent crystals can be controlled by simply imparting a selected curvature to the sample. The method of superficial indentations was found to offer high reproducibility and easy control of diffraction properties of the crystals. Moreover the method is cheap and simple, being based on mass production tools. A Laue lens made of crystals bent by superficial indentations can provide high-efficiency concentration of hard x-ray photons, leading significant improvement in many astrophysical applications.     

Global sensitivity analysis through polynomial chaos expansion of a basin-scale geochemical compaction model

We present a model-driven uncertainty quantification methodology based on sparse grid sampling techniques in the context of a generalized polynomial chaos expansion (GPCE) approximation of a basin-scale geochemical evolution scenario. The approach is illustrated through a one-dimensional example involving the process of quartz cementation in sandstones and the resulting effects on the dynamics of the vertical distribution of porosity, pressure, and temperature. The proposed theoretical framework and computational tools allow performing an efficient and accurate global sensitivity analysis (GSA) of the system states (i.e., porosity, temperature, pressure, and fluxes) in the presence of uncertain key mechanical and geochemical model parameters as well as boundary conditions. GSA is grounded on the use of the variance-based Sobol indices. These allow discriminating the relative weights of uncertain quantities on the global model variance and can be computed through the GPCE of the model response. Evaluation of the GPCE of the model response is performed through the implementation of a sparse grid approximation technique in the space of the selected uncertain quantities. GPCE is then be employed as a surrogate model of the system states to quantify uncertainty propagation through the model in terms of the probability distribution (and its statistical moments) of target system states.     

Late‐Pleistocene Wedge Structures Along the Patagonian Coast (Argentina): Chronological Constraints and Palaeo‐Environmental Implications

This paper investigates several wedge structures formed in continental deposits covering marine sediments deposited during MIS 5 along the central Patagonian coast of Argentina. The size and surface microtexture characteristics of the infilling sediments are consistent with a depositional environment dominated by aeolian transport. Fragments of Andean volcanic rocks (glass shards) in the wedge‐fill suggest long‐distance transport via a westerly component of wind direction. The wedges are interpreted as products of deep seasonal frost action in frozen ground, which produced open cracks that filled rapidly with partially non‐local aeolian sediments. Many wedges cross cut carbonate crusts that formed under permafrost conditions in coastal Patagonia. The radiocarbon dating of carbonate crusts yielded an age of 25–27 kyr bp , while wedge‐fill sediments are OSL dated to 14 670 ± 750 yr bp . This indicates that ground wedge formation occurred during a cold event (the Antarctic Cold Reversal period) that interrupted the permafrost degradation following the Last Glacial Maximum.     

Period-luminosity relations for Cepheid variables: from mid-infrared to multi-phase

This paper discusses two aspects of current research on the Cepheid period-luminosity (P-L) relation: the derivation of mid-infrared (MIR) P-L relations and the investigation of multi-phase P-L relations.     

Wavy Vertical Motions in the ABL Observed by Sodar

Some characteristics of wavelike motions in the atmospheric boundary layer observed by sodar are considered. In an experiment carried out in February 1993 in Milan, Italy, Doppler sodar measurements were accompanied by in situ measurements of temperature and wind velocity vertical profiles using a tethered balloon up to 600 m. The oscillations of elevated wavy layers containing intense thermal turbulence, usually associated with temperature-inversion zones, were studied by using correlation and spectral analysis methods. The statistics of the occurrence of wavelike and temperature-inversion events are presented. The height distributions of Brunt–Vaisala frequency and wind shear and their correlation within elevated inversion layers were determined, with a strong correlation observed between the drift rate of the wavy layers and the vertical velocity measured by Doppler sodar inside these layers. Spectral analysis showed similarities regarding their frequency characteristics. The phase speed and propagation direction of waves were estimated from the time delay of the signals at three antennae to provide estimates of wavelength. Moreover, wavelengths were estimated from the intrinsic frequency obtained from sodar measurements of the Doppler vertical velocity and oscillations of wavy turbulent layers. The two wavelength estimates are in good agreement.     

Tectonics,sea-level changes and palaeoenvironments in the early Pleistocene of Rome (Italy)

The historical site of the Monte Mario lower Pleistocene succession (Rome, Italy) is an important marker of the Pliocene/Pleistocene boundary. Recently, the Monte Mario site was excavated and restudied. A spectacular angular unconformity characterizes the contact between the Monte Vaticano and the Monte Mario formations, which marks the Pliocene/Pleistocene boundary. Biostratigraphical analyses carried out on ostracod, foraminifer, and calcareous nannofossil assemblages indicate an Early Pliocene age (topmost Zanclean, 3.81–3.70 Ma) for the underlying Monte Vaticano Formation, whereas the Monte Mario Formation has been dated as early Pleistocene (Santernian, 1.66–1.59 Ma). Palaeomagnetic analyses point to C2Ar and C1r2r polarity chrons for the Monte Vaticano and the Monte Mario formations, respectively. The Monte Mario Formation consists of two obliquity-forced depositional sequences (MM1 and MM2) characterized by transgressive systems tracts of littoral marine environments at depths, respectively, of 40–80 m and 15–20 m. The data obtained from foraminifer and ostracod assemblages allow us to reconstruct early Pleistocene relative sea-level changes near Rome. At the Plio/Pleistocene transition, a relative sea-level drop of at least 260 m occurred, as a result of both tectonic uplift of the central Tyrrhenian margin and glacio-eustatic changes linked to early Pleistocene glaciation (Marine Isotope Stage 58).