Multiproxy record for the last 4500 years from Lake Shkodra (Albania/Montenegro)

A multi‐proxy record is presented for approximately the last 4500 cal a BP from Lake Shkodra, Albania/Montenegro. Lithological analyses, C/N ratio and δ¹³C of the organic and inorganic carbon component suggest that organic matter and bulk carbonate are predominantly authigenic. The δ¹⁸O record of bulk carbonate indicates the presence of two prominent wet periods: one at ca. 4300 cal a BP and one at ca. 2500–2000 cal a BP. The latter phase is also found in southern Spain and Central Italy, and represents a prominent event in the western and central Mediterranean. In the last 2000 years, four relatively wet intervals occurred between ca. 1800 and 1500 cal a BP (150–450 AD), 1350–1250 (600–700 AD), 1100–800 (850–1150 AD), and at ca. 90 cal a BP (1860 AD). Between ca. 4100 and 2500 cal a BP δ¹⁸O values are relatively high, with three prominent peaks indicating drier conditions at ca. 4100–4000 cal a BP, ca. 3500 and at ca. 3300 cal a BP. Four additional drier events are identified at 1850 (ca. 100 AD), 1400 (ca. 550 AD), 1150 (800 AD) and ca.750 cal a BP (1200 AD). The pollen record does not show changes in accordance with these episodes owing to the poor sensitivity of vegetation in this area, which is dominated by an orographic rainfall effect and where changes in altitudinal vegetation belts do not affect the pollen rain in the lake catchment. However, since ca. 900 cal a BP a significant decrease in the percentage arboreal pollen and in pollen concentrations suggest major deforestation produced by human activities. Copyright © 2012 John Wiley & Sons, Ltd.     

Using helicopter electromagnetic data to predict groundwater quality in fractured crystalline bedrock in a semi-arid region, Northeast Brazil

Geostatistical modeling, using airborne and borehole electromagnetic data, was used to estimate electrical conductivity in groundwater within fractured paragneisses and migmatites in a semi-arid climate in northeastern Brazil. Despite the geologic heterogeneity of crystalline aquifers, the use of high resolution helicopter electromagnetic (HEM) data enabled the characterization of groundwater electrical conductivity where data from drilled wells were insufficient. The tacit assumption is that HEM measurements can be used to relate rock electrical conductivity to groundwater electrical conductivity. In this study, the HEM data were used as an external drift variable in non-stationary estimation and stochastic simulation to identify the variability of groundwater electrical conductivity. Validation tests, comparing predicted values for groundwater conductivity with measurements in new wells, confirmed the success of these models in locating fresh groundwater sources in crystalline bedrock.     

A geostatistical approach for mapping and uncertainty assessment of geogenic radon gas in soil in an area of southern Italy

Spatial distribution of concentrations of radon gas in the soil is important for defining high risk areas because geogenic radon is the major potential source of indoor radon concentrations regardless of the construction features of buildings. An area of southern Italy (Catanzaro-Lamezia plain) was surveyed to study the relationship between radon gas concentrations in the soil, geology and structural patterns. Moreover, the uncertainty associated with the mapping of geogenic radon in soil gas was assessed. Multi-Gaussian kriging was used to map the geogenic soil gas radon concentration, while conditional sequential Gaussian simulation was used to yield a series of stochastic images representing equally probable spatial distributions of soil radon across the study area. The stochastic images generated by the sequential Gaussian simulation were used to assess the uncertainty associated with the mapping of geogenic radon in the soil and they were combined to calculate the probability of exceeding a specified critical threshold that might cause concern for human health. The study showed that emanation of radon gas radon was also dependent on geological structure and lithology. The results have provided insight into the influence of basement geochemistry on the spatial distribution of radon levels at the soil/atmosphere interface and suggested that knowledge of the geology of the area may be helpful in understanding the distribution pattern of radon near the earth’s surface.     

Esterase activities in the bivalve mollusc Adamussium colbecki as a biomarker for pollution monitoring in the Antarctic marine environment

Marine environments are continuously being threatened by a large number of xenobiotics from anthropogenic sources. Even in sparsely populated and relatively pristine areas, such as Antarctica, hazardous chemicals can pose a serious environmental problem. The main aims of the present study were to (1) validate and optimize an analytical technique utilizing a microtitre-plate photometer to ascertain background levels of esterase activities in the Antarctic bivalve Adamussium colbecki, (2) carry out in situ monitoring of esterase activities to assess any potential environmental impacts of the Italian Scientific Antarctic Base "Terra Nova Bay" on the surrounding marine area. Results showed the presence of organophosphorous-sensitive cholinesterase (ChE) and carboxylesterase (CbE) activities in the gills of A. colbecki and optimal assay conditions were comparable with those found for bivalve species from temperate areas. A higher sensitivity of ChE versus acetylthiocholine activity in A. colbecki to chlorpyrifos compared to species from temperate areas may also be inferred. The in situ study indicated no differences in the environmental quality of the three study sites located around the Italian Base.     

Strike-slip faulting as a trigger mechanism for overpressure release through piercement structures. Implications for the Lusi mud volcano,Indonesia

Piercement structures such as hydrothermal vent complexes, pockmarks, and mud volcanoes, are found in various geological settings but are often associated with faults or other fluid-focussing features. This article aims to investigate and understand the mechanisms responsible for the formation of piercement structures in sedimentary basins and the role of strike-slip faulting as a triggering mechanism for fluidization. For this purpose four different approaches were combined: fieldwork, analogue experiments, and mathematical modeling for brittle and ductile rheologies. The results of this study may be applied to several geological settings, including the newly formed Lusi mud volcano in Indonesia (Mazzini et al., 2007).     

Observed and Modelled Convective Mixing-Layer Height at Dome C,Antarctica

The mixing-layer height is estimated using measurements from a high resolution surface-layer sodar run at the French-Italian station of Concordia at Dome C, Antarctica during the summer 2011–2012. The temporal and spatial resolution of the sodar allows the monitoring of the mixing-layer evolution during the whole diurnal cycle, i.e. a very shallow nocturnal boundary layer followed by a typical daytime growth. The behaviour of the summer mixing-layer height, variable between about 10- and 300 m, is analyzed as a function of the mean and turbulent structure of the boundary layer. Focusing on convective cases only, the retrieved values are compared with those calculated using a one-dimensional prognostic equation. The role of subsidence is examined and discussed. We show that the agreement between modelled and experimental values significantly increases if the subsidence is not kept fixed during the day. A simple diagnostic equation, which depends on the time-averaged integral of the near-surface turbulent heat flux, the background static stability and the buoyancy parameter, is proposed and evaluated. The diagnostic relation performance is comparable to that of the more sophisticated prognostic model.     

Interpreting the role of proximity on Industrial District competitiveness using a complexity science-based view and Systems Dynamics simulation

The paper investigates how proximity affects Industrial District competitiveness. We adopt the complexity theory by analyzing the influence of the proximity on the Industrial District adaptive capacity. Our argument in fact is that the more adaptive the Industrial District, the more the competitive success. Based on the complexity theory, we identify the structural features that allow Industrial District adaptation and their best values. Then, by developing a computational model based on the Systems Dynamics, we conduct a simulation analysis to evaluate the influence of proximity on the values of Industrial District structural features affecting its adaptive capacity. Results show that too much proximity is detrimental for the Industrial District competitiveness.     

A review of near-surface QS estimation methods using active and passive sources

Journal of Seismology - Seismic attenuation and the associated quality factor (Q) have long been studied in various sub-disciplines of seismology, ranging from observational and engineering...     

A continuous stable isotope record from the penultimate glacial maximum to the Last Interglacial (159–121 ka) from Tana Che Urla Cave (Apuan Alps,central Italy)

Relatively few radiometrically dated records are available for the central Mediterranean spanning the marine oxygen isotope stage 6–5 (MIS 6–5) transition and the first part of the Last Interglacial. Two flowstone cores from Tana che Urla Cave (TCU, central Italy), constrained by 19 U/Th ages, preserve an interval of continuous speleothem deposition between ca. 159 and 121 ka. A multiproxy record (δ¹⁸O, δ¹³C, growth rate and petrographic changes) obtained from this flowstone preserves significant regional-scale hydrological changes through the glacial/interglacial transition and multi-centennial variability (interpreted as alternations between wetter and drier periods) within both glacial and interglacial stages. The glacial stage shows a wetter period between ca. 154 and 152 ka, while the early to middle Last Interglacial period shows several drying events at ca. 129, 126 and 122 ka, which can be placed in the wider context of climatic instability emerging from North Atlantic marine and NW European terrestrial records. The TCU record also provides important insights into the evolution of local environmental conditions (i.e. soil development) in response to regional and global-scale climate events.