Highly siderophile element geochemistry of Os-enriched 2.8 Ga Kostomuksha komatiites, Baltic Shield

New analyses of highly siderophile elements (HSE; Re, Os, Ir, Ru, Pt, and Pd) obtained by Carius tube digestion isotope dilution inductively coupled plasma mass-spectrometry (ID-ICPMS) technique are reported for ¹⁸⁷Os-enriched 2.8 Ga komatiites from the Kostomuksha greenstone belt. As a result of a significant improvement in the yield over our previous digestions by the NiS fire-assay technique, these komatiites have now been shown to contain 22 to 25% more Os, Ir, and Pt and 34% more Ru. The emplaced komatiite lavas at Kostomuksha thus had siderophile element abundances comparable to those of the Abitibi belt. The discrepancies observed between the two techniques are interpreted to be the result of incomplete digestion of HSE carriers (particularly chromite) during the NiS fire-assay procedure. Our results for UB-N peridotite reference material agree well with those obtained by the high-pressure ashing digestion ID-ICPMS technique reported in the literature. Two types of komatiite lavas have been distinguished in this study based on the IPGE (Os, Ir, and Ru) behavior during lava differentiation. The Kostomuksha type is unique and is characterized by an incompatible behavior of IPGEs, with bulk solid-liquid partition coefficients for IPGEs being close to those for olivine. Cumulate zones in this type of komatiite lava occupy <20% of the total thickness of the flows. The Munro type exhibits a compatible behavior of IPGEs during lava differentiation. The cumulate zone in this type of komatiite occupies >20% of the total thickness of the flows. The calculated bulk partition coefficients indicate that, as with the other Munro-type komatiite lavas, the bulk cumulate contained an IPGE-rich minor phase(s) in addition to olivine. The non-CI chondritic HSE pattern for the source of the Kostomuksha komatiites calculated here is similar to that of Abitibi komatiites and to average depleted spinel lherzolite (ADSL) and supports the hypothesis of a non-CI chondritic HSE composition of the Earth’s mantle. The absolute HSE abundances in the source of the Kostomuksha komatiite have been demonstrated to be comparable to those of the source of Abitibi komatiites, even though the two komatiites contrast in their Os isotopic compositions. This supports the earlier hypothesis that if core-mantle interaction produced the ¹⁸⁷Os/¹⁸⁸Os radiogenic signature in the Kostomuksha source, it must have occurred in the form of isotope exchange at the core-mantle boundary. Other explanations of the radiogenic Os signature are similarly constrained to conserve the elemental abundance pattern in the mantle source of Kostomuksha komatiites.     

The response in floodplain respiration of an alpine river to experimental inundation under different temperature regimes

The respiratory potential [i.e. electron transport system activity (ETSA)] of soils and sediments from five floodplain habitats (channel, gravel, islands, riparian forest and grassland) of the Urbach River, Switzerland, and actual respiration rate (R) of the same samples exposed to experimental inundation were measured. Measurements were carried out at three incubation temperatures (4°C, 12°C and 20°C), and ETSA/R ratios (i.e. exploitation of the overall metabolic capacity) were investigated to better understand the effects of temperature and inundation on floodplain functional heterogeneity. Furthermore, ETSA/R ratios obtained during experimental inundation were compared with ETSA/R ratios from field measurements to investigate the exploitation in total metabolic potential at different conditions. Lowest ETSA and R were measured in samples from channel and gravel habitats, followed by those from islands. Substantially higher values were measured in soils from riparian forest and grassland. Both ETSA and R increased with increasing temperature in samples from all habitats, while the ETSA/R ratio decreased because of a rapid response in microbial community respiration to higher temperatures. The metabolic capacity exploitation (i.e. ETSA/R) during experimental inundation was lowest in predominantly terrestrial samples (riparian forest and grassland), indicating the weakest response to wetted conditions. Comparison of experimentally inundated and field conditions revealed that in rarely flooded soils, the metabolic capacity was less exploited during inundation than during non‐flooded conditions. The results suggest high sensitivity in floodplain respiration to changes in temperature and hydrological regime. ETSA/R ratios are considered good indicators of changes in metabolic activity of floodplain soils and sediments, and thus useful to estimate the impact of changes in hydrological regime or to evaluate success of floodplain restoration actions. Copyright © 2015 John Wiley & Sons, Ltd.     

Predicting the dependency of a degree of saturation on void ratio and suction using effective stress principle for unsaturated soils

The paper presents an approach to predicting variation of a degree of saturation in unsaturated soils with void ratio and suction. The approach is based on the effective stress principle for unsaturated soils and several underlying assumptions. It focuses on the main drying and wetting processes and does not incorporate the effects of hydraulic hysteresis. It leads to the dependency of water retention curve (WRC) on void ratio, which does not require any material parameters apart from the parameters specifying WRC for the reference void ratio. Its validity is demonstrated by comparing predictions with the experimental data on four different soils taken over from the literature. Good correlation between the measured and predicted behaviour indirectly supports applicability of the effective stress principle for unsaturated soils. Copyright © 2009 John Wiley & Sons, Ltd.     

Root‐related rhodochrosite and concretionary siderite formation in oxygen‐deficient conditions induced by a ground‐water table rise

Sedimentological, mineralogical, stable carbon and oxygen isotope determinations and biomarker analyses were performed on siderite concretions occurring in terrestrial silts to understand their formation and to characterize the sedimentary and diagenetic conditions favouring their growth. High δ¹³C values (6·4‰ on average) indicate that siderite precipitated in an anoxic environment where bacterial methanogenesis operated. The development of anoxic conditions during shallow burial was induced by a change in sedimentary environment from flood plain to swamp, related to a rise of the ground‐water table. Large amounts of decaying plant debris led to efficient oxygen consumption within the pore‐water in the peat. Oxygen depletion, in combination with a decrease in sedimentation rate, promoted anoxic diagenetic conditions under the swamp and favoured abundant siderite precipitation. This shows how a change in sedimentary conditions can have a profound impact on the early‐diagenetic environment and carbonate authigenesis. The concretions contain numerous rhizoliths; they are cemented with calcium‐rhodochrosite, a feature which has not been reported before. The rhodochrosite cement has negative δ¹³C values (?16·5‰ on average) and precipitated in suboxic conditions due to microbial degradation of roots coupled to manganese reduction. The exceptional preservation of the epidermis/exodermis and xylem vessels of former root tissues indicates that the rhodochrosite formed shortly after the death of a root in water‐logged sediments. Rhodochrosite precipitated during the initial stages of concretionary growth in suboxic microenvironments within roots, while siderite cementation occurred simultaneously around them in anoxic conditions. These suboxic microenvironments developed because oxygen was transported from the overlying oxygenated soil into sediments saturated with anoxic water via roots acting as permeable conduits. This model explains how separate generations of carbonate cements having different mineralogy and isotopic compositions, which would conventionally be regarded as cements precipitated sequentially in different diagenetic zones during gradual burial, can form simultaneously in shallow burial settings where strong redox gradients exist around vertically oriented permeable root structures.     

Convective and stratiform precipitation characteristics in an ensemble of regional climate model simulations

We apply a recently proposed algorithm for disaggregating observed precipitation data into predominantly convective and stratiform, and evaluate biases in characteristics of parameterized convective (subgrid) and stratiform (large-scale) precipitation in an ensemble of 11 RCM simulations for recent climate in Central Europe. All RCMs have a resolution of 25 km and are driven by the ERA-40 reanalysis. We focus on mean annual cycle, proportion of convective precipitation, dependence on altitude, and extremes. The results show that characteristics of total precipitation are often better simulated than are those of convective and stratiform precipitation evaluated separately. While annual cycles of convective and stratiform precipitation are reproduced reasonably well in most RCMs, some of them consistently and substantially overestimate or underestimate the proportion of convective precipitation throughout the year. Intensity of convective precipitation is underestimated in all RCMs. Dependence on altitude is also simulated better for stratiform and total precipitation than for convective precipitation, for which several RCMs produce unrealistic slopes. Extremes are underestimated for convective precipitation while they tend to be slightly overestimated for stratiform precipitation, thus resulting in a relatively good reproduction of extremes in total precipitation amounts. The results suggest that the examined ensemble of RCMs suffers from substantial deficiencies in reproducing precipitation processes and support previous findings that climate models’ errors in precipitation characteristics are mainly related to deficiencies in the representation of convection.     

Modeling Urban Land Use Changes Using Support Vector Machines

Support Vector Machines (SVM) is a machine learning (ML) algorithm commonly applied to the classification of remotely sensing data and more recently for modeling land use changes. However, in most geospatial applications the current literature does not elaborate on specifications of the SVM method with respect to data sampling, attribute selection and optimal parameters choices. Therefore the main objective of this study is to present and investigate the SVM technique for modeling urban land use change. The SVM model building procedure is presented together with the detailed evaluation of the output results with respect to the choice of datasets, attributes and the change of SVM parameters. Geospatial datasets containing nine land use classes and spatial attributes for the Municipality of Zemun, Republic of Serbia were used for years 2001, 2003, 2007 and 2011. The Correlation‐based Feature Subset method, kappa coefficient, Area Under Receiver Operating Characteristic Curve (AUC) and kappa simulation were used to perform the model evaluation and compare the model outputs with the real land use datasets. The obtained results indicate that the SVM‐based models perform better when implementing balanced data sampling, reduced data sets to informative subsets of attributes and properly identify the optimal learning parameters.     

Stratigraphic and lithologic characteristics of Pleistocene fluvial deposits in the Danube and Sava riparian area near Belgrade (Serbia)

The Quaternary sediments in the Danube and Sava riparian area near Belgrade have a considerable thickness. Several categories of deposits (fluvial-lacustrine, fluvial and aeolian) of Pliocene and Quaternary age have been identified. Their thickness, granulometric composition and paleontological features change depending on the distance from the recent Danube and Sava riverbeds. The Pleistocene fluvial deposits are underlain by sediments of the Late Miocene (Sarmatian and Pannonian) or the Plio-Pleistocene age, and are overlain by fluvial-palustrine deposits of the Pleistocene age and recent alluvial deposits. Pleistocene fluvial deposits that form a major part of the Quaternary sediments, have a great significance, since they are proved to be excellent collectors of ground water. Although these deposits are at lower altitudes in the area of Srem, they could be correlated with the high Danube and Morava terraces in Serbia and Drava in Croatia on the basis of their lithologic and paleontological features.     

Effects of demand estimates on the evaluation and optimality of service centre locations

Public service systems, such as emergency health care, police or fire brigades, are critical for day-to-day functioning of the society. To design and operate these systems efficiently much data needs to be collected and properly utilised. Here, we use the OpenStreetMap (OSM) data to model the demand points (DPs), which approximate the geographical location of customers, and the road network, which is used to access or distribute services. We consider all inhabitants as customers, and therefore to estimate the demand, we use the available population grids. People are changing their location in the course of the day and thus the demand for services is changing accordingly. In this paper, we investigate how the used demand estimate affects the optimal design of a public service system. We calculate and compare efficient designs corresponding to two demand models, a night-time demand model when the majority of inhabitants rest at home and the demand model derived from the 24-hour average of the population density. We propose a simple measure to quantify the differences between population grids and we estimate how the size of differences affects the optimal structure of a public service system. Our analyses reveal that the efficiency of the service system is not only dependent on the placement strategy, but an inappropriate demand model has significant effects when designing a system as well as when evaluating its efficiency.     

Appraisal of changes in sewage sludge management

A positive energy balance caused by accelerated production of CH₄ and additional financial benefits associated with shorter retention times, reduction in volumes, easier dewatering, enhanced hygiene, etc., are the reasons why most modern wastewater treatment plants are newly equipped with hydrothermal pretreatment units. This study examined how the changes in composition of the pretreated sewage sludge fermentation residues manifested themselves in subsequent processing by pyrolysis, both in terms of technology and financial impacts. It has been found that concentrations of heavy metals and other hazardous inhibitors might increase; however, the overall biotoxicity is lower due to their immobilization in the charred mass. Moreover, charring of the fermentation residues results in significant financial as well as technological benefits.