6: Classification of VMS deposits: Lessons from the South Uralides

VMS deposits of the South Urals developed within the evolving Urals palaeo-ocean between Silurian and Late Devonian times. Arc-continent collision between Baltica and the Magnitogorsk Zone (arc) in the south-western Urals effectively terminated submarine volcanism in the Magnitogorsk Zone with which the bulk of the VMS deposits are associated. The majority of the Urals VMS deposits formed within volcanic-dominated sequences in deep seawater settings. Preservation of macro and micro vent fauna in the sulphide bodies is both testament to the seafloor setting for much of the sulphides but also the exceptional degree of preservation and lack of metamorphic overprint of the deposits and host rocks. The deposits in the Urals have previously been classified in terms of tectonic setting, host rock associations and metal ratios in line with recent tectono-stratigraphic classifications. In addition to these broad classes, it is clear that in a number of the Urals settings, an evolution of the host volcanic stratigraphy is accompanied by an associated change in the metal ratios of the VMS deposits, a situation previously discussed, for example, in the Noranda district of Canada.Two key structural settings are implicated in the South Urals. The first is seen in a preserved marginal allochthon west of the Main Urals Fault where early arc tholeiites host Cu–Zn mineralization in deposits including Yaman Kasy, which is host to the oldest macro vent fauna assembly known to science. The second tectonic setting for the South Urals VMS is the Magnitogorsk arc where study has highlighted the presence of a preserved early forearc assemblage, arc tholeiite to calc-alkaline sequences and rifted arc bimodal tholeiite sequences. The boninitc rocks of the forearc host Cu–(Zn) and Cu–Co VMS deposits, the latter hosted in fragments within the Main Urals Fault Zone (MUFZ) which marks the line of arc-continent collision in Late Devonian times. The arc tholeiites host Cu–Zn deposits with an evolution to more calc-alkaline felsic volcanic sequences matched with a change to Zn–Pb–Cu polymetallic deposits, often gold-rich. Large rifts in the arc sequence are filled by thick bimodal tholeiite sequences, themselves often showing an evolution to a more calc-alkaline nature. These thick bimodal sequences are host to the largest of the Cu–Zn VMS deposits.The exceptional degree of preservation in the Urals has permitted the identification of early seafloor clastic and hydrolytic modification (here termed halmyrolysis sensu lato) to the sulphide assemblages prior to diagenesis and this results in large-scale modification to the primary VMS body, resulting in distinctive morphological and mineralogical sub-types of sulphide body superimposed upon the tectonic association classification.It is proposed that a better classification of seafloor VMS systems is thus achievable using a three stage classification based on (a) tectonic (hence bulk volcanic chemistry) association, (b) local volcanic chemical evolution within a single edifice and (c) seafloor reworking and halmyrolysis.     

Left upstream slope design for the Çatalan Dam, Adana, Turkey and its behaviour under actual earthquake loading

An investigation and remediation of instability along upstream cut slopes for an earthfill dam in differentially weathered rock in southern Turkey is described. The major instability problem was a 45-m high and 200-m long previously cut slope next to the main axis of the dam, above the diversion tunnels and water outlet structures. The slope was first designed and excavated in 1986 based on the temporary berm approach. Rising water level in the reservoir would change the shear strength parameters and the pore-water pressure in the slope; thus, probable deep failure would damage the entrance of the diversion tunnels and water outlet structures, as well as the earthfill embankment of the dam. In June 1996, the slope face was re-excavated and protected against wave erosion by placement of a layer of rock riprap over a layer of bedding and a filter material. A strong earthquake (M_S = 6.2) occurred during a period of rapid drawdown in 27 June 1998. The slope remained stable, although numerous tension cracks developed in Quaternary terrace deposits near the reservoir area.     

Conditions of pocket formation in the Oktyabrskaya tourmaline-rich gem pegmatite (the Malkhan field, Central Transbaikalia, Russia)

Coexisting melt (MI), fluid-melt (FMI) and fluid (FI) inclusions in quartz from the Oktaybrskaya pegmatite, central Transbaikalia, have been studied and the thermodynamic modeling of PVTX-properties of aqueous orthoboric-acid fluids has been carried out to define the conditions of pocket formation. At room temperature, FMI in early pocket quartz and in quartz from the coarse-grained quartz–oligoclase host pegmatite contain crystalline aggregates and an orthoboric-acid fluid. The portion of FMI in inclusion assemblages decreases and the volume of fluid in inclusions increases from the early to the late growth zones in the pocket quartz. No FMI have been found in the late growth zones. Significant variations of solid/fluid ratios in the neighboring FMI result from heterogeneous entrapment of coexisting melts and fluids by a host mineral. Raman spectroscopy, SEM EDS and EMPA indicate that the crystalline aggregates in FMI are dominated by mica minerals of the boron-rich muscovite–nanpingite CsAl₂[AlSi₃O₁₀](OH,F)₂ series as well as lepidolite. Topaz, quartz, potassium feldspar and several unidentified minerals occur in much lower amounts. Fluid isolations in FMI and FI have similar total salinity (4–8 wt.% NaCl eq.) and H₃BO₃ contents (12–16 wt.%). The melt inclusions in host-pegmatite quartz homogenize at 570–600 °C. The silicate crystalline aggregates in large inclusions in pocket quartz completely melt at 615 °C. However, even after those inclusions were significantly overheated at 650±10 °C and 2.5 kbar during 24 h they remained non-homogeneous and displayed two types: (i) glass+unmelted crystals and (ii) fluid+glass. The FMI glasses contain 1.94–2.73 wt.% F, 2.51 wt.% B₂O₃, 3.64–5.20 wt.% Cs₂O, 0.54 wt.% Li₂O, 0.57 wt.% Ta₂O₅, 0.10 wt.% Nb₂O₅, 0.12 wt.% BeO. The H₂O content of the glass could exceed 12 wt.%. Such compositions suggest that the residual melts of the latest magmatic stage were strongly enriched in H₂O, B, F, Cs and contained elevated concentrations of Li, Be, Ta, and Nb. FMI microthermometry showed that those melts could have crystallized at 615–550 °C.

Crystallization of quartz–feldspar pegmatite matrix leads to the formation of H₂O-, B- and F-enriched residual melts and associated fluids (prototypes of pockets). Fluids of different compositions and residual melts of different liquidus–solidus P–T-conditions would form pockets with various internal fluid pressures. During crystallization, those melts release more aqueous fluids resulting in a further increase of the fluid pressure in pockets. A significant overpressure and a possible pressure gradient between the neighboring pockets would induce fracturing of pockets and “fluid explosions”. The fracturing commonly results in the crushing of pocket walls, formation of new fractures connecting adjacent pockets, heterogenization and mixing of pocket fluids. Such newly formed fluids would interact with a primary pegmatite matrix along the fractures and cause autometasomatic alteration, recrystallization, leaching and formation of “primary–secondary” pockets.     

Emplacement age and thermal footprint of the diamondiferous Ellendale E9 lamproite pipe, Western Australia

The diamondiferous Ellendale 9 (E9) pipe is a funnel-shaped maar-diatreme volcano consisting of inward-dipping tuff sequences intruded by lamproite plugs and dykes. The host rocks for the E9 pipe are Permian sandstones. The multiple lithological contacts exposed within the mined maar volcano provide a natural laboratory in which to study the effect of volcanic processes on U–Th–Pb–He systematics. Zircon from the regional sandstone and E9 lamproite display a bimodal distribution of ages on (U–Th)/He–U/Pb plots. The zircon U/Pb ages for the E9 pipe (n?=?52) range from 440 to 2,725 Ma, while the cluster of (U–Th)/He ages for the lamproite dyke zircon indicate that dyke emplacement occurred at 20.6?±?2.8 Ma, concordant with a maximum emplacement age of about ≤22 Ma from phlogopite ⁴⁰Ar/³⁹Ar. These ages indicate a xenocrystic origin for the zircon entrained in the E9 dyke. The U/Pb ages of detrital zircon from the regional sandstone host (373–3,248 Ma; n?=?41) are indistinguishable from those of the lamproite zircon xenocrysts, whereas the detrital zircon in the host sandstone yield (U–Th)/He ages from 260 to 1,500 Ma. A thermochronology traverse across the E9 lamproite dyke reveals that the zircon (U–Th)/He ages in the host sandstone have not been significantly thermally reset during dyke emplacement, even at the contact. The capability of the zircon (U–Th)/He method to distinguish deep, mantle source lithologies from upper crustal source lithologies could be used in geochemical exploration for diamonds. Pre-screening of detrital samples using etching and helium assay methods will improve the efficiency and decrease the cost of greenfields exploration.     

Spheroidal equal angular DEMs: The specificity of morphometric treatment

Digital elevation models (DEMs) are commonly constructed using two main types of regular grids: plane square grids and spheroidal equal angular grids. Methods and algorithms intended for plane square‐gridded DEMs should not be directly applied to spheroidal equal angular DEMs. This is because these grids have fundamentally different geometry. However, some researchers continue to apply square‐grid algorithms to spheroidal equal angular DEMs. It seems appropriate to consider once again the specifity of morphometric treatment of spheroidal equal angular DEMs. This article, first, demonstrates possibilities of direct calculation of local, nonlocal, and combined morphometric variables from spheroidal equal angular DEMs exemplified by slope gradient, catchment area, and topographic index. Second, the article shows computational errors when algorithms for plane square‐gridded DEMs are unreasonably applied to spheroidal equal angular DEMs. The study is exemplified by two DEMs. A medium‐resolution DEM of a relatively small, high‐mountainous area (Mount Elbrus) was extracted from the SRTM1 DEM. A low‐resolution DEM of a vast region with the diverse topography (the central and western regions of Kenya) was extracted from the SRTM30_PLUS DEM. The results show that application of square‐grid methods to spheroidal equal angular DEMs leads to substantial computational errors in models of morphometric variables.     

Predicting the dependency of a degree of saturation on void ratio and suction using effective stress principle for unsaturated soils

The paper presents an approach to predicting variation of a degree of saturation in unsaturated soils with void ratio and suction. The approach is based on the effective stress principle for unsaturated soils and several underlying assumptions. It focuses on the main drying and wetting processes and does not incorporate the effects of hydraulic hysteresis. It leads to the dependency of water retention curve (WRC) on void ratio, which does not require any material parameters apart from the parameters specifying WRC for the reference void ratio. Its validity is demonstrated by comparing predictions with the experimental data on four different soils taken over from the literature. Good correlation between the measured and predicted behaviour indirectly supports applicability of the effective stress principle for unsaturated soils. Copyright © 2009 John Wiley & Sons, Ltd.     

Convective and stratiform precipitation characteristics in an ensemble of regional climate model simulations

We apply a recently proposed algorithm for disaggregating observed precipitation data into predominantly convective and stratiform, and evaluate biases in characteristics of parameterized convective (subgrid) and stratiform (large-scale) precipitation in an ensemble of 11 RCM simulations for recent climate in Central Europe. All RCMs have a resolution of 25 km and are driven by the ERA-40 reanalysis. We focus on mean annual cycle, proportion of convective precipitation, dependence on altitude, and extremes. The results show that characteristics of total precipitation are often better simulated than are those of convective and stratiform precipitation evaluated separately. While annual cycles of convective and stratiform precipitation are reproduced reasonably well in most RCMs, some of them consistently and substantially overestimate or underestimate the proportion of convective precipitation throughout the year. Intensity of convective precipitation is underestimated in all RCMs. Dependence on altitude is also simulated better for stratiform and total precipitation than for convective precipitation, for which several RCMs produce unrealistic slopes. Extremes are underestimated for convective precipitation while they tend to be slightly overestimated for stratiform precipitation, thus resulting in a relatively good reproduction of extremes in total precipitation amounts. The results suggest that the examined ensemble of RCMs suffers from substantial deficiencies in reproducing precipitation processes and support previous findings that climate models’ errors in precipitation characteristics are mainly related to deficiencies in the representation of convection.