Links between observed micro-meteorological variability and land-use patterns in the highveld priority area of South Africa

Links between spatial and temporal variability of Planetary Boundary Layer meteorological quantities and existing land-use patterns are still poorly understood due to the non-linearity of air–land interaction processes. This study describes the results of a statistical analysis of meteorological observations collected by a network of ten Automatic Weather Stations. The stations were in operation in the highveld priority area of the Republic of South Africa during 2008–2010. The analysis revealed localization, enhancement and homogenization in the inter-station variability of observed meteorological quantities (temperature, relative humidity and wind speed) over diurnal and seasonal cycles. Enhancement of the meteorological spatial variability was found on a broad range of scales from 20 to 50?km during morning hours and in the dry winter season. These spatial scales are comparable to scales of observed land-use heterogeneity, which suggests links between atmospheric variability and land-use patterns through excitation of horizontal meso-scale circulations. Convective motions homogenized and synchronized meteorological variability during afternoon hours in the winter seasons, and during large parts of the day during the moist summer season. The analysis also revealed that turbulent convection overwhelms horizontal meso-scale circulations in the study area during extensive parts of the annual cycle.     

Geochronology of the medium to high-grade metamorphic units of the Peloritani Mts., Sicily

The Peloritani Mountains are a fragment of an orogen variably attributed to the Alpine or Hercynian orogeny. On the basis of ³⁹Ar-⁴⁰Ar, U-Pb and Rb-Sr dating, the main metamorphism of the two medium–high grade metamorphic units, the Mela and Aspromonte Units, and most of the thrusting responsible for stacking the orogenic edifice are seen to be Hercynian. The main thrusting of the Aspromonte Unit over the lower grade units took place at 301±2 Ma. Brittle deformation during Tertiary reactivation of Hercynian thrust planes did not generate any rejuvenation of white micas in the studied sector. Our dataset shows a great complexity and we propose to unravel it by considering different levels of information. To first order, the Mela and Aspromonte Units differ in their metamorphic paths and their geochronological evolution. The Mela Unit shows generally younger ages (Carboniferous) than the Aspromonte Unit and, unlike the latter, was extensively retrogressed in greenschist facies. The Aspromonte Unit is itself geochronologically heterogeneous. Proterozoic ages are preserved both in titanite and in amphibole relics of one tectonic subunit; Devonian to Carboniferous amphibole ages are found in different other subunits; tertiary overprint is minor and spatially limited. We propose to consider the chronologically heterogeneous subunits as accreted pre-Hercynian terranes amalgamated late during the Hercynian orogeny. Micas in both units give scattered Mesozoic ³⁹Ar-⁴⁰Ar and Rb-Sr ages, with evidence for heterochemical mica generations. We interpret them as a result of widespread hydrothermal circulation event(s). Tertiary overprint is generally absent, with the exception of a small area near Messina where biotite and muscovite underwent a complex recrystallisation history in the interval between 48 and 61 Ma.An erratum to this article can be found at     

Re-Os isotopic systematics and platinum group element composition of the Tagish Lake carbonaceous chondrite

The Tagish Lake meteorite is a primitive C2 chondrite that has undergone aqueous alteration shortly after formation of its parent body. Previous work indicates that if this type of material was part of a late veneer during terrestrial planetary accretion, it could provide a link between atmophile elements such as H, C, N and noble gases, and highly siderophile element replenishment in the bulk silicate portions of terrestrial planets following core formation. The systematic Re-Os isotope and highly siderophile element measurements performed here on five separate fractions indicate that while Tagish Lake has amongst the highest Ru/Ir (1.63 ± 0.08), Pd/Ir (1.19 ± 0.06) and ¹⁸⁷Os/¹⁸⁸Os (0.12564-0.12802) of all carbonaceous chondrites, these characteristics still fall short of those necessary to explain the observed siderophile element systematics of the primitive upper mantles of Earth and Mars. Hence, a direct link between atmophile and highly siderophile elements remains elusive, and other sources for replenishment are required, unless an as yet poorly constrained process fractionated Re/Os, Ru/Ir, and Pd/Ir following late accretion on both the Earth and Mars mantles.The unique elevated Ru/Ir combined with elevated ¹⁸⁷Os/¹⁸⁸Os of Tagish Lake may be attributed to Ru and Re mobility during aqueous alteration very early in its parent body history. The Os, Ir, Pt, and Pd abundances of Tagish Lake are similar to CI chondrites. The elevated Ru/Ir and the higher Re/Os and consequent ¹⁸⁷Os/¹⁸⁸Os in Tagish Lake, are balanced by a lower Ru/Ir and lower Re/Os and ¹⁸⁷Os/¹⁸⁸Os in CM-chondrites, relative to CI chondrites. A model that links Tagish Lake with CI and CM chondrites in the same parent body may explain the observed systematics. In this scenario, CM chondrite material comprises the exterior, grading downward to Tagish Lake material, which grades to CI material in the interior of the parent body. Aqueous alteration intensifies towards the interior with increasing temperature. Ruthenium and Re are mobilized from the CM layer into the Tagish Lake layer. This model may thus provide a potential direct parent body relationship between three separate groups of carbonaceous chondrites.     

Application of a Large-Eddy Simulation Database to Optimisation of First-Order Closures for Neutral and Stably Stratified Boundary Layers

Large-eddy simulation (LES) is a well-established numerical technique, resolving the most energetic turbulent fluctuations in the planetary boundary layer. By averaging these fluctuations, high-quality profiles of mean quantities and turbulence statistics can be obtained in experiments with well-defined initial and boundary conditions. Hence, LES data can be beneficial for assessment and optimisation of turbulence closure schemes. A database of 80 LES runs (DATABASE64) for neutral and stably stratified planetary boundary layers (PBLs) is applied in this study to optimize first-order turbulence closure (FOC). Approximations for the mixing length scale and stability correction functions have been made to minimise a relative root-mean-square error over the entire database. New stability functions have correct asymptotes describing regimes of strong and weak mixing found in theoretical approaches, atmospheric observations and LES. The correct asymptotes exclude the need for a critical Richardson number in the FOC formulation. Further, we analysed the FOC quality as functions of the integral PBL stability and the vertical model resolution. We show that the FOC is never perfect because the turbulence in the upper half of the PBL is not generated by the local vertical gradients. Accordingly, the parameterised and LES-based fluxes decorrelate in the upper PBL. With this imperfection in mind, we show that there is no systematic quality deterioration of the FOC in the strongly stable PBL provided that the vertical model resolution is better than 10 levels within the PBL. In agreement with previous studies, we found that the quality improves slowly with the vertical resolution refinement, though it is generally wise not to overstretch the mesh in the lowest 500 m of the atmosphere where the observed, simulated and theoretically predicted stably stratified PBL is mostly located. The submission to a special issue of the “Boundary-Layer Meteorology” devoted to the NATO advanced research workshop “Atmospheric Boundary Layers: Modelling and Applications for Environmental Security”.     

Strontium-90 in surface and groundwater of the reclamation systems at the Chernobyl exclusion zone

The left bank of the Pripiat' river, opposite of the Chernobyl Nuclear Power Plant (ChNPP) is covered with a developed network of drainage canals, built for the reclamation of the swampy floodplain. This area is highly contaminated after the disaster in 1986. Concentrations of the most mobile radionuclide, ⁹⁰Sr, are comparable with ¹³⁷Cs, and reach many MBq m^-2. Their ratio in the upper 10 cm of soil is about 1. The high surface contamination as well as precipitation and flooding have been responsible for the water pollution in this area. Some specifics of ⁹⁰Sr behaviour in surface and groundwater, controlled by the hydrological regime, are described.     

Non-Equilibrium Distribution Functions in the Heliospheric Interface and Their Relaxation by Local Wave–Particle Interactions

The partially ionized local interstellar medium, before interacting with the heliospheric plasma on the upwind side, most probably undergoes an outer bow shock. After conversion into a sub-magnetosonic plasma flow, it then passes around the heliopause. While the ionized component at the bow shock undergoes abrupt changes of its dynamical properties, the neutral component first continues to flow downstream of the shock with its unperturbed properties. Consequently, the two fluids immediately after the bow shock passage are out of dynamical and thermodynamical equilibrium. Neutral atoms move with a higher bulk velocity and are cooler than the ions. Due to intensive local charge-exchange couplings between neutral atoms and protons these different properties tend to mix each other via momentum and energy exchanges. It turns out that the charge exchange period is shorter than the relaxation period. Hence the distribution functions cannot relax rapidly enough to their highest-entropy forms, i.e. shifted Maxwellians. Here we study the transport processes of newly injected ions in velocity space considering their quasi-linear and non-linear interactions with the ambient MHD turbulence in the plasma interface region. For that purpose we study the turbulence levels in the helio-sheath plasma region. We calculate the expected deviations from equilibrium distributions of ionic and atomic species in the outer heliospheric interface. It clearly turns out from these studies that non-relaxated non-equilibrium distribution functions have to be expected both for O-/H-ions and atoms in this region. This has inherent implications for the diagnostics of interstellar parameters, deduced from observations made further inwards from the interface region.     

Average temporal signatures of GRBs: applications to theoretical models

New statistical results for cosmic gamma-ray bursts are presented, based on aligned average time profiles. General signatures are discussed of averaged flux/spectrum evolution of the full set of the Second BATSE Catalog GRBs (Fishmanet al., 1995), as well as of the bright and dim subsets. The contradictory conclusions made by Norriset al., (1994) and Mitrofanovet al., (1995a) about the presence or the absence of the time-dilation of dim GRBs are discussed. The well-established effect of hardness/brightness correlation of GRBs is presented. The consequences of these statistical studies are discussed for the cosmological and galactic paradigms of GRBs sources.     

Geochemical Baselines of Nickel and Chromium in Various Surficial Materials in the Barents Region, NW Russia and Finland

The geochemical baselines of nickel and chromium were studied from the data produced by the Barents Ecogeochemistry project, a large international regional geochemical mapping exercise. The project surveyed major and trace element distributions in stream water, organic and mineralogically-modified soil horizons, and terrestrial moss in the northwestern part of Russia and in Finland. Other materials were collected during the pilot phase and later from thirty special sites. The results on respective materials by XRF, ICP-MS and ICP-AES showed that both geological and anthropogenic factors have an influence on the geochemical baseline concentrations of Ni and Cr in organic soil and stream water. The main explanation of the observed distribution patterns in terrestrial moss is human activity, but geological factors can also affect the baselines. The variation of geochemical baselines in the mineral-rich soil horizon depends only on variations in bedrock. The mineralogy of samples mainly controls the leachability properties of soil samples.