Characterization of Colliery Spoils in León: Potential Uses in Rural Infrastructures

One of the bases of sustainable development is the responsible management of natural resources, and this is the approach which has been adopted by developed countries as regards management of all kinds of waste, through the establishment of management strategies based on prevention, reuse and recycling. This article present the results of a physical, chemical and geotechnical characterization of colliery spoils stored in slag heaps in the Ciñera-Matallana coal mining area in León, Spain. The primary objectives of this research were to determine the suitability of this mining waste for use as granular material in rural and civil engineering infrastructures and to classify it according to national and international road construction standards. On the basis of the results obtained, they are proposed several possible uses (foundation and core layers in track and road embankments, granular sub-base for light traffic and top layers of embankments), although it should be noted the need for mechanical treatments as crushing or sieving and the recommendation of use of sulphate resistant cement to avoid the possible problems.     

Methodological proposal to assess groundwater contamination danger: study case of Bajo Cauca aquifer (Colombia)

Interaction between vulnerability and contaminating charge was used in order to determine the groundwater contamination danger. The result of danger being adapted to the scale of impact on human or animal health and ecosystems is known as “risk”. Index and overlapping methodologies such as EPNNA, DRASTIC, SINTACS, GOD AVI, and Ekv were used and compared to evaluate vulnerability. Contaminating charge to the subsoil, which is generated from specific human activity, has four characteristics: kind of contaminant, means of disposal, intensity, and duration. Interaction among these characteristics obtains a Contaminating Charge Index. In the Bajo Cauca Antioqueño region, over 150,000 inhabitants require ground water for meeting their basic needs at home, for cattle breeding activities, and for irrigation. For this region, an assessment of the groundwater contamination of the free aquifer, as well as an estimation of its impact and the danger this contamination may pose to ecosystems or communities has been performed. Analysis of the interaction between vulnerability and threat allows for the creation of danger and risk maps.     

Mitigation of lateral ground displacements of liquefied soils with underground barriers

Analyses of damage data from earthquakes in the last 35 years show that very high financial losses have resulted from cases where liquefaction of soils was associated with ground lateral displacements towards a free boundary such as a shoreline, a river channel, or an open trench. Lateral displacements in excess of 10 m have been documented in the literature [Bartlett and Youd, J. Geotech. Engng, ASCE 121 (1995) 316]. In fact, in many cases, displacements amounting to only a fraction of this number are capable of causing considerable disruption to man-made works. Several factors contribute to the extent of lateral spreading: surface and subsurface geometry, soil characteristics, and intensity of ground motion.

Ground displacements can be minimized or even arrested in practice with an underground structure properly designed to counter the driving forces, gravity and inertia combined. Mitchell et al. suggested practical guidance for the design of such structures, or barriers, in 1998 [Geotech. Spec. Publ. 75 (1998) 580]. However, to date there is no standard procedure to carry out the analysis of such barriers. The paper describes several recent designs of underground barriers that have been constructed in highly seismic environments. Three types of underground barriers are described: clay fill, a grid of structural piles, and a grid of cement-treated soil. The design of the cement-treated cell barrier is discussed in detail as it accounts for the most unfavorable combination of all forces acting on the structure: lateral stresses induced by liquefied soil, hydrodynamic effects, inertia forces, and loss of ground.     

Low-ionization galaxies and evolution in a pilot survey up to z=1

We present galactic spectroscopic data from a pencil beam of 10.75×7.5 centered on the X-ray cluster RXJ0054.0-2823 at z=0.29.We study the spectral evolution of galaxies from z=1 down to the cluster redshift in a magnitude-limited sample at R≤23,for which the statistical properties of the sample are well understood.We divide emission-line galaxies into star-forming galaxies,Low Ionization Nuclear Emission line Regions(LINERs) ,and Seyferts by using emission-line ratios of[OII],Hβ,and[OIII],and derive stella...     

H2S Emissions from a Submerged Pilot‐Scale Fixed Bed Biofilm Reactor

A study was performed in two submerged, pilot‐scale biofilm bioreactors operated under different conditions to determine the relationship between the operating parameters and H₂S emission. H₂S was always detected in the exhaust air at concentrations varying from 1 to 353 ppm_v. The specific aeration rate was the most influencing parameter, with As < 30 kg COD (dissolved oxygen concentrations <4 mg L^?1) increasing noticeably the H₂S production. The periodical removal of the accumulated sludge reduced H₂S emissions by ～14%.     

Hydrothermal alteration,fluid inclusions and stable isotope systematics of the Alvo 118 iron oxide–copper–gold deposit,Carajás Mineral Province (Brazil): Implications for ore genesis

The Alvo 118 iron oxide–copper–gold (IOCG) deposit (170 Mt at 1.0 wt.% Cu, 0.3 g/t Au) lies in the southern sector of the Itacaúnas Shear Belt, Carajás Mineral Province, along a WNW–ESE-striking, 60-km-long shear zone, close to the contact of the ~2.76-Ga metavolcano-sedimentary Itacaiúnas Supergroup and the basement (~3.0 Ga Xingu Complex). The Alvo 118 deposit is hosted by mafic and felsic metavolcanic rocks and crosscutting granitoid and gabbro intrusions that have been subjected to the following hydrothermal alteration sequence towards the ore zones: (1) poorly developed sodic alteration (albite and scapolite); (2) potassic alteration (biotite or K-feldspar) accompanied by magnetite formation and silicification; (3) widespread, pervasive chlorite alteration spatially associated with quartz–carbonate–sulphide infill ore breccia and vein stockworks; and (4) local post-ore quartz–sericite alteration. The ore assemblage is dominated by chalcopyrite (~60%), bornite (~10%), hematite (~20%), magnetite (10%) and subordinate chalcocite, native gold, Au–Ag tellurides, galena, cassiterite, F-rich apatite, xenotime, monazite, britholite-(Y) and a gadolinite-group mineral. Fluid inclusion studies in quartz point to a fluid regime composed of two distinct fluid types that may have probably coexisted within the timeframe of the Cu–Au mineralizing episode: a hot (>200°C) saline (32.8‰ to 40.6 wt.% NaCl eq.) solution, represented by salt-bearing aqueous inclusions, and a lower temperature (<200°C), low to intermediate salinity (<15 wt.% NaCl eq.) aqueous fluid defined by two-phase (L_H2O + V_H2O) fluid inclusions. This trend is very similar to those defined for other IOCG systems of the Carajás Mineral Province. δ ¹⁸O_H2O values in equilibrium with calcite (−1.0‰ to 7.5‰ at 277°C to 344°C) overlap the lower range for primary magmatic waters, but the more ¹⁸O-depleted values also point to the involvement of externally derived fluids, possibly of meteoric origin. Furthermore, sulphide δ ³⁴S values (5.1‰ to 6.3‰), together with available boron isotope and Cl/Br–Na/Cl data provide evidence for a significant component of residual evaporative fluids (e.g., bittern fluids generated by seawater evaporation) in this scenario that, together with magma-derived brines, would be the main sources of the highly saline fluids involved in the formation Alvo 118 IOCG deposit. The restricted high temperature sodic alteration, the pervasive overprinting of the potassic alteration minerals by chlorite proximal to the ore zones, ore breccias with open-space filling textures in brittle structures, microthermometric and stable isotope data indicate, collectively, that the Alvo 118 IOCG system developed at structurally high levels and may be considered the shallower representative of the IOCG systems of the CMP.     

Temperate rainforest response to climate change and disturbance agents in northwestern Patagonia (41°S) over the last 2600 years

We present detailed pollen and charcoal records from Lago Pichilafquén (~ 41°S) to decipher the effects of climate change and varying disturbance regimes on the composition and structure of the vegetation on the Andean foothills of northwestern Patagonia during the last 2600 yr. Here, temperate rainforests have dominated the landscape since 2600 cal yr BP with variations ranging from cool-temperate and wet north Patagonian rainforests to relatively warm and summer-drought-resistant Valdivian rainforests. We interpret relatively warm/dry conditions between 1900–2600, 690–750 and 320–430 cal yr BP, alternating with cold/wet conditions between 1500–1900, 750–1100 and 430–690 cal yr BP. Rapid deforestation and spread of plants introduced by Europeans occurred at 320 and 140 cal yr BP. The record includes five tephras with ages of 2130, 1460, 1310, 1210, and 340 cal yr BP, all of which precede local fire events and increases in trees favored by disturbance by less than 100 yr. We conclude that centennial-scale changes in the southern westerlies were the primary driver of vegetation shifts in northwestern Patagonia over the last 2600 yr. Within this interval, local disturbance regimes altered the structure, composition, and dynamics of the lowland rainforest vegetation during several discrete, short-lived episodes.     

A Bayesian analysis of the Gumbel distribution: an application to extreme rainfall data

With the objective of modelling annual rainfall maximum intensities in different geographical zones of Chile, we have created a Bayesian inference method for the generalized extreme value type I distribution (Gumbel distribution). We considered an uninformative prior distribution for the location parameter, μ, and three different prior distributions for the scale parameter, σ. Under these conditions we obtained the posterior distribution of (μ, σ) and associated summary statistics such as modes, expected values, quantiles and credibility intervals. In order to predict and estimate return periods, we obtained the posterior distribution of future observations, its expected value, quantiles and credibility intervals. To obtain several of these posterior summary measures it was necessary to utilize both numerical and Laplace approximations. Furthermore we estimate return period curves and intensity–duration–frequency curves.     

Effect of different wavelengths of light on the antioxidant and immunity status of juvenile rock bream, <Emphasis Type="Italic">Oplegnathus fasciatus</Emphasis>, exposed to thermal stress

We investigated the effect of light wavelengths on antioxidant and immunity parameters in juvenile rock bream, Oplegnathus fasciatus, exposed to thermal stress (25 and 30°C). We exposed the fish to light emitting diodes (LEDs) emitting green (520 nm) and red light (630 nm) of 0.25 and 0.5 W/m² intensity, and measured the activity, and mRNA and protein expression levels of the antioxidant enzymes, superoxide dismutase, catalase, and glutathione peroxidase. We also determined the levels of plasma hydrogen peroxide (H₂O₂), melatonin, and lysozyme. Furthermore, the mRNA and protein levels of caspase-3 were measured and terminal transferase dUTP nick end labeling (TUNEL) assays were performed. We observed that mRNA expression and activities of antioxidant enzymes and plasma H₂O₂ levels were significantly higher after exposure to high temperatures. However, increases in these parameters were significantly lower after exposure to green LED light. The plasma melatonin and lysozyme levels were significantly lower in the different groups after exposure to high temperatures; however, in groups exposed to green LED light, their levels were significantly higher than those in the control group. The expression pattern of caspase-3 mRNA was similar to that of H₂O₂. The TUNEL assay showed that apoptosis was markedly higher at higher water temperatures than that at 20°C. These results indicate that high water temperatures induce oxidative stress and decrease the immunity in juvenile rock bream but green LED light inhibits the rise in oxidative stress and combats the decrease in immunity and should, thus, be useful in the culture of rock bream.