Groundwater characteristics within loessic deposits: the coastal springs of Los Acantilados,Mar del Plata,Argentina

The urban growth of the southern neighborhoods of Mar del Plata City provoked significant changes in the groundwater balance of the loessic sequences. These regional loessic levels with a significant portion of volcanic ash layers were reported subject to fluoride and nitrate concentrations. Residential houses pump from sands located 70 m depth and withdraw the sewages to depths less than 5 m. These effects cause significant local and seasonal (summer) increments of the water table outcropping via springs at certain unconformities of the coastal cliffs. A mathematical model was applied to analyze the water level lowering at the productive levels, while there is a decrease in the quality of the upper levels subject to waste discharges. Much of this groundwater flow is concentrated in unconformities between different types of sediments. Human activities have affected the aquifer dynamics increasing the groundwater pumping rates and the return velocity of the sewages. This should be considered in the management strategies of coastal hydric resources.     

Late Holocene marine terraces of the Cartagena region,southern Caribbean: The product of neotectonism or a former high stand in sea-level?

The detailed stratigraphic survey and paleontological study (mollusks, corals, foraminifera and ostracods) of four low-level, ～3 m, marine terrace sections: Punta Canoas, Manzanillo del Mar, Playa de Oro, and Tierra Bomba Island, from the Cartagena region, southern Caribbean, supplemented with 22 radiocarbon dates, reveals that the northern terraces were deposited as parasequences in a clastic depositional system compared to the Tierra Bomba Island succession that was deposited in a carbonate depositional system between ～3600 and ～1700 cal yrs BP. Drier conditions and the southern location of the ITCZ at about 3 ka triggered stronger easterly Trades and more dynamic southwestward sediment drift fed by the Magdalena River mouth, thus promoting the formation of sand spits that ultimately isolated the Cienaga de Tesca coastal lagoon from the Caribbean Sea. Our estimates support the hypothesis that the present position of the terraces is the product of neotectonism rather than a higher 3 ka, sea-level. Upheaval of the terraces varies between ～3.8 mmyr^?1 at Punta Canoas and ～2.2 mmyr^?1 at Tierra Bomba to ～1.5 mmyr^?1 at Manzanillo del Mar and Playa de Oro terraces. Our study corroborates previous contentions on the role of mud diapirism and the dynamics of the Dique Fault as late Holocene upheaval mechanisms.     

Airborne measurements of particle and gas emissions from the December 1994–January 1995 eruption of Popocatépetl volcano (Mexico)

Airborne and ground-based (correlation spectrometer, cascade impactor, and photoelectric counter together with intake filter probes) measurements are described for the volcanic emissions from Popocatépetl volcano (Mexico) from December 23, 1994 to January 28, 1995. Measurements of SO₂ restarted 48 h after the eruption onset of December 21, 1994. Maximum sulfur dioxide (4560 t d⁻¹) plus 3.8×10⁴ t d⁻¹ of particulate matter were ejected on December 24, 1994. The maximum rate of ejection occurred coincidentally with the maximum amplitude of harmonic tremor and the maximum number of seismic type B events. Sulfur dioxide emission rates ranged from 1790 to 2070 t d⁻¹ (December 23–24, 1994). Afterwards, sulfur dioxide emission rates clearly indicated a consistent decline. However, frequent gas and ash emission puffs exhibited SO₂ fluxes reaching values as high as 3060 t d⁻¹. The emission SO₂ baseline for the period of study (February 1994–January 1995) was about 1000 t d⁻¹. Ejection velocity of particulate matter was approximately 270 m s⁻¹ reaching a height of about 2.5 km over the summit. The immediate aerosol dispersion area was estimated at 6.0×10⁴ km² maximum. The microscopic structure of particles (aerosol and tephra) showed a fragile material, probably coming from weathered crustal layers. X-ray fluorescence and neutron-activation analysis from the impactor samples found the following elements: Si, Al, Ca, S, P, Cl, K, Ni, Fe, Ti, Sc, Cu, Zn, Mn, Sr, Cr, Co, Y, Br, Se, Ga, Rb, Hg and Pb. Morphological analysis shows that ash samples might be from pulverized basaltic rock indicating that the Popocatépetl eruption of December 21, 1994 was at low temperature. The microscopic structure of puff material showed substance aggregates consisted of fragile rock, water and adsorbed SO₂. These aggregates were observed within water droplets of approximately 1 mm and even larger. Sulfur transformations in the droplets occurred intensively. Volcanic ash contained 5–6% of sulfur during the first expulsion hours. Elemental relative concentrations with respect to Al show that both Si and S have relative concentrations >1, i.e., 13.73 and 2.17, respectively in agreement with the photoelectric counter and COSPEC measurements.     

Baseline of butyltin pollution in coastal sediments within the Basque Country (northern Spain), in 2007-2008

Tributyltin (TBT), dibutyltin (DBT) and monobutyltin (MBT) were measured in surficial sediments at, the ports of Pasaia and Bilbao, together with other mid- and small-size harbours of the Basque Country (northern Spain), in 2007-2008. The highest values of the sum of the three measured butyltin species (3523-3640 ng g⁻¹, as Sn) were found at sampling stations near to shipyards located within the port of Pasaia. The highest value of TBT concentration (3143 ng g⁻¹, as Sn) was found at the marina of Getxo, in the port of Bilbao. The degree of TBT degradation varied greatly between sampling stations, being found to be generally higher in those sediments with higher values of redox potential and lower values of TBT concentration (normalized by organic matter content).     

San Quirce (Palencia,Spain): new chronologies for the Lower to Middle Palaeolithic transition of south-west Europe

San Quirce is an open-air archaeological site situated on a fluvial terrace in the Duero basin (Palencia, northern Iberia). This paper presents new and consistent chronologies obtained for the sedimentary sequence using post-infrared infrared stimulated luminescence (pIR-IR) dating of K-feldspars and single-grain thermally transferred optically stimulated luminescence (TT-OSL) dating of quartz. The new dating results indicate that the sequence is older than ~200 000 years and place San Quirce Level III within marine isotope stages (MIS) 8 and 7, between 274 ± 13 ka and 238 ± 13 ka. The main lithic assemblage at San Quirce comes from Level III. The predominant tool types found in this level are hammerstones, manuports and flakes, with a small proportion of cores and a significant presence of denticulates. Adaptation to local environmental conditions resulted in distinctive cultural habits, which were embedded in the cultural tradition of hominins occupying the site during the final third of the Middle Pleistocene. San Quirce preserves a simple cultural tradition that was employed by local hominins to engage in a diverse array of activities, and highlights the cultural diversity that appears to have been a characteristic feature of the Lower to Middle Palaeolithic transition 300–200 ka.     

On the resurfacing of Ganymede by liquid-water volcanism

A long-popular model for producing Ganymede's bright terrain involves flooding of low-lying graben with liquid water, slush, or warm, soft ice. The model suffers from major problems, however, including the absence of obvious near-surface heat sources, the negative buoyancy of liquid water, and the lack of a mechanism for confining the flows to graben floors. We present new models for cryovolcanic resurfacing to overcome these difficulties. Tidal heating within an ancient Laplace-like orbital resonance (Showman and Malhotra 1997, Icarus 127, 93; Showman et al., 1997, Icarus 129, 367) provides a plausible heat source and could allow partial melting to occur as shallow as 5-10 km depth. Our favored mechanism for delivering this water to the surface invokes the fact that topography—such as a global set of graben—causes subsurface pressure gradients that can pump water or slush upward onto the floors of topographic lows (graben) despite the negative buoyancy of the liquid. These eruptions can occur only within the topographic lows; furthermore, as the low areas become full, the pressure gradients disappear and the resurfacing ceases. This provides an explanation for the observed straight dark-bright terrain boundaries: water cannot overflow the graben, so resurfacing rarely embays craters or other rough topography. Pure liquid water can be pumped to the surface from only 5-10 km depth, but macroscopic bodies of slush ascending within fractures can reach the surface from much greater depths due to the smaller negative buoyancy of slush. A challenge for these models is the short predicted gravitational relaxation timescale of topographic features at high heat flows; the resurfacing must occur before the graben topography disappears. We also evaluate alternate resurfacing mechanisms, such as pumping of liquid water to the surface by thermal expansion stresses and buoyant rise of water through a silicate-contaminated crust that is denser than liquid water, and conclude that they are unlikely to explain Ganymede's bright terrain.     

Construction and screening of a functional metagenomic library to identify novel enzymes produced by Antarctic bacteria

A metagenomic fosmid library of approximately 52 000 clones was constructed to identify functional genes encoding cold-adapted enzymes. Metagenomic DNA was extracted from a sample of glacial meltwater,...     

Turbidometric estimations in Mexico city using the Volz sun photometer

Summary Measuring, with the aid of two filters, the instantaneous intensity of the solar radiation in two wave lengths ( _B = 0.44 , _R = 0.64 ) by means of a sun photometer designed byVolz, we carried out determinations of the decadic turbidity coefficientB (=0.5 ) and the wave length exponent of the haze extinction for Mexico City. Observations were made for almost two and a half years (1960 to 1962 period). A seasonal size distribution in both parameters was found. Although the data thus obtained are provenient of a contaminated atmosphere, comparison of our data is made with those found for higher latitudes ofÅngström, Schüepp andVolz. The height of the homogeneous haze layerH _D was calculated showing pronounced variations for a given wind direction. The maximum and minimum values ofB enable us to get, by the first approximation, the aerosol size distribution ofJunge for our latitudes. However, for exceptional very clear days having maximum actinometric intensity of the solar radiation the sensitivity of the microamperimeter in theVolz sun photometer fails.     

Mitigation of lateral ground displacements of liquefied soils with underground barriers

Analyses of damage data from earthquakes in the last 35 years show that very high financial losses have resulted from cases where liquefaction of soils was associated with ground lateral displacements towards a free boundary such as a shoreline, a river channel, or an open trench. Lateral displacements in excess of 10 m have been documented in the literature [Bartlett and Youd, J. Geotech. Engng, ASCE 121 (1995) 316]. In fact, in many cases, displacements amounting to only a fraction of this number are capable of causing considerable disruption to man-made works. Several factors contribute to the extent of lateral spreading: surface and subsurface geometry, soil characteristics, and intensity of ground motion.

Ground displacements can be minimized or even arrested in practice with an underground structure properly designed to counter the driving forces, gravity and inertia combined. Mitchell et al. suggested practical guidance for the design of such structures, or barriers, in 1998 [Geotech. Spec. Publ. 75 (1998) 580]. However, to date there is no standard procedure to carry out the analysis of such barriers. The paper describes several recent designs of underground barriers that have been constructed in highly seismic environments. Three types of underground barriers are described: clay fill, a grid of structural piles, and a grid of cement-treated soil. The design of the cement-treated cell barrier is discussed in detail as it accounts for the most unfavorable combination of all forces acting on the structure: lateral stresses induced by liquefied soil, hydrodynamic effects, inertia forces, and loss of ground.     

Petrology, magnetostratigraphy and geochronology of the Miocene volcaniclastic Tepoztlán Formation: implications for the initiation of the Transmexican Volcanic Belt (Central Mexico)

The volcaniclastic Tepoztlán Formation (TF) represents an important rock record to unravel the early evolution of the Transmexican Volcanic Belt (TMVB). Here, a depositional model together with a chronostratigraphy of this Formation is presented, based on detailed field observations together with new geochronological, paleomagnetic, and petrological data. The TF consists predominantly of deposits from pyroclastic density currents and extensive epiclastic products such as tuffaceous sandstones, conglomerates and breccias, originating from fluvial and mass flow processes, respectively. Within these sediments fall deposits and lavas are sparsely intercalated. The clastic material is almost exclusively of volcanic origin, ranging in composition from andesite to rhyolite. Thick gravity-driven deposits and large-scale alluvial fan environments document the buildup of steep volcanic edifices. K-Ar and Ar-Ar dates, in addition to eight magnetostratigraphic sections and lithological correlations served to construct a chronostratigraphy for the entire Tepoztlán Formation. Correlation of the 577 m composite magnetostratigraphic section with the Cande and Kent (1995) Geomagnetic Polarity Time Scale (GPTS) suggests that this section represents the time intervall 22.8–18.8 Ma (6Bn.1n-5Er; Aquitanian-Burdigalian, Lower Miocene). This correlation implies a deposition of the TF predating the extensive effusive activity in the TMVB at 12 Ma and is therefore interpreted to represent its initial phase with predominantly explosive activity. Additionally, three subdivisions of the TF were established, according to the dominant mode of deposition: (1) the fluvial dominated Malinalco Member (22.8–22.2 Ma), (2) the volcanic dominated San Andrés Member (22.2–21.3 Ma) and (3) the mass flow dominated Tepozteco Member (21.3–18.8 Ma).