The impact of tributyltin from large vessels on dogwhelk (Nucella lapillus) populations around Scottish oil ports

Surveys of imposex in dogwhelk (Nucella lapillus) populations around oil terminals in Sullom Voe (Shetland) and Scapa Flow (Orkney) have confirmed that the effects of tributyltin (TBT) released from large vessels in coastal waters can be recognised. The impact of large vessels can be separated from the effects of other inputs of TBT in the areas studied. The intensity of the effects was greater in Shetland than in Orkney, reflecting the higher exposure to TBT resulting from the greater volume of traffic using the Shetland terminal, and the more restricted water exchange in that area. A large proportion of the female dogwhelks in Sullom Voe were unable to reproduce. Females in Scapa Flow were still able to reproduce, except for a small proportion close to two fish farm sites where TBT net-treatments were used prior to 1987.     

Contributions to atmospheric methane by natural seepages on the U.K. continental shelf [Mar. Geol. 137 (1997) 165–189]

Natural gas seepages occur on the United Kingdom's continental shelf and although published reports suggest that they are very rare, the petroleum industry has identified, but not publicly reported, many more. There is also very little data on the flux of gas from seabed seepages, and even less on the contribution of seepages to atmospheric concentrations of gases such as methane.

Potential gas source rocks include Quaternary and Tertiary peats as well as petroliferous source rocks such as the Carboniferous Coal Measures and the Upper Jurassic Kimmeridge Clays. There are also other organic-rich sediments which are potential source rocks. Together these cover a considerable part of the U.K. continental shelf.

Analogue seismic reflection (pinger) profiles acquired during the British Geological Survey's regional mapping programme have been reviewed to identify water column targets including fish and plumes of gas bubbles. The ability to distinguish targets is critical to an assessment of the distribution of gas seepages. Both theoretical predictions of target identity and the habits of shoaling fish have been investigated in order to identify a method of distinction.

Data from seabed seepages and measurements of seepage rates have been used to establish likely ranges of gas flux rates and the sizes of gas bubbles. The likelihood that a rising bubble will survive and escape into the atmosphere is determined primarily by bubble size and water depth; methane, the principal constituent of seepage gas, is relatively unreactive and sparingly soluble.

The studies have enabled a new estimate of the distribution of gas seepages on the U.K. continental shelf, and of the contribution to atmospheric methane levels. The results suggest that natural gas seepages are significantly more important as a source of methane than had hitherto been established. It is estimated that between 120,000 and 3.5 mtonnes of methane per year come from a continental shelf area of about 600,000 km². This represents between 2% and 40% of the total United Kingdom methane emission. It is suggested that similar contributions arise from other continental shelf areas worldwide, and that geological sources of atmospheric methane are more significant than is generally acknowledged.     

Land-based activities: what remains to be done

The Global Programme of Action for the Protection of the Marine Environment from Land-based Activities (GPA) represents an ambitious attempt to make the leap between the rhetoric of protecting and preserving the marine environment and action. With degradation of the marine environment from land based activities posing one of the most serious threats to the quality and productivity of the coastal and marine environment, the GPA can only be viewed as a milestone rather than a destination, as so much work remains to be done in this field.States supporting the GPA are entering the most challenging phase of the program, that of implementation. But the international community in taking on this challenge is not without a few signposts. The failure of the Montreal Guidelines to be implemented, provides States with many important lessons. This paper suggests that if the GPA is to have an impact on the complex problem of land-based activities then several tasks need to be grappled with. Substantial financial support needs to be generated, a proactive and cooperative secretariat established and the nexus between the GPA and United Nations Environment Programme Regional Seas Programme examined. The importance of people and training to the capacity building process needs to be recognised and a wider variety of stakeholders engaged in the follow up phase. Pivotal to the aforementioned is the need to generate political will to address the problem, without which the GPA will become yet another dusty volume on the bookshelf.     

Coalification in Carboniferous sediments from the Lötschberg base tunnel

Vitrinite reflectance (Rr), proximate analysis and carbon isotope composition (δ¹³C) have been used to characterise coal samples from two zones of Late Carboniferous sediments (Gastern and Ferden) in the Aar massif where they are penetrated by the Lötschberg base tunnel (constructed between 1999 and 2005). Samples are characterised by variable ash yields (21.7–93.9%; dry basis); those with ash yields of less than ~50% and with volatile matter content (V;dry ash-free basis) within the limits 2 < V% ≤ 8 are anthracite. Values of Rr range from 3.89% to 5.17% and indicate coalification to the rank of anthracite and meta-anthracite in both Gastern and Ferden Carboniferous zones. Samples of anthracite and shale from the Gastern Carboniferous exhibit a relatively small range in δ¹³C values (–24.52‰ to –23.38‰; mean: –23.86‰) and are lighter than anthracite samples from the Ferden Carboniferous (mean: –22.20‰). The degree of coalification in the Gastern and Ferden Carboniferous zones primarily depends on the maximum rock temperature (T) attained as a result of burial heating. Vitrinite reflectance based estimates of T range from ~290° –360 °C. For a proposed palaeogeothemal gradient of 25 ° C/km at the time of maximum coalification the required overburden is attributable to relatively thin autochtonous Mesozoic/Cenozoic sedimentary cover of the Aar massif and Gastern granite and deep tectonic burial beneath advancing Helvetic, Ultrahelvetic and Prealpine (Penninic) nappes in Early Oligocene to Miocene.     

Revised chemical models of ζ Oph based on HST data

Hubble Space Telescope observations by Savage, Cardelli and Sofia (1992) and Cardelliet al. (1993) have led to improved gas phase abundances for many elements in the diffuse cloud towards the star Oph. Most remarkably, it was found that oxygen is much more strongly depleted than previousCopernicus observations indicated. As a consequence, chemical models of the Oph cloud are severely affected by the drop in the observed oxygen abundance by almost a factor of two; some previous model calculations for the Oph cloud failed to reproduce-even approximately-the observed high CO column density. The model calculations for the Oph cloud developed by Wagenblast (1992) in which the abundance of all observed neutral molecules could be reproduced have been revised and it is found that oxygen and nitrogen hydrides are required to be formed efficiently on the surface of grains; further, there are indications for a high cosmic ray ionization rate of the order 10^–16 s^–1.     

Global comparison of the regional rainfall results of enhanced greenhouse coupled and mixed layer ocean experiments: Implications for climate change scenario development

The extent of agreement amongst current global climate models (GCMs) on the global pattern of rainfall change simulated under enhanced greenhouse conditions is assessed. We consider the results of five experiments which use a simple mixed layer ocean formulation and five which use a fully dynamic ocean model (coupled experiments). For many regions of the northern hemisphere there is strong agreement amongst both mixed layer and coupled experiments on the sign of simulated rainfall change. However, in the southern hemisphere there are large, and apparently systematic, differences between the coupled and mixed layer experiments. In particular, whereas the mixed layer experiments agree on simulated rainfall increase in summer in the tropics and subtropics of the Australian sector, the coupled experiments agree (although more weakly) on rainfall decreases. These differences appear to relate to the much reduced warming simulated by the coupled experiments in the high latitudes of the southern hemisphere. However, recent oceanographie evidence suggests that this suppressed warming may be considerably overestimated. We conclude therefore that despite the in-principle advantages of coupled models, it may be too soon to base some regionally specific climate change scenarios solely on the results of coupled experiments.     

Definition and measurement of salinity in salt lakes

Salinity is the most important chemical attribute of athalassic salt lakes. Even so, some confusion persists of what salinity means and how to measure it. For sal lakes, salinity is best defined as the sum total of all ion concentrations, or total ion concentration. Ideally, it is recommended that salinities be expressed on a mass per mass basis and as ppt (parts per thousand). Direct measurements of salinity can only be derived from full ionic analyses. Indirect measurements can be derived by determinations of density, conductivity, freezing point depression and total dissolved solids or matter.     

Fluid-rock interaction between syenites and marbles at Stephen Cross Quarry,Québec,Canada: petrological and stable isotope data

Grenville dolomitic marbles and calc-silicates at Stephen Cross Quarry, Québec, underwent contact metamorphism and metasomatism associated with the intrusion of the Wakefield syenite at ambient pressures of 0.4GPa at 1090–1070Ma. Fluid infiltration produced exoskarns, calcite+periclase+forsterite±diopside±orthoclase assemblages in the marbles, and quartz±calcite±wollastonite±diopside±anorthite assemblages in the calc-silicates. Phase-equilibria in the CaO–MgO–Al₂O₃–SiO₂–H₂O–CO₂ system suggest that fluid infiltration occurred close to the thermal peak of contact metamorphism (715–815°C) and that the fluids hadXCO₂0.15. In the metasediments, ¹⁸O values of calcite (Cc) are as low as 8.6, suggesting that the fluids were in isotopic equilibrium with the syenites (¹⁸O =8.8–10.2). Marble ¹³C(Cc) values are-0.1 to-3.2; the lack of correlation between ¹³C(Cc) and ¹⁸O(Cc) is consistent with the infiltration of water-rich fluids. The resetting of stable isotopes and the mineralogical changes can be explained by time-integrated fluid fluxes of up to 110 m³/m² (4×10⁶ mol/m²), corresponding to actual fluxes of 3×10^-11 to 3×10^-12 m³/m²-s and intrinsic permeabilities of 10^-18 to 10^-20 m² for fluid flow lasting 0.1-1Ma. Marble ¹⁸O(Cc) values do not correlate well with distance from the syenite, and fluids were probably channelled across lithological layering. The correlation between the degree of resetting of marble ¹⁸O(Cc) values with the abundance of submillimetre-wide veins, suggests that fluid focussing may have resulted from variations in fracture density. Late, lower temperature (<500°C), fluid flow formed serpentine (Serp) and brucite (Br) from periclase and forsterite. ¹⁸O(Br) and ¹⁸O(Scrp) values correlate with ¹⁸O(Cc), suggesting that retrogression involved only limited volumes of fluid. The observation that ¹⁸O(Cc-Br) and ¹⁸O(Cc-Serp) values are higher in marbles that have lower ¹⁸O(Cc) values is interpreted as indicating that fluid flow persisted to lower temperatures in those rocks due to higher intrinsic permeabilities. Calcite in the syenite was also formed by the influx of fluids during cooling. Syenite ¹⁸O(Cc) values are approximately in isotopic equilibrium with the high-temperature silicate minerals, suggesting that again only minor volumes of fluid were involved. In detail fluid flow was prolonged and complex, creating problems for the application of quantitative fluid flow models.This paper is a contribution to IGCP 304, Lower Crustal Processes     

Malta: macropolitical threats

Despite constitutional neutrality and non-alignment, for the last decade Malta has dabbled in Western security circles. By pledging commitment to the European CFSP and forging closer associations with NATO the government consummated allegiances with the hegemonic flank of their region and the only remaining superpower. However, Maltese security in the post-Cold War era is about more than just power fealty. Whilst not overlooking the still highly relevant military threats to security, this paper elucidates three macropolitical threats that are too impetuous for the worlds most powerful security organizations to handle. Indeed, future Maltese membership of the WEU or closer ties with NATO may even exacerbate these menaces.