Employment in retailing: A case study of employment in suburban shopping centres

There have been many studies of the retail industry in recent years, and of the impact that retailing has had on the spatial arrangement of urban areas and on consumer behaviour. Little attention has been paid, however, to employment in retailing, which is disturbing in view of its growing importance and its rapidly changing nature and composition. This paper examines the nature of the broad structural changes within the industry, and investigates their spatial consequences through a case study of employment generation within a system of suburban retail centres in Canberra, Australia. It is shown that the evolution of suburban centres, particularly those of a regional variety, has had an important and enriching impact on the suburban labour market. The regional centres are also seen to be the focus of the major structural employment changes currently affecting the retail industry. This has some important implications for urban planning.     

Diagenesis of Cretaceous sandstones of the Kootenay Formation at Elk Valley (southeastern British Columbia) and Mt Allan (southwestern Alberta)

Vitrinite reflectance data for two sections of the Kootenay Formation are different, but increase with depth. Illite crystallinities (XRD) are irregular with depth but detailed S.E.M. examination shows that crystal size and morphology increase with depth.At Elk Valley (low reflectance) S.E.M. examination shows kaolinite + dolomite as the authigenic assemblage. At Mt Allan (45 km north, higher reflectance) kaolinite disappears at 265 m and chlorite + calcite appears implying the equilibrium 5 CaMg(CO₃)₂ + Al₂Si₂O₅(OH)₄ + SiO₂ + H₂OagMg₅Al₂Si₃O₁₀(OH)₈ + 5CaCO₃ + 5CO₂. (1)Equilibrium (1) involves CO₂ and H₂O which form an immiscible fluid at diagenetic conditions. Thermochemical data, activity coefficients for the fluid mixture (Margules solution model), and fugacity coefficients allow the position of intersection of the miscibility surface and equilibria similar to (1) to be calculated. Maximum temperatures (180–250°C) in water-rich fluids are in accord with geothermal gradients of 33°C/km and temperatures from vitrinite reflectance (220°C). It is suggested that produced CO₂ may be responsible for the development of secondary porosity during deep burial.     

Soil water residence times and solute uptake on a dolomite bedrock—preliminary results

Calcium and magnesium levels have been monitored in slope foot drainage waters on a dolomite bedrock. Both calcium and magnesium rich pulses occur. Short term dissolution experiments demonstrate high calcium levels in solution while other authors have suggested that long residence time groundwater has relatively high levels of magnesium due to calcite precipitation. Patterns of field fluctuations in Ca: Mg ratios can thus be tentatively interpreted in terms of short residence time water of high calcium content mixing with long residence time water of high magnesium content. Fluorometric dye tracing has been used to indicate the orders of magnitude of soil water residence times, suggesting that quickflow components are resident in the system for a few hours to a few days. Further work is in progress.     

A scree slope rockfall model

Certain observed characteristics of scree slopes; namely concavity of profile, straight slope angle less than the angle of repose, and good size sorting of particles, are not consistent with an angle of repose model for accumulation. An alternative model is proposed based upon rockfall and surface stone movement and is tested against experimental data of particle movement in the field. It is found that the mechanical model of stone movement generated adequately explains the motion of particles on scree slopes and that it is in keeping with the characteristics of many screes. The static features of some Isle of Skye screes were also measured and the straight-concave slope form with good downslope sorting of material, characteristic of the rockfall process, was found to be present.     

Geochronology of Gran Canaria,Canary Islands: Age of shield building volcanism and other magmatic phases

Forty-six new K-Ar age determinations are presented on whole rock samples and mineral separates from volcanic and subvolcanic rocks of Gran Canaria. The main subaerial shield building basaltic volcanism with estimated volume of about 1000 km³ was confined to the interval about 13.7 m.y. to 13.5 m.y. ago in the middle Miocene. Substantial volume (～100 km³) of silicic volcanics (trachyte and peralkaline rhyolite) were erupted with no detectable time break following the basaltic volcanism, essentially contemporaneous with formation of a large collapse caldera at 13.4±0.3 m.y. ago. Trachytic to phonolitic volcanism continued intermittently in the waning states of activity until about 9 m.y. ago. Following a long hiatus there was resurgence of volcanism with eruption of about 100 km³ of basanitic to hauyne phonolitic rocks of the Roque Nublo Group between about 4.4 m.y. and 3.4 m.y. ago in the Pliocene. After a hiatus of less than 1.0 m.y., olivine nephelinite magmas were erupted and this activity continued intermittently until relatively recent times, the younger eruptives being mainly basanitic in composition. The volume of volcanic products in this phase probably does not exceed 10 km³. Thus the volume of all the resurgent volcanism comprises less than 10 percent of the subaerially exposed part of Gran Canaria. The results show that the subaerial main shield building phase of volcanism in Gran Canaria, consisting of mildly alkali to transitional basalts, occurred over a time interval that was less than 0.5 m.y. Magmatic evolution on Gran Canaria appears to be similar to that found on other basaltic volcanoes in oceanic regions. Thus volcanoes in the Hawaiian, Marquesas and Society Islands all were built by basaltic lavas in similar short-lived episodes of volcanism. In some Hawaiian volcanoes, a resurgent phase of volcanism of strongly undersaturated basalts of small volume is recognized following a long hiatus, again similar to that found on Gran Canaria. The relatively large volume of silicic lavas erupted in Gran Canaria immediately following the main basaltic shield building phase is, however, not matched in the Pacific volcanoes mentioned.     

Alkali-feldspars: Which solvus?

Variation in published alkali-feldspar solvus curves is discussed in the light of the concept of complete (crystal-crystal) and exchange (crystal-fluid-crystal) equilibrium. Exchange equilibrium may lead to very regular solvus-like two-phase curves differing substantially from the true binodal solvus; certain experimental strategies tend to favour the attainment and persistence of the exchange equilibrium condition. New long duration experiments under “alkali excess” and “alkali+silica excess” conditions did not yield fledspar pairs significantly off the bracketed binodal obtained by Smith and Parsons (1974) but exchange equilibrium behaviour is shown to influence the course of equilibration in peralkaline experiments. Agreement in solvus curves obtained by bracketing experiments by several workers is excellent (±2 mol. % Or) with a straight linear relationship between T _crit and P such that dT _crit/dP≈16°/Kbar. These curves do not exhibit breaks or sensitivity to chemical environment, and there is no evidence that the solvus changes shape with increasing P.     

Growth defects in metamorphic biotite

Metamorphic biotites examined by transmission electron microscopy contain planar defects on the (001) plane, superlattices, twins and a microstructure causing streaking of k≠3n rows. Analysis of the fringe contrast shows that the fault vectors associated with the planar defects are either R ₁=±1/3 [010], R ₂=±1/6 [310] or R ₃=±1/6 [3 \(\bar 1\) 0]. Structural considerations indicate that a stacking fault R ₁, R ₂ or R ₃ is most likely to exist in the octahedral layer rather than the potassium layer. The result of such a fault on a unit layer of mica is effectively to rotate it through ±120° about c* (equivalent to the common mica twin law). These stacking faults can provide the mechanism for producing the ±120° rotations associated with the common mica polytypes. Furthermore, many of the observed microstructures can be generated by these stacking faults.     

Armalcolite stability as a function of pressure and oxygen fugacity

The stability of synthetic armalcolite of composition (Fe_0.5Mg_0.5Ti₂O₅ was studied as a function of total pressure up to 15 kbar and 1200°C and also as a function of oxygen fugacity (?O₂) at 1200°C and 1 atm total pressure. The high pressure experiments were carried out in a piston-cylinder apparatus using silver-palladium containers. At 1200°C, armalcolite is stable as a single phase at 10 kbar. With increasing pressure, it breaks down ($\text{dT}\text{dP}\text{= 20°C/}\text{kbar}$), to rutile, a more magnesian armalcolite, and ilmenite solid solution. At 14 kbar, this three-phase assemblage gives way ($\text{dT}\text{dP}\text{= 30°C/}\text{kbar}$) to a two-phase assemblage of rutile plus ilmenite solid solution.A zirconian-armalcolite was synthesized and analyzed; 4 wt % ZrO₂ appears to saturate armalcolite at 1200°C and 1 atm. The breakdown of Zr-armalcolite occurs at pressures of 1–2 kbar less than those required for the breakdown of Zr-free armalcolite. The zirconium partitions approximately equally between rutile and ilmenite phases.The stability of armalcolite as a function of ?O₂ was determined thermogravimetrically at 1200°C and 1 atm by weighing sintered pellets in a controlled atmosphere furnace. Armalcolite, (Fe_0.5Mg_0.5)-Ti₂O₅, is stable over a range ?O₂ from about 10^?9.5to 10^?10.5 atm. Below this range to at least 10^?12.8 atm, ilmenite plus a reduced armalcolite are formed. These products were observed optically and by Mössbauer spectroscopy, and no metallic iron was detected; therefore, some of the titanium must have been reduced to Ti³⁺. This reduction may provide yet another mechanism to explain the common association of ilmenite rims around lunar armalcolites.