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911.
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Dissolved and particulate manganese in seawater samples derived from the English Channel has been analyzed using graphite furnace atomic absorption (GFAAS), and inductively coupled plasma atomic emission (ICP—AES) spectroscopies. Because of the high contents of carbonate minerals found in the suspended matter samples, the English Channel constitutes an ideal field area for the study of the Mn2+/Ca2+/CaCO3 system. Owing to the chemical speciation of particulate manganese and the combined use of the X-ray diffraction and electron spin resonance spectroscopy we have shown the importance of the carbonate phase in the stabilization of manganese (II). This has been confirmed by p-pH measurements in the field. All these studies have also indicated that: (1) manganese is associated with calcite in the form of a solid solution, MnxCa1−xCO3; and (2) significant increases in the concentrations of particulate manganese, especially in offshore waters, occur in summer. This seasonal phenomenon has been attributed to the proliferation of coccolithophorids, which are known to be covered with calcified skeletons at high specific surface areas. To appraise the implication of the coccolithophorid-blooms phenomenon on the Mn2+/Ca2+/CaCO3 system, we have used the manganese distribution coefficient, Di, between the liquid phase and CaCO3 particles. Overall we have shown that: (1) Di in summer (i.e. when coccoliths considered as very fine-grained calcite are abundant) is much higher than that obtained in winter; and (2) in the vicinity of the French coast, Di does not vary significantly even in summer. This is because of the high content of chalk-derived particles found in the near-shore waters. 相似文献
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917.
Short-Term Benthic Recolonization after Dredging in the Harbour of Ceuta, North Africa 总被引:2,自引:0,他引:2
Abstract. The benthic recovery after dredging (area: 2625 m2) was studied in a polluted and enclosed area of the harbour of Ceuta, in which the recolonization through the water column (larvae and adult bedload transport) could be limited by the lack of renewal. The benthos was sampled at two sites (control and dredged) using a van Veen grab and adopting a BACI (Before, After, Control, Impacted) approach. Five samplings were conducted after dredging (3, 15, 30, 90, 180 days). The proportion of gravel in the sediment of the dredged site increased after dredging, while the organic matter decreased. The impact on the community was estimated at species level, using both univariate and multivariate analyses. The maximum negative effect on benthic macrofauna was a reduction by 65% for species richness (15 days after dredging) and by 75% for abundance (3 days after dredging). Between 15 and 30 days after dredging, the abundance of some species such as the molluscs Parvicardium exiguum and Retusa obtusa and the polychaete Pseudomalacoceros tridentata increased considerably in the dredged site, while typical ‘opportunistic’ species such as Capitella capitata were disfavoured by the disturbance. For this small‐scale dredging, about 6 months are required for the disturbed area to re‐establish a sediment structure and a macrobenthic community similar to the undisturbed area. Small‐patch dredging operations are proposed in harbour management whenever possible, since they allow a quick re‐adjustment of the initial sediment structure and benthic communities. 相似文献
918.
Tide gauges distributed all over the world provide valuable information for monitoring mean sea level changes. The statistical models used in estimating sea level change from the tide gauge data assume implicitly that the random model components are stationary in variance. We show that for a large number of global tide gauge data this is not the case for the seasonal part using a variate-differencing algorithm. This finding is important for assessing the reliability of the present estimates of mean sea level changes because nonstationarity of the data may have marked impact on the sea level rate estimates, especially, for the data from short records. 相似文献
919.
920.
M. Tiwari R. Ramesh B. L. K. Somayajulu A. J. T. Jull G. S. Burr 《Geo-Marine Letters》2006,26(1):23-30
Rapid shifts in past climate recorded in polar ice sheets have elicited various explanations relating to either thermohaline
circulation changes by ice-rafting or natural greenhouse gas concentrations modulated by climatic conditions in the tropics.
To compare the tropical paleoclimate record with the polar record, one must choose sediment cores from highly productive ocean
regions. Necessarily, such regions reflect the wind records in the tropics, because high productivity is associated with upwelling
driven by winds. Comparing tropical precipitation records with high-latitude records is, however, a more difficult task because
sediments recording paleoprecipitation usually have low sedimentation rates, and offer coarser resolution relative to polar
ice cores. Here, we present δ
18O data of three planktonic species of Foraminifera (a proxy for precipitation) from such a sediment core, spanning the past
35 ka for the equatorial Indian Ocean, which falls under the southwest monsoon (SWM) realm. Results show that minimum SWM
precipitation occurred at the Last Glacial Maximum, with a subsequent increase at Termination IA. During the Holocene, SWM
precipitation intensified uniformly up to the core top (∼2.2 ka b.p.), as revealed by generally decreasing δ
18O values. Variations in precipitation are consistent with climate changes recorded in polar ice sheets. Although the different resolutions of the two records preclude
a rigorous comparison, abrupt cooling/warming events appear to be accompanied by sudden reduction/enhancement in (SWM) rainfall.
Thus, mechanisms with time scales much shorter than a millennium, such as natural greenhouse warming (e.g., CH4 concentration), controlled by emissions from the tropics, could have played a major role in high-latitude climate change. 相似文献