Shear-wave anisotropy: spatial and temporal variations in time delays at Parkfield, Central California

Shear-wave splitting is analysed on data recorded by the High Resolution Seismic Network (HRSN) at Parkfield on the San Andreas fault, Central California, during the three-year period 1988-1990. Shear-wave polarizations either side of the fault are generally aligned in directions consistent with the regional horizontal maximum compressive stress, at some 70° to the fault strike, whereas at station MM in the immediate fault zone, shear-wave polarizations are aligned approximately parallel to the fault. Normalized time delays at this station are found to be about twice as large as those in the rock mass either side. This suggests that fluid-filled cracks and fractures within the fault zone are elastically or seismically different from those in the surrounding rocks, and that the alignment of fault-parallel shear-wave polarizations are associated with some fault-specific phenomenon.
Temporal variations in time delays between the two split shear-waves before and after a M_L = 4 earthquake can be identified at two stations with sufficient data: MM within the fault zone and VC outside the immediate fault zone. Time delays between faster and slower split shear waves increase before the M_L = 4 earthquake and decrease near the time of the event. The temporal variations are statistically significant at 68 per cent confidence levels. Earthquake doublets and multiplets also show similar temporal variations, consistent with those predicted by anisotropic poroelasticity theory for stress modifications to the microcrack geometry pervading the rock mass. This study is broadly consistent with the behaviour observed before three other earthquakes, suggesting that the build-up of stress before earthquakes may be monitored and interpreted by the analysis of shear-wave splitting.     

Leucoxene fish as a micro-kinematic indicator

Asymmetric aggregates of fine-grained leucoxene and quartz are reported from siliceous L-S tectonites deformed by progressive simple shear. The leucoxene fish, morphologically similar to mica fish, consistently yield shear senses in agreement with other kinematic criteria. We interpret the leucoxene as a pre- or early syntectonic alteration product of detrital heavy-minerals in a siliciclastic protolith. The leucoxene fish behave as passive markers, and they record kinematics by modification of pre-existing aggregates rather than syndeformational mineral growth. For siliceous metasedimentary rocks otherwise lacking in micro-kinematic indicators, leucoxene fish may provide an alternative to quartz c-axis analysis.     

Arrays of Unpumped Wells for Plume Migration Control by Semi-Passive In Situ Remediation

Arrays of unpumped wells can be used as discontinuous permeable walls in which each well serves both as a means to focus ground water flow into the well for treatment and as a container either for permeable reactive media which directly destroy dissolved ground water contaminants or for devices or materials which release amendments that support in situ degradation of contaminants within the aquifer downgradient of the wells. This paper addresses the use of wells for amendment delivery, recognizing the potential utility of amendments such as electron acceptors (e.g., oxygen nitrate), electron donors (primary substrates), and microbial nutrients for stimulating bioremediation, and the potential utility of oxidizers, reducers, etc., for controlled abiotic degradation. Depending on its rate and constraints, the remedial reaction may occur within the well and/or downgradient. For complete remediation of ground water passing through the well array, the total flux of amendment released must meet or exceed the total flux demand imposed by the plume. When there are constraints on the released concentration of amendment (relative to the demand), close spacing of the wells may be required. If the flux balance allows wider spacing, it is likely that limited downgradient spreading of the released amendment will then be the primary constraint on interwell spacing. Divergent flow from the wells, roughly two times the well diameter, provides the bulk of downgradient spreading and constrains maximum well spacing in the absence of significant lateral dispersion. Stronger lateral dispersion enhances the spreading of amendment, thereby increasing the lateral impact of each well, which allows for wider well spacing.     

Cold anticyclonic eddies formed from cold pool water in the southern Middle Atlantic Bight

AVHRR satellite imagery of the southern Mid-Atlantic Bight during May 1993 revealed a large area of cold water over the shelf break and slope that appeared to spin up into a series of southward propagating anticyclonic eddies. The eddies had diameters of 35–45 km at the surface and moved southward at about 20 cm/sec. A radial TOYO CTD (to 50m) and ADCP velocity (to 400m) transect was conducted across the southern-most of these eddies. The upper 50 meters had minimum temperatures of less than 7°C and salinities of about 33 pss, characteristics similar to cold pool waters usually found over the continental shelf. ADCP velocity data from one of the eddies revealed anticyclonic flow extending to a depth of about 250m. The transport of cold pool water by the eddies was estimated to be 0.1 to 0.2 Sv which is of the same order as the annual mean alongshore transport of shelf water in this region. The origin of the deeper water within the eddy is unlikely to be the continental shelf because the shelf break is less than 100 m. The depth and velocity profiles along the TOYO transect were consistent with the constant potential vorticity eddy model of Flierl (1979) although the source of the eddy kinetic energy is uncertain. The cause for the exodus of cold pool water from the shelf, which extended northward to at least 38°N, is unclear but must involve the establishment of an alongshore baroclinic pressure gradient against the usual southwestward shelf flow. It is possible that the intrusion of Gulf Stream waters onto the shelf near Cape Hatteras was a precursor of this off shelf transport. The southern-most eddy was marked by high biological productivity and very high oxygen supersaturation. The phytoplankton bloom detected within the exported cold pool water, located over the continental slope, suggests a mechanism whereby production fueled by nutrients derived from the shelf can be locally exported into deep water.     

Radiative Exchange in an Urban Street Canyon

The influence of building geometry on the radiation terms ofthe surface energy balance is a principal reason for surfacetemperature differences between rural and urban areas.Methods exist to calculate the radiation balance in an urban area,but their validity across the range of urban geometries andmaterials has not been carefully considered.Here the exchange of diffuse radiation in an urban street canyon isinvestigated using a method incorporating all reflections of radiation.This exact solution is compared to two commonly used approximationsthat retain either no reflections, or just one reflection of radiation.The area-averaged net radiative flux density from the facets of the canyondecreases in magnitude monotonically as the canyon aspect ratio increases.The two approximate solutions possess unphysical differences from thismonotonic decrease for high canyon aspect ratios or low materialemissivities/high material albedos.The errors of the two approximate solutions are small for near blackbodymaterials and small canyon aspect ratios but can be an order ofmagnitude for intermediate material properties and deep street canyons.Urban street canyon models need to consider at least one reflectionof radiation and multiple reflections are desirable for full applicability.     

International and National Aspects of a Legislative Framework to Manage Soil Carbon Sequestration

This article discusses the international and national environmental law framework for the management of soil carbon sequestration. Aspects of the legislative framework important to this process include its ability to recognise carbon sinks, expand existing sinks, and the procedures available to return and store carbon in soil reservoirs. International law provides global standards and guidelines and national legislative systems provide the substantive and procedural legal mechanisms to manage soil carbon. The United Nations Framework Convention on Climate Change and the Kyoto Protocol are the primary international legislative instruments but other international instruments and strategies have a significant synergistic role. Various approaches are presented for framing new legislation or to reform existing legislative frameworks to improve the procedures to manage soil carbon.     

On the Incorporation of the Effect of Crustal Structure into Empirical Strong Ground Motion Estimation

This article has two purposes. Firstly, a validation exercise of the modal summation technique for the computation of synthetic strong-motion records is performed for two regions of Europe (Umbria-Marche and south Iceland), using a variety of region specific crustal structure models, by comparing the predicted ground motion amplitudes with observed motions. It is found that the rate of decay of ground motions is well predicted by the theoretical decay curves but that the absolute size of the ground motions is underpredicted by the synthetic time-histories. This is thought to be due to the presence of low-velocity surface layers that amplify the ground motions but are not included in the crustal structure models used to compute the synthetic time-histories. Secondly, a new distance metric based on the computed theoretical decay curves is introduced which should have the ability to model the complex decay of strong ground motions. The ability of this new distance metric to reduce the associated scatter in empirically derived equations for the estimation of strong ground motions is tested. It is found that it does not lead to a reduction in the scatter but this is thought to be due to the use of crustal structure models that are not accurate or detailed enough for the regions studied. This revised version was published online in July 2006 with corrections to the Cover Date.     

Oxygen isotopic compositions of IVA iron meteorites: implications for the thermal evolution derived from in situ ultraviolet laser microprobe analyses

Oxygen isotopic compositions of silicate inclusions in IVA iron meteorites have been measured with an in situ UV laser microprobe technique. The homogeneity of oxygen isotopic compositions within and among individual mineral grains has also been examined. Oxygen isotope fractionations between coexisting mineral pairs were utilized in oxygen isotope thermometry. Our measured Δ¹⁷O values, ranging from 0.97 to 1.25‰, are characteristic of a single reservoir and fully confirm the oxygen isotopic similarity between IVA irons and L/LL chondrites. Steinbach and São João Nepomuceno, containing inclusions of two silicate minerals in mutual contact, exhibit a mass-dependent fractionation of ¹⁸O/¹⁶O between tridymite and bronzite with apparent oxygen isotopic heterogeneity. The SiO₂-bearing member, Gibeon, gives homogeneous oxygen isotopic compositions without detectable fractionation of ¹⁸O/¹⁶O between tridymite and quartz. Oxygen isotope equilibrium temperatures are estimated for coexisting tridymite and bronzite in the same sample slabs or clusters in Steinbach and São João Nepomuceno. The fractionations of ¹⁸O/¹⁶O between bronzite and tridymite range from 1.6 to 2.3‰ in different sample slabs or clusters. On the basis of the closure temperature concept, cooling rates are estimated at approximately 20 to 1000°C/Myr between 800 and 1000°C, a range of temperatures not accessible to other cooling rate methods. Using the Fast Grain Boundary diffusion model, we have demonstrated that significant oxygen heterogeneity both in tridymite and bronzite is probably due to isotope exchange during cooling between minerals with various grain sizes and mineral abundances in different regions of the samples. The new estimates of cooling rate by oxygen isotope thermometry refine previous cooling curves of IVA irons and support the breakup-reassembly model for the IVA parent body.     

Geochemical Correlation Between Metasediments of the Mfongosi Group of the Natal Sector of the Namaqua-Natal Metamorphic Province, South Africa and the Ahlmannryggen Group of the Grunehogna Province, Antarctica

The whole-rock geochemistry of metamorphosed greywackes, arenites and arkoses within the Mesoproterozoic Namaqua-Natal-Maudheim Province is interpreted with the aim of establishing geochemical correlations and defining common sediment source terrains. Metasediments of the Mfongosi Group of the Natal Sector of the Namaqua-Natal Metamorphic Province were sampled from their type area in the Mfongosi Valley. Metagreywackes from the northern limits of the Mfongosi Valley, directly adjacent to the Kaapvaal Craton, show ocean island arc signatures while metagreywackes from the southern limits of the Mfongosi Valley, near the contact with the Madidima Thrust of the Natal nappe zone, show mainly active continental margin signatures. Interleaved, geochemically distinct low-Ca+Na, high-K metamorphosed arkoses to lithic arkoses indicate a minor passive margin sediment component. Geochemical classification of low-grade Ahlmannryggen Group greywackes, arenites and arkoses of the Grunehogna Province, Antarctica, indicates both active and passive continental margin sediment sources. An oceanic island arc signature is not evident in Ahlmannryggen Group data. The active continental margin signature in both Natal Sector and Grunehogna Province metasediments potentially provides for a common link between these terranes. Discriminant Function Analysis, using three pre-defined provenance sub-sets within the Mfongosi Group and two pre-defined provenance sub-sets within the Ahlmannryggen Group, indicate that metasediments with active continental margin signatures from both groups are geochemically identical, implying that the active continental margin of the Grunehogna Province shed immature sediments westwards (African azimuths) into the developing, narrow or restricted Mesoproterozoic ‘Mfongosi Basin.’ This was accompanied by minor sediment influx from a stable continental platform, potentially the Kaapvaal Craton. Oblique and diachronous collision, initiated in the southwestern portions of the combined Natal Sector/Grunehogna Province system produced a laterally variable Mfongosi Group, which formed in the ‘Mfongosi Basin’. Coarse-grained sediments dominated in its eastern portions while basalts with thin sapropelite units dominated in its western portions.