Implications of Nb/U, Th/U and Sm/Nd in plume magmas for the relationship between continental and oceanic crust formation and the development of the depleted mantle

The Nb/U and Th/U of the primitive mantle are 34 and 4.04 respectively, which compare with 9.7 and 3.96 for the continental crust. Extraction of continental crust from the mantle therefore has a profound influence on its Nb/U but little influence on its Th/U. Conversely, extraction of midocean ridge-type basalts lowers the Th/U of the mantle residue but has little influence on its Nb/U. As a consequence, variations in Th/U and Nb/U with Sm/Nd can be used to evaluate the relative importance of continental and basaltic crust extraction in the formation of the depleted (Sm/Nd enriched) mantle reservoir.This study evaluates Nb/U, Th/U, and Sm/Nd variations in suites of komatiites, picrites, and their associated basalts, of various ages, to determine whether basalt and/or continental crust have been extracted from their source region. Emphasis is placed on komatiites and picrites because they formed at high degrees of partial melting and are expected to have Nb/U, Th/U, and Sm/Nd that are essentially the same as the mantle that melted to produce them. The results show that all of the studied suites, with the exception of the Barberton, have had both continental crust and basaltic crust extracted from their mantle source region. The high Sm/Nd of the Gorgona and Munro komatiites require the elevated ratios seen in these suites to be due primarily to extraction of basaltic crust from their source regions, whereas basaltic and continental crust extraction are of subequal importance in the source regions of the Yilgarn and Belingwe komatiites. The Sm/Nd of modern midocean ridge basalts lies above the crustal extraction curve on a plot of Sm/Nd against Nb/U, which requires the upper mantle to have had both basaltic and continental crust extracted from it.It is suggested that the extraction of the basaltic reservoir from the mantle occurs at midocean ridges and that the basaltic crust, together with its complementary depleted mantle residue, is subducted to the core-mantle boundary. When the two components reach thermal equilibrium with their surroundings, the lighter depleted component separates from the denser basaltic component. Both are eventually returned to the upper mantle, but the lighter depleted component has a shorter residence time in the lower mantle than the denser basaltic component. If the difference in the recycling times for the basaltic and depleted components is ∼1.0 to 1.5 Ga, a basaltic reservoir is created in the lower mantle, equivalent to the amount of basalt that is subducted in 1.0 to 1.5 Ga, and that reservoir is isolated from the upper mantle. It is this reservoir that is responsible for the Sm/Nd ratio of the upper mantle lying above the trend predicted by extraction of continental crust on the plot of Sm/Nd against Nb/U.     

The effect of wildfire on runoff and erosion in native Eucalyptus forest

Wildfires raise concerns over the risk of accelerated erosion as a result of increased overland flow and decreased protection of the soil by litter and ground vegetation cover. We investigated these issues following the 1994 fires that burnt large areas of native Eucalyptus forest surrounding Sydney, Australia. A review of previous studies identifies the fire and rainfall conditions that are likely to lead to increased runoff and accelerated erosion. We then compare runoff and erosion between burnt and unburnt sites for 10 months after the 1994 fires. At the scale of hillslope plots, the 1994 fire increased runoff by enhancing soil hydrophobicity, and greatly increased sediment transport, mainly through the reduced ground cover, which lowered substantially the threshold for initial sediment movement. However, both runoff and sediment transport were very localized, resulting in little runoff or sediment yield after the fire at the hillslope catchment scale. We identify that after moderately intense fires, rainfall events of greater than one year recurrence interval are required to generate substantial runoff and sediment yield. Such events did not occur during the monitoring period. Past work shows that mild burns have little effect on erosion, and it is only after the most extreme fires that erosion is produced from small, frequent storms. © 1998 John Wiley & Sons, Ltd.     

A New Appraisal of Sri Lankan BB Zircon as a Reference Material for LA‐ICP‐MS U‐Pb Geochronology and Lu‐Hf Isotope Tracing

A potential zircon reference material (BB zircon) for laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) U‐Pb geochronology and Hf isotope geochemistry is described. A batch of twenty zircon megacrysts (0.5–1.5 cm³) from Sri Lanka was studied. Within‐grain rare earth element (REE) compositions are largely homogeneous, albeit with some variation seen between fractured and homogeneous domains. Excluding fractured cathodoluminescence bright domains, the variation in U content for all analysed crystals ranged from 227 to 368 μg g^?1 and the average Th/U ratios were between 0.20 and 0.47. The Hf isotope composition (0.56–0.84 g/100 g Hf) is homogeneous within and between the grains – mean ¹⁷⁶Hf/¹⁷⁷Hf of 0.281674 ± 0.000018 (2s). The calculated alpha dose of 0.59 × 10¹⁸ g^?1 for a number of BB grains falls within the trend of previously studied, untreated zircon samples from Sri Lanka. Aliquots of the same crystal (analysed by ID‐TIMS in four different laboratories) gave consistent U‐Pb ages with excellent measurement reproducibility (0.1–0.4% RSD). Interlaboratory assessment (by LA‐ICP‐MS) from individual crystals returned results that are within uncertainty equivalent to the TIMS ages. Finally, we report on within‐ and between‐grain homogeneity of the oxygen isotope systematic of four BB crystals (13.16‰ VSMOW).     

The Neogene and Quaternary of England: landscape evolution,tectonics, climate change and their expression in the geological record

During the Neogene and Quaternary, tectonic and climatic processes have had a profound impact upon landscape evolution in England and, perhaps as far back as 0.9 Ma, patterns of early human occupation. Until the Late Miocene, large-scale plate tectonic processes were the principal drivers of landscape evolution causing localised basin inversion and widespread exhumation. This drove, in places, the erosion of several kilometres of Mesozoic cover rocks and the development of a regional unconformity across England and the North Sea Basin. By the Pliocene, the relative influence of tectonics on landscape evolution waned as the background tectonic stress regime evolved and climatic influences became more prominent. Global-scale climate-forcing increased step-wise during the Plio-Pleistocene amplifying erosional and depositional processes that operated within the landscape. These processes caused differential unloading (uplift) and loading (subsidence) of the crust (‘denudational isostasy’) in areas undergoing net erosion (upland areas and slopes) and deposition (basins). Denudational isostasy amplified during the Mid-Pleistocene Transition (c.0.9 Ma) as landscapes become progressively synchronised to large-scale 100 ka ‘eccentricity’ climate forcing. Over the past 0.5 Ma, this has led to the establishment of a robust climate record of individual glacial/interglacial cycles enabling comparison to other regional and global records. During the Last Glacial-Interglacial Transition and early Holocene (c.16–7 ka), evidence for more abrupt (millennial/centennial) scale climatic events has been discovered. This indicates that superimposed upon the longer-term pattern of landscape evolution is a more dynamic response of the landscape to local and regional drivers.     

Using Diurnal Temperature Signals to Infer Vertical Groundwater‐Surface Water Exchange

Heat is a powerful tracer to quantify fluid exchange between surface water and groundwater. Temperature time series can be used to estimate pore water fluid flux, and techniques can be employed to extend these estimates to produce detailed plan‐view flux maps. Key advantages of heat tracing include cost‐effective sensors and ease of data collection and interpretation, without the need for expensive and time‐consuming laboratory analyses or induced tracers. While the collection of temperature data in saturated sediments is relatively straightforward, several factors influence the reliability of flux estimates that are based on time series analysis (diurnal signals) of recorded temperatures. Sensor resolution and deployment are particularly important in obtaining robust flux estimates in upwelling conditions. Also, processing temperature time series data involves a sequence of complex steps, including filtering temperature signals, selection of appropriate thermal parameters, and selection of the optimal analytical solution for modeling. This review provides a synthesis of heat tracing using diurnal temperature oscillations, including details on optimal sensor selection and deployment, data processing, model parameterization, and an overview of computing tools available. Recent advances in diurnal temperature methods also provide the opportunity to determine local saturated thermal diffusivity, which can improve the accuracy of fluid flux modeling and sensor spacing, which is related to streambed scour and deposition. These parameters can also be used to determine the reliability of flux estimates from the use of heat as a tracer.     

Dating megafaunal extinction on the Pleistocene Darling Downs,eastern Australia: the promise and pitfalls of dating as a test of extinction hypotheses

A key to understanding Late Pleistocene megafaunal extinction dynamics is knowledge of megafaunal ecological response(s) to long-term environmental perturbations. Strategically, that requires targeting fossil deposits that accumulated during glacial and interglacial intervals both before and after human arrival, with subsequent palaeoecological models underpinned by robust and reliable chronologies. Late Pleistocene vertebrate fossil localities from the Darling Downs, eastern Australia, provide stratigraphically-intact, abundant megafaunal sequences, which allows for testing of anthropogenic versus climate change megafauna extinction hypotheses. Each stratigraphic unit at site QML796, Kings Creek Catchment, was previously shown to have had similar sampling potential, and the basal units contain both small-sized taxa (e.g., land snails, frogs, bandicoots, rodents) and megafauna. Importantly, sequential faunal horizons show stepwise decrease in taxonomic diversity with the loss of some, but not all, megafauna in the geographically-small palaeocatchment. The purpose of this paper is to present the results of our intensive, multidisciplinary dating study of the deposits (>40 dates). Dating by means of accelerator mass spectrometry (AMS) ¹⁴C (targeting bone, freshwater molluscs, and charcoal) and thermal ionisation mass spectrometry U/Th (targeting teeth and freshwater molluscs) do not agree with each other and, in the case of AMS ¹⁴C dating, lack internal consistency. Scanning electron microscopy and rare earth element analyses demonstrate that the dated molluscs are diagenetically altered and contain aragonite cements that incorporated secondary young C, suggesting that such dates should be regarded as minimum ages. AMS ¹⁴C dated charcoals provide ages that occur out of stratigraphic order, and cluster in the upper chronological limits of the technique (～40–48 ka). Again, we suggest that such results should be regarded as suspicious and only minimum ages. Subsequent OSL and U/Th (teeth) dating provide complimentary results and demonstrate that the faunal sequences actually span ～120–83 ka, thus occurring beyond the AMS ¹⁴C dating window. Importantly, the dates suggest that the local decline in biological diversity was initiated ～75,000 years before the colonisation of humans on the continent. Collectively, the data are most parsimoniously consistent with a pre-human climate change model for local habitat change and megafauna extinction, but not with a nearly simultaneous extinction of megafauna as required by the human-induced blitzkrieg extinction hypothesis. This study demonstrates the problems inherent in dating deposits that lie near the chronological limits of the radiocarbon dating technique, and highlights the need to cross-check previously-dated archaeological and megafauna deposits within the timeframe of earliest human colonisation and latest megafaunal survival.     

Frequency dependence of elastic wave speeds at high temperature: a direct experimental demonstration

At sufficiently high temperatures and/or long periods, the elastic behaviour of crystalline material gives way progressively to viscoelastic behaviour associated with the stress-induced migration of crystal defects. This transition is marked by the onset of appreciable strain energy dissipation accompanied by frequency dependence (dispersion) of the shear modulus and elastic wave speeds. Ultrasonic interferometry and torsional forced-oscillation techniques can be used to probe the low-amplitude stress-strain behaviour of fine-grained polycrystalline material in two very different frequency ranges, respectively 10-100 MHz and 1 mHz-1 Hz. Here we demonstrate and apply these two complementary methods in a study of the high-temperature mechanical behaviour of a fine-grained synthetic olivine polycrystal. At the high frequencies of ultrasonic interferometry, the shear wave speed varies linearly with temperature between room temperature and the highest experimentally accessible temperature (1300 °C) in close accord with expectations based on similarly high-frequency studies of the elastic behaviour of single-crystal olivine. However, at teleseismic frequencies (<1 Hz) and temperatures >900 °C, the shear wave speed becomes much more strongly temperature-sensitive reflecting markedly viscoelastic behaviour. Newly emerging laboratory-derived constraints on this viscoelastic enhancement of the temperature sensitivity of seismic wave speeds and its grain-size dependence will provide a more robust interpretation of seismological models for the variation of wave speeds and attenuation within the Earth's interior.     

‘Committing to Place’ at the Local Scale: the potential of youth education programs for promoting community participation in regional natural resource management

Emerging approaches to environmental governance require a greater level of community participation than did previous approaches in which these responsibilities largely rested with government agencies. There is consequently a need for increased engagement with NRM among a broad community sector. This paper examines initiatives by two prominent government agencies, the Murray–Darling Basin Commission (MDBC) and the National Museum of Australia (NMA), to engage school children from regional communities using education programs that focus on place and environmental health. We focus on the MDBC's International Riverhealth Conference held in Mildura in 2003 and the associated Murray–Darling Basin TalkBack Classroom sponsored by the NMA and the Parliamentary Education Office (PEO). We explore how key themes of local scale, place-based identities, youth voice and critical engagement are developed in these programs and consider how they relate to the environmental agency of children. We then reflect on the potential for the kinds of environmental agency promoted through these programs to help build the capacity of local communities to progress larger goals of environmental restoration and sustainability in the Murray–Darling Basin. The evaluation research reported here forms part of the Committing to Place research project, an Australian Research Council Linkage grant involving the University of Tasmania, the National Museum of Australia and the Murray–Darling Basin Commission.     

Near-Wall Flow Development After A Step Change In Surface Roughness

An experimental study of the initial flow field downstream of a step change in surface roughness is presented. The roughness length of the downstream surface was approximately tenfold that of the upstream roughness and, unlike all previous studies, attention was concentrated on the roughness sublayer region beneath the inertial (log-law) region. The experiments were conducted at a boundary layer Reynolds number of about 6 × 10⁴ (based on layer thickness andfree-stream velocity) and around a longitudinal location where the (downstream) roughness length, z_o2, was about 1% of the boundary-layer thickness atthe roughness change point.The thickness of the roughness sublayer was found for the two roughness. It was observed that the vertical profiles of mean velocity and turbulence characteristics started to show similarity after about 160z₀₂ downstream of the roughness change. The presence of a shear stress overshoot is shown to depend strongly on the precise location (with respect to the roughness elements) at which the measurements are made and the thickness of the equilibrium layer is shown to be very sensitive to the way it is defined. It is demonstrated that the growing equilibrium layer has first to encompass the roughness sublayer before any thickness of inertial sublayer can be developed. It follows that, in somepractical cases, like flows across some urban environments, the latter(log-law) region may never exist at all.