Jorvik MIST – 2001

The magnetosphere, ionosphere and solar–terrestrial physics community gathered at the Department of Chemistry, University of York from 9–11 April 2001. Neil Arnold and Ian Mann report.     

Microbial–silica interactions in Icelandic hot spring sinter: possible analogues for some Precambrian siliceous stromatolites

Silicified deposits, such as sinters, occur in several modern geothermal environments, but the mechanisms of silicification (and crucially the role of microorganisms in their construction) are still largely unresolved. Detailed examination of siliceous sinter, in particular sections of microstromatolites growing at the Krisuvik hot spring, Iceland, reveals that biomineralization contributes a major component to the overall structure, with approximately half the sinter thickness attributed to silicified microorganisms. Almost all microorganisms observed under the scanning electron microscope (SEM) are mineralized, with epicellular silica ranging in thickness from < 5 μm coatings on individual cells, to regions where entire colonies are cemented together in an amorphous silica matrix tens of micrometres thick. Within the overall profile, there appears to be two very distinct types of laminae that alternate repeatedly throughout the microstromatolite: ‘microbial’ layers are predominantly consisting of filamentous, intact, vertically aligned, biomineralized cyanobacteria, identified as Calothrix and Fischerella sp.; and weakly laminated silica layers which appear to be devoid of any microbial component. The microbial layers commonly have a sharply defined base, overlying the weakly laminated silica, and a gradational upper surface merging into the weakly laminated silica. These cyclic laminations are probably explained by variations in microbial activity. Active growth during spring/summer allows the microorganisms to keep pace with silicification, with the cell surfaces facilitating silicification, while during their natural slow growth phase in the dark autumn/winter months silicification exceeds the bacteria’s ability to compensate (i.e. grow upwards). At this stage, the microbial colony is probably not essential to microstromatolite formation, with silicification presumably occurring abiogenically. When conditions once again become favourable for growth, recolonization of the solid silica surface by free‐living bacteria occurs: cell motility is not responsible for the laminations. We have also observed that microbial populations within the microstromatolite, some several mm in depth, appear viable, i.e. they still have their pigmentation, the trichomes are not collapsed, cell walls are unbroken, cytoplasm is still present and they proved culturable. This suggests that the bulk of silicification occurred rapidly, probably while the cells were still alive. Surprisingly, however, measurements of light transmittance through sections of the microstromatolite revealed that photosynthetically active light (PAL) only transmitted through the uppermost 2 mm. Therefore the ‘deeper’ microbial populations must have either: (i) altered their metabolic pathways; (ii) become metabolically inactive; or (iii) the deeper populations may be dominated by different microbial assemblages from that of the surface. From these collective observations, it now seems unequivocal that microstromatolite formation is intimately linked to microbial activity and that the sinter fabric results from a combination of biomineralization, cell growth and recolonization. Furthermore, the similarities in morphology and microbial component to some Precambrian stromatolites, preserved in primary chert, suggests that we may be witnessing contemporaneous biomineralization processes and growth patterns analogous to those of the early Earth.     

Dolomitization of the Waulsortian Limestone (Lower Carboniferous) in the Irish Midlands

The Waulsortian Limestone (Lower Carboniferous) of the southern Irish Midlands is dolomitized pervasively over a much larger region than previous studies have documented. This study indicates a complex, multistage, multiple fluid history for regional dolomitization. Partially and completely dolomitized sections of Waulsortian Limestones are characterized by finely crystalline (0·01–0·3 mm) planar dolomite. Planar replacive dolomite is commonly followed by coarse (≥0·5 mm) nonplanar replacive dolomite, and pervasive void‐filling saddle dolomite cement is frequently associated with Zn–Pb mineralization. Planar dolomite has average δ¹⁸O and δ¹³C values (‰ PDB) of –4·8 and 3·9 respectively. These are lower oxygen and slightly higher carbon isotope values than averages for marine limestones in the Waulsortian (δ¹⁸O=–2·2, δ¹³C=3·7). Mean C and O isotope values of planar replacive dolomite are also distinct from those of nonplanar and saddle dolomite cement (–7·0 and 3·3; –7·4 and 2·4 respectively). Fluid inclusions indicate a complex history involving at least three chemically and thermally distinct fluids during dolomite cementation. The petrography and geochemistry of planar dolomites are consistent with an early diagenetic origin, possibly in equilibrium with modified Carboniferous sea water. Where the Waulsortian was exposed to hydrothermal fluids (70–280 °C), planar dolomite underwent a neomorphic recrystallization to a coarser crystalline, planar and nonplanar dolomite characterized by lower δ¹⁸O values. Void‐filling dolomite cement is isotopically similar to nonplanar, replacive dolomite and reflects a similar origin from hydrothermal fluids. This history of multiple stages of dolomitization is significantly more complex than earlier models proposed for the Irish Midlands and provides a framework upon which to test competing models of regional vs. localized fluid flow.     

The beachwatch pollution monitoring programme: Changing priorities to recognize changed circumstances

Since the commissioning of the three major deepwater outfalls in Sydney, there has been a dramatic improvement in general beach water quality at Sydney's ocean beaches. This has required the NSW Environment Protection Authority's Beachwatch Programme to shift from assessing the impacts of gross sewage pollution due to nearshore outfalls to more diffuse pollution from stormwater and sewer overflows.

The visual indicators of gross sewage pollution originally used by Beachwatch for the daily assessment of bacterial water quality are now of limited value. General linear models (with multiple effects) were constructed to identify the secondary indicators which best describe the levels of bacterial contamination due to stormwater pollution. Data from four representative Sydney beaches were modelled separately due to the site-specific effects of pollution sources and hydrodynamics. Factors which were built into the models and were known on the day of prediction were rain amount, presence of stormwater material, the maximum daily stormwater rating, drain or lagoon flows at the time of sampling, and the drain/lagoon bacterial concentration two days before sampling.

Results indicate that there is a general linear relationship between visual indicators and bacterial density; however, the reliability of the prediction on a daily basis is poor and rainfall alone as a predictor is equivalent to or better than visual assessment alone. The primary source of information for the preparation of Beachwatch daily pollution bulletins now is rainfall reports from a telemetered network of rain gauges along the coast. This is a more cost-effective approach and has allowed the reallocation of resources to address more directly the problem of stormwater pollution at higher risk beaches.     

Morphological characteristics of the earthquake surface ruptures on Awaji Island, associated with the 1995 Southern Hyogo Prefecture Earthquake

Abstract The earthquake surface ruptures on the northern side of Awaji Island accompanying the 1995 Southern Hyogo Prefecture Earthquake in Japan consist of three earthquake surface rupture zones called the Nojima, Matsuho, and Kusumoto Earthquake Surface Rupture Zones. The Nojima Earthquake Surface Rupture Zone is - 18 km long and was formed from Awaji-cho at the northern end of Awaji Island to Ichinomiya-cho. It occurred along the pre-existing Nojima geological fault in the northern segment and as a new fault in the southern segment. The northern segment of the Nojima Earthquake Surface Rupture Zone is composed of some subparallel shear faults showing a right-step en echelon form and many extensional cracks showing a left-step en echelon form. The southern segment consists of some discontinuous surface ruptures which are concentrated in a narrow zone a few tens of meters in width. This surface rupture zone shows a general trend striking north 30°-60° east, and dipping 75°-85° east. The deformational topographies and striations on the fault plane generated during the co-seismic displacement show that the Nojima Earthquake Surface Rupture Zone is a right-lateral strike-slip fault with some reverse component. Displacements measured at many of the outcrops are generally 100-200 em horizontally and 50-100 em vertically in the northern segment and a few em to 20 em both horizontally and vertically in the southern segment. The largest displacements are 180 em horizontally, 130 em vertically, and 215 em in netslip measured at the Hirabayashi fault scarp. The Matsuho Earthquake Surface Rupture Zone striking north 40°-60° west was also found along the coastline trending northwest-southeast in Awaji-cho for ～1 km at the northern end of Awaji Island. The Kusumoto Earthquake Surface Rupture Zone occurred along the pre-existing Kusumoto geological fault for ～ 1.5 km near the northeastern coastline, generally striking north 35°-60° east, dipping 60°-70° west. From the morphological and geomorphological characteristics, the Nojima Earthquake Surface Rupture Zone can be divided into four segments which form a right-step en echelon formation. The geological and geomorphological evidence and the aftershock epicenter distributions show clearly that the distributions and geometry of these four segments are controlled by the pre-existing geological structures.     

Deuterium tracing for the estimation of transpiration from trees Part 1. Field calibration

Flow rates calculated using the deuterium tracing method were compared with measurements of direct water uptake of excavated trees which had been inserted into water containers. Taking into account that the tracing method provides an estimate of the weighted mean flow rate over the period that the tracer pulse is present (the weighting factor is the relative concentration of the tracer as measured at the sampling point) agreement was obtained within the experimental error (about 10%) associated with the tracing method.     

Evidence for the trapped liquid shift effect in the Mount Ayliff Intrusion,South Africa

Postcumulus trapped liquid shift in layered complexes produces cumulate minerals with more fractionated compositions than the original primary phases. This effect is shown by olivine compositions from the base of the Mount Ayliff Intrusion, where varying proportions of olivine to interstitial liquid produce a suite of rocks which define a tight linear trend on a binary whole-rock plot of MgO versus FeO. Extrapolation of this trend constrains the composition of the primary cumulus olivine to the range Fo_84–86, whereas olivine actually present have compositions Fo_77–83. The magnitude of the discrepancy between the theoretical and observed olivine compositions correlates directly with the weight fraction of interstitial liquid. These observations are quantitatively predicted by the trapped liquid shift model. They also argue against significant migration of residual liquid. Trapped liquid shift is documented over a vertical interval of 60 m. It occurred in rocks lying only 1 m above the basal contact of the intrusion and hence must be a comparatively rapid process.     

Estimates of total radiation and albedo in Sub-Arctic Canada

Summary Maps have recently been prepared of the physiography and plant cover of Labrador-Ungava, in the Canadian Sub-Arctic. These enable detailed studies of representative localities to be extended over wider areas. Methods of estimating the average total insolation from sun and sky received at the surface are discussed, together with aerial measurements of albedo and thus a method of calculating the insolation absorbed by the surface is demonstrated. The limitations of the technique are stressed.

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Zusammenfassung Es wurden Karten der Physiographie und Pflanzenbedeckung von Labrador-Ungava im sub-arktischen Klimagebiet Kanadas bearbeitet; an Hand dieser Karten kann von einzelnen, repräsentativen Orten auf die Verhältnisse in größeren Gebieten geschlossen werden. Die Methoden zur Abschätzung der Globalstrahlung an der Erdoberfläche werden diskutiert. Zusammen mit Messungen der Albedo vom Flugzeug aus ergibt sich eine Möglichkeit, die vom Erdboden absorbierte Strahlungsenergie zu berechnen. Die Grenzen der Leistungsfähigkeit dieser Methode werden betont.

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Résumé On a dressé des cartes de la physiographie et de la couverture végétale du Labrador-Ungava soumis au climat subarctique du Canada. Elles permettent d'étendre les conclusions relatives à certains lieux représentatifs à de plus grands territoires. Discussion des méthodes d'estimation du rayonnement global à la surface du sol. En tentant compte de mesures de l'albédo faites depuis l'avion, on peut calculer l'énergie de rayonnement absorbée par le sol. Les limites d'application de la méthode sont discutées.

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The research described in this paper was sponsored jointly by the Carnegie Arctic Programme of McGill University and the Defence Research Board of Canada.     

The petrology of the Las Canadas volcanoes,Tenerife, Canary islands

Tenerife is the largest of the seven Tertiary to Recent volcanic islands that make up the Canary Archipelago. The island is composed of volcanics belonging to the basanitetrachyte-phonolite assemblage that characterises many Atlantic islands. The most voluminous development of intermediate and salic volcanics has been in the centre of the island where the Las Canadas volcanoes arose upon a basement shield composed mainly of basanite and ankaramite flows, tuffs and agglomerates. The initial post-shield activity built the Vilaflor volcanic complex (Lower and Upper Canadas Series) that originally covered much of the underlying shield volcanics. A vast collapse of the complex, probably during post-Pleistocene times, in the centre of the island has left a large semi-circular wall, and provides an excellent vertical section through the complex. Quaternary volcanism within the collapsed area has built the twin, central-type volcanoes, Viejo and Teide, both of which have attendant satellite vents. That part of the Vilaflor Complex exposed in Las Canadas, together with the Viejo and Teide volcanoes, comprise the Las Canadas volcanoes.Four distinct rock types can be recognised in these volcanoes, basanite, trachybasanite, plagioclase phonolite, and phonolite. Each rock type can be recognised chemically and mineralogically, but there is essentially a gradational series from basanite to phonolite that includes both aphyric and glomerophyric rocks. The volcanics are strongly undersaturated and sodic, and some of the phonolites are mildly peralkaline. Variations in degree of undersaturation, and trace element abundances indicate a number of cycles of activity which would be consistent with the known field relations.Forsteritic olivine occurs in the basanites and trachybasanites but is not a stable phase in the more salic volcanics. Clinopyroxene is ubiquitous, varying in composition from titanaugite in the basanites to slightly sodic augite in the phonolites. Strongly sodic pyroxene is restricted to the groundmass of the microcrystalline phonolites along with aenigmatite and a kataphoritic amphibole. Plagioclase is found only in the groundmass of the basanites, but andesine and potash-oligoclase are common phenocryst minerals in the trachybasanites and plagioclase phonolites respectively, whereas the characteristic feldspar of the phonolites is anorthoclase.The relatively smooth curves of major and trace element variation, the presence of accumulative volcanics at all stages of differentiation, zoning of the mineral phases, and the clustering of the phonolites around the low temperature trough in Petrogeny's Residua System, all indicate that the descent from basanite to phonolite has resulted from fractional crystallisation of a basanite parent magma. The trend of pyroxene crystallisation, and the fairly constant FeO/Fe₂O₃ ratio during fractionation indicate crystallisation under low PO₂ conditions.