Hydrogeological processes controlling the release of arsenic in parts of 24 Parganas district,West Bengal

A study was conducted to understand the hydrogeological processes dominating in the North 24 Parganas and South 24 Parganas based on representative 39 groundwater samples collected from selected area. The abundance of major ions was in the order of Ca²⁺ > Na⁺ > Mg²⁺ > K⁺ > Fe²⁺ for cations and HCO₃ ^? > PO₄ ^3? > Cl^? > SO₄ ^2? > NO₃ ^? for anions. Piper trilinear diagram was plotted to understand the hydrochemical facies. Most of the samples are of Ca-HCO₃ type. Based on conventional graphical plots for (Ca + Mg) vs. (SO₄ + HCO₃) and (Na + K) vs. Cl, it is interpreted that silicate weathering and ion exchange are the dominant processes within the study area. Previous studies have reported quartz, feldspar, illite, and chlorite clay minerals as the major mineral components obtained by the XRD analysis of sediments. Mineralogical investigations by SEM and EDX of aquifer materials have shown the occurrence of arsenic as coating on mineral grains in the silty clay as well as in the sandy layers. Excessive withdrawal of groundwater for irrigation and drinking purposes is responsible for fluctuation of the water table in the West Bengal. Aeration beneath the ground surface caused by fluctuation of the water table may lead to the formation of carbonic acid. Carbonic acid is responsible for the weathering of silicate minerals, and due to the formation of clay as a product of weathering, ion exchange also dominates in the area. These hydrogeological processes may be responsible for the release of arsenic into the groundwater of the study area, which is a part of North 24 Parganas and South 24 Parganas.     

Post-peak,fluid-mediated modification of granulite facies zircon and monazite in the Trivandrum Block,southern India

The quarry at Kottavattom in the Trivandrum Block of southern India contains spectacular examples of fluid-assisted alteration of high-grade metamorphic rocks. Garnet-biotite gneiss has undergone a change in mineral assemblage to form submetre scale orthopyroxene-bearing patches, later retrogressed to form an amphibole-bearing lithology. These patches, often referred to as arrested or incipient charnockite, crosscut the original metamorphic foliation and are typically attributed to passage of a low aH₂O fluid through the rock. Whilst this conversion is recognised as a late stage process, little detailed chronological work exists to link it temporally to metamorphism in the region. Zircon and monazite analysed from Kottavattom not only record metamorphism in the Trivandrum Block but also show internal, lobate textures crosscutting the original zoning, consistent with fluid-aided coupled dissolution-reprecipitation during formation of the orthopyroxene-bearing patches. High-grade metamorphism at the quarry occurred between the formation of metamorphic monazite at ~585 Ma and the growth of metamorphic zircon at ~523 Ma. The fluid-assisted alteration of the garnet-biotite gneiss is poorly recorded by altered zircon with only minimal resetting of the U–Pb system, whereas monazite has in some cases undergone complete U–Pb resetting and records an age for fluid infiltration at ~495 Ma. The fluid event therefore places the formation of the altered patches at least 25 Myr after the zircon crystallisation in the garnet-biotite gneiss. The most likely fluid composition causing the modification and U–Pb resetting of zircon and monazite is locally derived hypersaline brine.     

Global very long-baseline interferometry observations of compact radio sources in M82

Observations of the starburst galaxy, M82, have been made with a 20-station global very long-baseline interferometry (VLBI) array at λ 18 cm. Maps are presented of the brightest young supernova remnants (SNR) in M82 and the wide-field mapping techniques used in making images over a field of view of ∼1 arcmin with 3-milliarcsecond resolution are discussed. A limit has been placed on the power-law deceleration of the young supernova remnant (SNR) 43.31+592 with an index greater than 0.73±0.11 from observations with the European VLBI Network. Using the global array we have resolved compact knots of radio emission in the source which, with future global observations, will enable better constraints to be placed on the expansion parameters of this SNR.
The latest global observations have also provided high-resolution images of the most compact radio source in M82, 41.95+575. We determine an upper limit to the radial expansion rate along the major axis of 2000 km s⁻¹. However, the new images also show structure resembling that of collimated ejection which brings into question the previous explanation of the source as being a result of the confinement of a supernova by a high-density circumstellar medium.
It is apparent that we are now able to image the brightest supernova remnants in M82 with a linear scale which allows direct comparison with galactic SNR such as Cassiopeia A.     

Propagation of magnetoacoustic-gravity waves in a horizontally-stratified medium: IV. kinematics

A model magneto-atmosphere is used to discuss the behavior of the group velocity for magnetoacoustic-gravity (MAG) waves as a function of their angular frequency. The qualitative frequency/time history of a signal generated by a source differs significantly from the case where the magnetic field is zero, for which a clear distinction may be made between the acoustic and gravity components of the signal.     

Achieving additional emission reductions under a cap-and-trade scheme

Over the last decade, cap-and-trade emissions schemes have emerged as one of the favoured policy instruments for reducing GHG emissions. An inherent design feature of cap-and-trade schemes is that, once the cap on emissions has been set, no additional reductions beyond this level can be provided by the actions of those individuals, organizations and governments within the covered sectors. Thus, the emissions cap constitutes an emissions floor. This feature has been claimed by some to have undesirable implications, in that it discourages ethically motivated mitigation actions and preempts the possibility that local, state and national governments can take additional mitigation action in the context of weak national or regional targets. These criticisms have become prominent in Australia and the US within the public debate regarding the adoption of an emissions trading scheme (ETS). These criticisms and their potential solutions are reviewed. A set-aside reserve is proposed to automatically retire ETS permits, which would correspond to verified and additional emissions reductions. This minimizes the possibility that ethically motivated mitigation actions are discouraged, allows for additional action by other levels of government, while providing transparency to other market participants on the level of permit retirements.     

Comparison of the Energy Spectra and Number Fluxes From a simple Flare Model to Observations

In this paper, we investigate the energy spectra produced by a simple test particle X-point model of a solar flare for different configurations of the initial electromagnetic field. We find that once the reconnection electric field is larger than 1 Vm^-1 the particle distribution transits from a heated one to a partially accelerated one. As we close the separatrices of the X-point and the angle in the inflow direction widens we find that more particles are accelerated out of the thermal distribution and this power–law component extends to lower energies. When we introduce a guiding magnetic field component we find that more particles are energised, but only up to a maximum energy dictated primarily by the reconnection electric field. Despite being able to accelerate particles to observable energies and demonstrate behaviour in the energy spectra that is consistent with observations, this single X-line model can only deliver the number fluxes required for microflares.     

Spectroscopic anatomy of a meteor trail cross section with the European Southern Observatory Very Large Telescope

Abstract— A meteor spectrum was recorded serendipitously at the European Southern Obrervatory (ESO) Very Large Telescope (VLT) during a long exposure in long‐slit spectroscopic mode with FORS1. The ?8 magnitude fireball crossed the narrow 1Î × 7î slit during the observation of a high z supernova in normal service mode operation on May 12, 2002. The spectrum covered the range of 637–1050 nm, where the meteor's air plasma emissions from N₂, N, and O dominate. Carbon atom emission was not detected in the relatively unexplored wavelength range above 900 nm, but the observed upper limit was only 3 sigma less than expected from the dissociation of atmospheric CO₂. The meteor trail was resolved along the slit, and the emission had a Gaussian distribution with a dimension of FWHM = 7.0 (±0.4) * sin(α) * H (km)/90 m, where α is the unknown angle between the orientation of the meteor path and slit and H the assumed altitude of the meteor in km. To our knowledge, this is the first observation of a spatially resolved spectrum across a meteor trail. Unlike model predictions, the plasma excitation temperature varied only from about 4,300 to 4,365 K across the trail, based on the ratio of atomic and molecular nitrogen emissions. Unfortunately, we conclude that this was because the meteor at 100 km altitude was out of focus.     

Woodleigh impact structure,Australia: Shock petrography and geochemical studies

Abstract— The large, complex Woodleigh structure in the Carnarvon basin of Western Australia has recently been added to the terrestrial impact crater record. Many aspects of this structure are, however, still uncertain. This work provides a detailed petrographic assessment of a suite of representative drill core samples from the borehole Woodleigh 1 that penetrated uplifted basement rocks of the central part of this structure. Fundamental rock and mineral deformation data and high‐precision chemical data, including results of PGE and oxygen isotopic analysis, are presented. The sampled interval displays likely impact‐produced macrodeformation in the form of fracturing and breccia veining at the microscopic scale. Contrary to earlier reports that these breccias represent pseudotachylite (friction melt) or even shock/shear‐produced pseudotachylitic melt breccia cannot be confirmed due to pervasive post‐impact alteration. Abundant planar deformation features (PDFs) in quartz, in addition to diaplectic glass and partial isotropization, are the main shock deformation effects observed, confirming that Woodleigh is of impact origin. Over the investigated depth interval, the statistics of quartz grains with a variable number of sets of PDFs does not change significantly, and the patterns of crystallographic orientations of PDFs in randomly selected quartz grains does not indicate a change in absolute shock pressure with depth either. The value of oxygen isotopes for the recognition of meteoritic contamination, as proposed by earlier Woodleigh workers, is critically assessed. Neither INA nor PGE analyses of our samples support the presence of a meteoritic component within this basement section, as had been claimed in earlier work.