The rheology of olivine and spinel magnesium germanate (Mg2GeO4): TEM study of the defect microstructures

Synthetic polycrystals of α-Mg₂GeO₄ (with the olivine structure) and γ-Mg₂GeO₄ (with the spinel structure) deformed at high temperature and pressure in their respective stability fields were investigated by analytical transmission electron microscopy. Specimens with a mean grain size of 20–30 µm deform by dislocation glide and/or climb. The predominance of glide versus climb depends on stress and grain orientation. The defect microstructures of both polymorphs are very similar to those observed in their respective silicate analogues, α- and γ-(Mg,Fe)₂SiO₄, and, in the case of the spinel phase, very similar to those observed in magnesium aluminate spinels. These observations suggest that Mg₂GeO₄ is a good rheological analogue for the Earth’s upper mantle. A spinel specimen deformed under the same conditions of temperature and strain rate as an olivine specimen was approximately three times stronger than olivine. In specimens of both phases deformed at or above 1400 K, a thin amorphous film composed of Mg, Ge, and O was detected along some grain boundaries. Grains ≤10 µm diameter surrounded by a film of amorphous phase (>10 nm thick) exhibited low dislocation densities, and deformation appeared to have occurred by grain boundary sliding.     

Linking snowmelt‐derived fluxes and groundwater flow in a high elevation meadow system,Sierra Nevada Mountains,California

Quantifying snowmelt‐derived fluxes at the watershed scale within hillslope environments is critical for investigating local meadow scale groundwater dynamics in high elevation riparian ecosystems. In this article, we investigate the impact of snowmelt‐derived groundwater flux from the surrounding hillslopes on water table dynamics in Tuolumne Meadows, which is located in the Sierra Nevada Mountains of California, USA. Results show water levels within the meadow are controlled by a combination of fluxes at the hillslope boundaries, snowmelt within the meadow and changes in the stream stage. Observed water level fluctuations at the boundaries of the meadow show the hydrologic connection and subsequent disconnection between the hillslope and meadow aquifers. Timing of groundwater flux entering the meadow as a result of spring snowmelt can vary over 20 days based on the location, aspect, and local geology of the contributing area within the larger watershed. Identifying this temporal and spatial variability in flux entering the meadow is critical for simulating changes in water levels within the meadow. Model results can vary significantly based on the temporal and spatial scales at which watershed processes are linked to local processes within the meadow causing errors when boundary fluxes are lumped in time or space. Without a clear understanding of the surrounding hillslope hydrology, it is difficult to simulate groundwater dynamics within high elevation riparian ecosystems with the accuracy necessary for understanding ecosystem response. Copyright © 2010 John Wiley & Sons, Ltd.     

A framework for understanding the hydroecology of impacted wet meadows in the Sierra Nevada and Cascade Ranges, California, USA

Meadows of the Sierra Nevada and Cascade mountains of California, USA, support diverse and highly productive wet-meadow vegetation dominated by sedges, rushes, grasses, and other herbaceous species. These groundwater–dependent ecosystems rely on the persistence of a shallow water table throughout the dry summer. Case studies of Bear Creek, Last Chance, and Tuolumne meadow ecosystems are used to create a conceptual framework describing groundwater–ecosystem connections in this environment. The water requirements for wet-meadow vegetation at each site are represented as a water-table-depth hydrograph; however, these hydrographs were found to vary among sites. Causes of this variation include (1) differences in soil texture, which govern capillary effects and availability of vadose water and (2) elevation-controlled differences in climate that affect the phenology of the vegetation. The field observations show that spatial variation of water-table depth exerts strong control on vegetation composition and spatial patterning. Groundwater-flow modeling demonstrates that lower hydraulic-conductivity meadow sediments, higher groundwater-inflow rates, and a higher ratio of lateral to basal-groundwater inflow all encourage the persistence of a high water table and wet-meadow vegetation, particularly at the margin of the meadow, even in cases with moderate stream incision.     

Lithospheric structure and tectonics at Isidis Planitia, Mars

We characterize the lithospheric structure of Isidis Planitia on Mars by analyzing Mars Global Surveyor and Mars Odyssey gravity and topography data using a flexural model of a thin elastic shell including bending and membrane stresses. Isidis Planitia is a circular, relatively flat plain formed near the end of the Early Noachian, at the edge of the highlands-lowlands boundary and the site of a large free-air gravity anomaly, features consistent with modification and filling of an impact basin. Our results suggest that the bulk density of the fill material inside Isidis must be more than 2600 kg m⁻³ and higher densities are probable. A comparison of the faulting observed at Nili Fossae to the predicted zone of extensional strain northwest of Isidis constrains the thickness of the elastic lithosphere to be 100-180 km thick beneath the basin at the time of loading. We also find that loads outside of the basin play a significant role in the interpretation of the tectonics; simplified models tend to overestimate the lithospheric thickness. We place relatively narrow bounds on the thermal gradient (3.4-6.5 K km⁻¹) and heat flux (13.6-26 mW m⁻²) at Isidis at the time of loading.     

Despinning plus global contraction and the orientation of lobate scarps on Mercury: Predictions for MESSENGER

Observations by the Mariner 10 spacecraft suggest that the lobate scarps on Mercury, which have been interpreted to record at most 1-2 km of radial contraction of the planet after the end of the Late Heavy Bombardment, possess a global, preferred N-S orientation but lack a strong latitudinal dependence on their surface expression. Here, we reexamine the idea that a decrease in the planetary rotation rate (despinning) coupled with global contraction of at least 3-5.5 km prior to the end of Late Heavy Bombardment resulted in global N-S oriented thrust faults. The surface expression of these faults is assumed to have been erased by the end of the Late Heavy Bombardment, and the faults were subsequently reactivated by later global contraction, producing generally N-S oriented thrust faults from an isotropic stress field. We use the estimate of >3-5.5 km contraction prior to ∼4 Ga as an additional constraint to thermomechanical simulations of the evolution of Mercury, finding that a wide range of models are consistent with this observation. The fact that a wide range of states are consistent with the contraction of Mercury prior to the end of Late Heavy Bombardment but only a restricted set of states are consistent with the at most 1-2 km of subsequent contraction bolsters the idea that there may be hidden strain on Mercury, features unseen by Mariner 10 but likely visible to the MESSENGER spacecraft.     

Adsorption of l-aspartate to rutile (α-TiO2): Experimental and theoretical surface complexation studies

Interactions between aqueous amino acids and mineral surfaces influence many geochemical processes from biomineralization to the origin of life. However, the specific reactions involved and the attachment mechanisms are mostly unknown. We have studied the adsorption of l-aspartate on the surface of rutile (α-TiO₂, pH_PPZC = 5.4) in NaCl(aq) over a wide range of pH, ligand-to-solid ratio and ionic strength, using potentiometric titrations and batch adsorption experiments. The adsorption is favored below pH 6 with a maximum of 1.2 μmol of adsorbed aspartate per m² of rutile at pH 4 in our experiments. The adsorption decreases at higher pH because the negatively charged aspartate molecule is repelled by the negatively charged rutile surface above pH_PPZC. At pH values of 3-5, aspartate adsorption increases with decreasing ionic strength. The adsorption of aspartate on rutile is very similar to that previously published for glutamate (Jonsson et al., 2009). An extended triple-layer model was used to provide a quantitative thermodynamic characterization of the aspartate adsorption data. Two reaction stoichiometries identical in reaction stoichiometry to those for glutamate were needed. At low surface coverages, aspartate, like glutamate, may form a bridging-bidentate surface species binding through both carboxyl groups, i.e. “lying down” on the rutile surface. At high surface coverages, the reaction stoichiometry for aspartate was interpreted differently compared to glutamate: it likely involves an outer-sphere or hydrogen bonded aspartate surface species, as opposed to a partly inner-sphere complex for glutamate. Both the proposed aspartate species are qualitatively consistent with previously published ATR-FTIR spectroscopic results for aspartate on amorphous titanium dioxide. The surface complexation model for aspartate was tested against experimental data for the potentiometric titration of aspartate in the presence of rutile. In addition, the model correctly predicted a decrease of the isoelectric point with increased aspartate concentration consistent with previously published studies of the aspartate-anatase system. Prediction of the surface speciation of aspartate on rutile indicates that the relative proportions of the two complexes are a strong function of environmental conditions, which should be taken into account in considerations of geochemical systems involving the interactions of biomolecules and minerals in electrolyte solutions.