The history of water salinity in the Pearl River estuary,China, during the Late Quaternary

This research reconstructed the Late Quaternary salinity history of the Pearl River estuary, China, from diatom records of four sedimentary cores. The reconstruction was produced through the application of a diatom–salinity transfer function developed based on 77 modern surface sediment samples collected across the estuary from shallow marine environment to deltaic distributaries. The statistical analysis indicates that the majority of sediment samples from the cores has good modern analogues, thus the reconstructions are reliable. The reconstructed salinity history shows the older estuarine sequence formed during the last interglacial was deposited under similar salinity conditions to the younger estuarine sequence, which was formed during the present interglacial. Further analysis into the younger estuarine sequence reveals the interplays between sea level, monsoon‐driven freshwater discharge, and deltaic shoreline movement, key factors that have influenced water salinity in the estuary. In particular, a core from the delta plain shows the effects of sea‐level change and deltaic progradation, while cores from the mouth region of the estuary reveal changes of monsoon‐driven freshwater discharge. This study demonstrates the advantages of quantitative salinity reconstructions to improve the quality of reconstruction and allow direct comparison with other quantitative records and the instrumentally observed values of salinity. Copyright © 2010 John Wiley & Sons, Ltd.     

The Scale of VGI in Map Production: A Perspective on European National Mapping Agencies

The perspective of European National Mapping Agencies (NMA) on the role of citizen sensing in map production was explored. The NMAs varied greatly in their engagement with the community generating volunteered geographic information (VGI) and in their future plans. From an assessment of NMA standard practices, it was evident that much VGI was acquired with a positional accuracy that, while less than that typically acquired by NMAs, actually exceeded the requirements of the nominal data capture scale used by most NMAs. Opportunities for VGI use in map revision and updating were evident, especially for agencies that use a continuous rather than cyclical updating policy. Some NMAs had also developed systems to engage with citizen sensors and examples are discussed. Only rarely was VGI used to collect data on features beyond the standard set used by the NMAs. The potential role of citizen sensing and so its current scale of use by NMAs is limited by a series of concerns, notably relating to issues of data quality, the nature and motivation of the contributors, legal issues, the sustainability of data source, and employment fears of NMA staff. Possible priorities for future research and development are identified to help ensure that the potential of VGI in mapping is realized.     

Severe soil erosion during a 3‐day exceptional rainfall event: combining modelling and field data for a fallow cereal field

Exceptional rainfall events cause significant losses of soil, although few studies have addressed the validation of model predictions at field scale during severe erosive episodes. In this study, we evaluate the predictive ability of the enhanced Soil Erosion and Redistribution Tool (SERT‐2014) model for mapping and quantifying soil erosion during the exceptional rainfall event (~235 mm) that affected the Central Spanish Pyrenees in October 2012. The capacity of the simulation model is evaluated in a fallow cereal field (1.9 ha) at a high spatial scale (1 × 1 m). Validation was performed with field‐quantified rates of soil loss in the rills and ephemeral gullies and also with a detailed map of soil redistribution. The SERT‐2014 model was run for the six rainfall sub‐events that made up the exceptional event, simulating the different hydrological responses of soils with maximum runoff depths ranging between 40 and 1017 mm. Predicted average and maximum soil erosion was 11 and 117 Mg ha^?1 event^?1, respectively. Total soil loss and sediment yield to the La Reina gully amounted to 16.3 and 9.0 Mg event^?1. These rates are in agreement with field estimations of soil loss of 20.0 Mg event^?1. Most soil loss (86%) occurred during the first sub‐event. Although soil accumulation was overestimated in the first sub‐event because of the large amount of detached soil, the enhanced SERT‐2014 model successfully predicted the different spatial patterns and values of soil redistribution for each sub‐event. Further research should focus on stream transport capacity. Copyright © 2014 John Wiley & Sons, Ltd.     

Phase equilibria modelling and LASS monazite petrochronology: P–T–t constraints on the evolution of the Priest River core complex,northern Idaho

Phase equilibria modelling, laser‐ablation split‐stream (LASS)‐ICP‐MS petrochronology and garnet trace‐element geochemistry are integrated to constrain the P–T–t history of the footwall of the Priest River metamorphic core complex, northern Idaho. Metapelitic, migmatitic gneisses of the Hauser Lake Gneiss contain the peak assemblage garnet + sillimanite + biotite ± muscovite + plagioclase + K‐feldspar ± rutile ± ilmenite + quartz. Interpreted P–T paths predict maximum pressures and peak metamorphic temperatures of ~9.6–10.3 kbar and ~785–790 °C. Monazite and xenotime ²⁰⁸Pb/²³²Th dates from porphyroblast inclusions indicate that metamorphism occurred at c. 74–54 Ma. Dates from HREE‐depleted monazite formed during prograde growth constrain peak metamorphism at c. 64 Ma near the centre of the complex, while dates from HREE‐enriched monazite constrain the timing of garnet breakdown during near‐isothermal decompression at c. 60–57 Ma. Near‐isothermal decompression to ~5.0–4.4 kbar was followed by cooling and further decompression. The youngest, HREE‐enriched monazite records leucosome crystallization at mid‐crustal levels c. 54–44 Ma. The northernmost sample records regional metamorphism during the emplacement of the Selkirk igneous complex (c. 94–81 Ma), Cretaceous–Tertiary metamorphism and limited Eocene exhumation. Similarities between the Priest River complex and other complexes of the northern North American Cordillera suggest shared regional metamorphic and exhumation histories; however, in contrast to complexes to the north, the Priest River contains less partial melt and no evidence for diapiric exhumation. Improved constraints on metamorphism, deformation, anatexis and exhumation provide greater insight into the initiation and evolution of metamorphic core complexes in the northern Cordillera, and in similar tectonic settings elsewhere.     

Atmospheric and Surface Water Pollution Interpretation in the Gdańsk Beltway Impact Range by the Use of Multivariate Analysis

The present study deals with the application of the hierarchical cluster analysis and non‐parametric tests in order to interpret the Gdańsk Beltway impact range. The data set represents concentration values for major inorganic ions (Na⁺, NH, K⁺, Mg²⁺, Ca²⁺, F⁻, Cl⁻, NO, and SO) as well as electrolytic conductivity and pH measured in various water samples [precipitation, throughfall water, road runoff, and surface water (drainage ditches, surface water reservoirs, and spring water)] collected in the vicinity of the beltway. Several similarity groups were discovered both in the objects and in the variables modes according to the water sample. In the majority of cases clear anthropogenic (fertilizers usage and transport, road salting in winter) and semi‐natural (sea salt aerosols, erosion of construction materials) impacts were discovered. Spatial variation was discovered for road runoff samples and samples collected from surface water reservoirs and springs. Surprisingly no clear seasonal variability was discovered for precipitation chemistry, while some evidences for existing of summer and winter specific chemical profile was discovered for road runoff samples. In general, limited range of the Gdańsk Beltway impact was proven.     

Methane‐related microbial gypsum calcitization in stromatolites of a marine evaporative setting (Münder Formation,Upper Jurassic,Hils Syncline,north Germany)

Fossil stromatolites may reveal information about their hydrochemical palaeoenvironment, provided that assignment to a specific microbial community and a corresponding biogeochemical mechanism of formation can be made. Tithonian stromatolites of the Münder Formation at Thüste, north Germany, have traditionally been considered as formed by intertidal cyanobacterial communities. However, thin sections of the stromatolites show elongated angular traces of former gypsum crystals in a dense arrangement, but no algal or cyanobacterial filament traces. Moreover, high Fe²⁺ and Mn²⁺ contents, oxygen‐isotope and sulphur‐isotope ratios of carbonate‐bound sulphates, and sulphurized hydrocarbon biomarkers of the stromatolitic carbonate indicate that CaCO₃ precipitation occurred near the oxic–anoxic interface as a result of intensive bacterial sulphur cycling rather than photosynthetic activity. Furthermore, anaerobic oxidation of methane by Archaea may have driven CaCO₃ precipitation in deeper parts of the biofilm community, as reflected by high concentrations of squalane with a strongly negative δ¹³C in conjunction with evaporite pseudomorphs showing extremely low δ¹³C_Carb ratios. Consequently, the Thüste stromatolites are now interpreted as having initially formed by gypsum impregnation of biofilms. Subsequently, early Mg‐calcitic calcitization within the biofilms occurred because of combined bacterial iron, manganese and sulphate reduction, with an increasing contribution of anaerobic oxidation of methane with depth. This model plausibly explains the prominent preservation of signals derived from oxygen‐independent metabolic pathways, whereas virtually no geochemical record exists for an aerobic community that may, nevertheless, have prevailed at the stromatolite surface. Photic‐zone stromatolites with a prominent signal of anaerobic oxidation of methane may be common in, and indicative of, oxygen‐depleted sulphate‐bearing environments with high rates of methane production, conditions that possibly were fulfilled at the Archaean to Proterozoic transition.     

Flood‐based analysis of high‐magnitude sediment transport using a non‐parametric method

Upland erosion and the resulting reservoir siltation is a serious issue in the Isábena catchment (445 km² Central Spanish Pyrenees). During a three‐month period, water and sediment fluxes have been monitored at the catchment outlet (Capella), two adjacent subcatchments (Villacarli, 41 km²; Cabecera, 145 km²) and the elementary badland catchment Torrelaribera (8 ha). This paper presents the results of the monitoring, a method for the calculation of a sedigraph from intermittent measurements and the derived sediment yields at the monitored locations. The observed suspended sediment concentrations (SSCs) demonstrate the role of badlands as sediment sources: SSCs of up to 280 g l^?1 were encountered for Villacarli, which includes large badland areas. SSCs at the Cabecera catchment, with great areas of woodland, barely exceeded 30 g l^?1. SSCs directly at the sediment source (Torrelaribera) were comparable to those at Villacarli, suggesting a close connection within this subcatchment. At Capella, SSCs of up to 99 g l^?1 were observed. For all sites, SSC displayed only a loose correlation with discharge, inhibiting the application of a simple sediment rating curve. Instead, ancillary variables acting as driving forces or proxies for the processes (rainfall energy, cumulative discharge, rising/falling limb data) were included in a quantile regression forest model to explain the variability in SSC. The variables with most predictive power vary between the sites, suggesting the predominance of different processes. The subsequent flood‐based calculation of sediment yields attests high specific sediment yields for Torrelaribera and Villacarli (6277 and 1971 t km^?2) and medium to high yields for Cabecera and Capella (139 and 410 t km^?2) during the observation period. In all catchments, most of the sediment was exported during intense storms of late summer. Later flood events yield successively less sediment. Relating upland sediment production to yield at the outlet suggests considerable effects of sediment storage within the river channel. Copyright © 2008 John Wiley & Sons, Ltd.     

Location,location, location: changes in the diversity of animal resources exploited by Tardiglacial humans in northern Spain

Prey diversity of Homo sapiens in north Iberia exhibited shifts associated with climate warming after the Last Glacial Maximum, as deduced from animal remains obtained from Upper Palaeolithic caves in Asturias (northern Spain). Significant association of prey diversity and river proximity was found during adverse climate conditions, indicating opportunistic predation. A high increase of prey diversity was found when small animals (including fish) were taken into account in archaeological records, highlighting the importance of this type of prey in Palaeolithic diets. Copyright © 2009 John Wiley & Sons, Ltd.     

Evidence for high‐temperature fractionation of lithium isotopes during differentiation of the Moon

Lithium isotope and abundance data are reported for Apollo 15 and 17 mare basalts and the LaPaz low‐Ti mare basalt meteorites, along with lithium isotope data for carbonaceous, ordinary, and enstatite chondrites, and chondrules from the Allende CV3 meteorite. Apollo 15 low‐Ti mare basalts have lower Li contents and lower δ⁷Li (3.8 ± 1.2‰; all uncertainties are 2 standard deviations) than Apollo 17 high‐Ti mare basalts (δ⁷Li = 5.2 ± 1.2‰), with evolved LaPaz mare basalts having high Li contents, but similar low δ⁷Li (3.7 ± 0.5‰) to Apollo 15 mare basalts. In low‐Ti mare basalt 15555, the highest concentrations of Li occur in late‐stage tridymite (>20 ppm) and plagioclase (11 ± 3 ppm), with olivine (6.1 ± 3.8 ppm), pyroxene (4.2 ± 1.6 ppm), and ilmenite (0.8 ± 0.7 ppm) having lower Li concentrations. Values of δ⁷Li in low‐ and high‐Ti mare basalt sources broadly correlate negatively with ¹⁸O/¹⁶O and positively with ⁵⁶Fe/⁵⁴Fe (low‐Ti: δ⁷Li ≤4‰; δ⁵⁶Fe ≤0.04‰; δ¹⁸O ≥5.7‰; high‐Ti: δ⁷Li >6‰; δ⁵⁶Fe >0.18‰; δ¹⁸O <5.4‰). Lithium does not appear to have acted as a volatile element during planetary formation, with subequal Li contents in mare basalts compared with terrestrial, martian, or vestan basaltic rocks. Observed Li isotopic fractionations in mare basalts can potentially be explained through large‐degree, high‐temperature igneous differentiation of their source regions. Progressive magma ocean crystallization led to enrichment in Li and δ⁷Li in late‐stage liquids, probably as a consequence of preferential retention of ⁷Li and Li in the melt relative to crystallizing solids. Lithium isotopic fractionation has not been observed during extensive differentiation in terrestrial magmatic systems and may only be recognizable during extensive planetary magmatic differentiation under volatile‐poor conditions, as expected for the lunar magma ocean. Our new analyses of chondrites show that they have δ⁷Li ranging between ?2.5‰ and 4‰. The higher δ⁷Li in planetary basalts than in the compilation of chondrites (2.1 ± 1.3‰) demonstrates that differentiated planetary basalts are, on average, isotopically heavier than most chondrites.