模拟CO_2埋藏的煤储层元素迁移实验研究

采用高压超临界CO2地球化学反应器对CO2在煤储层中的地质埋藏进行模拟,利用电感耦合等离子体发射光谱仪(ICP-OES)以及电感耦合等离子体质谱(ICP-MS)分别对淋滤液和煤样中的10种微量元素进行测试,对煤中微量元素在CO2的地质埋藏过程中的迁移进行了实验研究。结果表明:在CO2的地质埋藏过程中对煤的有机组成和无机矿物等均具有改造作用,从而影响到煤中微量元素的赋存和迁移特征,Cr、Zn、Cu等元素迁移能力相对较强,而Co、Ba、V等元素相对较弱;元素迁移能力大小顺序为:CrZnCuNiCdMnCoBaV。     

澳大利亚与元三古代海底喷气矿床伴生的电气石岩

在绿片岩、角闪岩和麻粒岩和变质岩层中，电气石岩和富电气石的沉积物与喷气矿化伴生，它们遭受了中等到强烈的变形，呈连续层状分布于褶皱构造附近，显示出诸如层理、递变层理、交错层理、层内滑动等沉积构造和拉裂构造。在高级变质作用区，它们显示变质结构，通常被再活化而成的石英－电气石脉所穿切。富电气石岩出现在由海底喷气而形成的Pb－Zn－Ag、Cu－Co、Cu－Bi、W、Sn、Au和稀土元素矿化的下部、内部及矿化之上，且在横向上与矿化同期的地层中。在一些地方，电气石岩没有上述矿化现象，也不与花岗质岩石相伴生。电气石的成分是黑电气石－镁电气石，虽反映了其全岩成分，但不能作为矿化的标志。虽然电气石是与花岗岩、交代岩、角砾岩简伴生的普通矿物，但本文描述的富电气石层为山硅电气石前身的变质作用产生的富硼硅质铁建造。它们是一种常见的喷气岩类型，并且常常出现在早－中元古代厚层的泥质变沉积岩和蒸发岩层序中。这就说明硼是由含硼的粘土的淋滤作用或由含硼酸盐的蒸发岩的淋滤作用产生的。     

Measurement of DNA single-strand breaks in gill and hemolymph cells of mussels, Mytilus sp., collected on the French Atlantic Coast

DNA single-strand breaks were measured by the comet assay in both gill and hemolymph cells of mussels collected in 3 sampling areas of the French coast (Pointe du Castelli, Pen Bron and Saint-Nazaire Harbour). Whole mussel tissue samples were also collected for the chemical determination of PAH, PCB and heavy metal concentrations. In mussel, a higher level of DNA strand breaks was measured in gill than in hemolymph cells (p < 0.01). Despite a factor of contamination from 2 to 3 between sites, no difference in the extent of mussel DNA strand breaks was shown between sampling locations (p > 0.05), questioning the sensitivity of the assays used in biomonitoring studies.     

Variations of antioxidant efficiency and presence of endosymbiotic diatoms in the Antarctic porifera Haliclona dancoi

The role of endosymbiotic diatoms as pro-oxidant stressors in porifera has been investigated in the Antarctic sponge Haliclona dancoi in which the presence of diatoms is influenced by marked seasonal variations during the austral summer. Both chlorophaeopigments and frustules were absent in sponge tissues sampled in early November at the beginning of the summer and increased from the mid of December with slightly shifted temporal trends. The efficiency of antioxidant defenses in the sponge showed a marked response to symbionts with clearly enhanced values corresponding to the peak of diatoms.     

气候的过渡:冰期-间冰期和近代气候变化的制约与反馈机制

就地球气候而言,无论是人口增长和工业化进程的加快导致气候变化,还是对引起气候重大变化的那些潜在因素的了解都至关重要。遗憾的是,全球范围气候直接测定的温度记录时间太短,而这些记录出现在人类严重影响自然条件的时期内。至于前人类时期的系统信息可以从记录过去气候和环境条件的替代指标中获取,也可以由合适外力作用的数字模型来模拟气候系统,古气候记录对于揭示过去气候变化的这些模型提供了一个极好的检验机会,计算机模拟和概念模式有助于对气候系统动力分析的理解。     

Differential sensitivity of flounder (Platichthys flesus) in response to oestrogenic chemical exposure: an issue for design and interpretation of monitoring and research programmes

This study was conducted as an initial investigation of 'differential response' in one of the main sentinel organisms used for monitoring programmes in United Kingdom estuaries, the flounder Platichthys flesus. It has been hypothesised that monitoring using species with a wide geographical spread and limited migration, such as flounder, might result in the comparison of different genetic stocks and certainly of populations with differing early life stage contaminant exposure histories. Furthermore, it is probable that these pre-exposure and genetic differences could manifest themselves in an ability to respond differently to contaminant exposure, so-called 'differential response'. It is important that the extent and nature of this response is understood, if we want to be able to fully interpret the monitoring data from such programmes. During this study, flounder were collected from four separate sources; wild caught fish from the estuaries of the Rivers Alde, Mersey and Tyne, and farmed flounder from Port Erin Farm, Isle of Man. Under controlled laboratory conditions, groups of fish from each source were exposed to water-borne concentrations of the synthetic oestrogen ethynylestradiol (EE2) at a nominal concentration of 50 ng/l. Plasma was taken from each male fish after 6 and 10 days exposure and analysed for the presence of vitellogenin (VTG) using an ELISA technique. Significant levels of VTG induction were evident in fish from all sources after both 6 and 10 days exposure. Flounder from the Mersey were the only fish with significantly elevated initial background levels of VTG (day 0) and this appeared to be reflected in that these specimens showed the highest induction response after day 6. However, after day 10, fish from all other sites had a slightly higher mean VTG than those from the Mersey which showed significantly (p < 0.05) lower mean plasma VTG. It is suggested that other differential responses may have been masked by the use of a high dose of EE2 which produced maximum induction in nearly all fish. The findings of the study are discussed in terms of implications for further research into the differential response issue and how the initial plasma VTG figures contribute to a time-series from the Mersey, Tyne and Alde estuaries.     

西印度构造演化及其对烃类显示意义综述

印度最大的油气聚集区位于西印度,具有独特的构造事件集中发生。中生代沿元古代活动带构造方向的裂谷作用形成了印度海岸的被动边缘盆地。Campanian期（83．5—70．6Ma）,马达加斯加与印度发生分离,南北向正断层传播进入到Cambay Graben地区。在初始德干Reunion热点之上,晚Maastrichtian（70．6—65．5Ma）隆起在西北印度海岸产生了伸展应力场,形成盂买高断块。早古新世,德干溢流玄武岩喷发后,伸展在薄弱的地壳中继续,引起了孟买地堑和Surat坳陷沉降的加强、Seychelles微大陆从印度分离以及孟买高地上正断层的重新活动。孟买地堑和Surat（Danahu）坳陷在热沉降期间充填了富有机质页岩,在缓慢沉降的盂买台地上发育了始新-中新世浅水碳酸盐,海平面波动产生了次生孔隙的发育。晚第三纪成熟的Surat（Danahu）坳陷页岩生成烃类,运移至孟买高的碳酸盐储层。Canlpanian构造事件之后,Konkan—kerala和印度东海岸的较老盆地并未受到影响,缺乏有利的成藏要素是该地区的特点。     

The amphipod Talitrus saltator as a bioindicator of human trampling on sandy beaches

The present paper assesses the use of the supralittoral amphipod Talitrus saltator as a bioindicator of the effects of human trampling on the supralittoral sandy band. Samplings in delimited areas were carried out at sites subjected to different human impact. The results showed a strong negative correlation between the number of swimmers and the sandhopper population density, while there was no clear relationship between sandhopper abundance and the other factors considered: granulometry, compactness and organic carbon content of the sand, and trace metal contents in the sand and sandhoppers. A field test of trampling conducted in a confined space showed its direct negative effect on sandhopper survival. However, trace metal analysis confirmed the ability of T. saltator to bioaccumulate some elements (Hg, Zn, Cu, Cd). Our study demonstrates that T. saltator is a good bioindicator of human impact in the supralittoral zone of sandy shores.     

The role of water mass dynamics in controlling bacterial abundance and production in the middle Adriatic Sea

Month-to-month fluctuations in the abundance of bacteria and heterotrophic nanoflagellates (HNF) and bacterial production, as well as various chemical (nutrients, oxygen) and physical (salinity, temperature) parameters were analysed at a station located in the open middle Adriatic Sea during one decade (1997-2006). Being influenced by both coastal waters and open Adriatic circulation in the surface layer, and by the deep Adriatic water masses in the deep layers (100 m), this station is quite suitable for detecting the environmental changes occurring in the open Adriatic Sea with respect to the circulation of its water masses and their long-term changes and anomalies. Multivariate methods were used to identify seasonal and inter-annual changes of the investigated parameters, associating observed changes to the changes in Adriatic water masses and circulation regimes. The analyses showed that bacterial abundance and production were controlled by different water mass dynamics during 1997-2001 compared to 2002-2006 period, particularly noticeable in different seasonal patterns of biological parameters. The interplay between North Adriatic Dense Water (NAdDW) and Levantine Intermediate Water (LIW) resulted in a change in the available nutrients (NAdDW is poor in orthophosphates), and as a consequence different bacterial abundance and production. A few periods were examined in detail, such as 2004, when LIW inflow was particularly strong and was accompanied by an increase of bacterial and HNF abundances, as well as of bacterial production.