Manganoan garnet rocks associated with the Broken Hill Pb–Zn–Ag orebody, Australia

Summary The Palaeoproterozoic Broken Hill Pb–Zn–Ag stratiform orebody is intimately associated with manganoan garnet-bearing rocks. On stratigraphic and chemical grounds it is argued that garnet-rich metasediments below, equivalent to and above massive sulphide were hydrothermal precipitates. Other manganoan garnet rocks formed during pre-metamorphic hydrothermal alteration, syn-metamorphic dehydration and reaction of manganese with prograde pelitic rocks, reaction between cataclastic manganese-bearing sulphide rocks injected along axial planes, shears and faults and pelitic wall rocks and reaction between dolerite dykes and sulphide rocks.     

Rare earth elements in the clay fraction of coaliferous sediments of the Arkagalinskoe (Magadan district) and Dolinskoe (Sakhalin Island) coalfields

The study of REE distribution in the clay fraction of sedimentary rocks from two coalfields made it possible to distinguish several types of REE distribution, which correlate with their mineral composition. It is shown that the REE fractionation was related to the mineral reconstruction of the primary clay fraction and some detrital minerals in the course of postsedimentary transformations of rocks during diagenesis, early catagenesis, and beginning of late catagenesis. These transformations were governed by several factors, such as the composition of sediments; hydrochemical features of accumulation environment; the chemical composition, dynamics, and feeding sources of pore solutions; the porosity and permeability of sediments and rocks; and the content of organic matter and its reaction ability.     

Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.     

Improved Petrological Modal Analyses from X-ray Powder Diffraction Data by use of the Rietveld Method I. Selected Igneous, Volcanic, and Metamorphic Rocks

Mineral modes have been determined for specimens of eight rocktypes from CuK X-ray powder diffraction data using the Rietveldmethod. The samples include two granites, a granodiorite, adamellite,gabbro, basalt, trachyte, and two granulite-facies metamorphicrocks. Up to eight individual mineral components have been measuredin each sample (no glassy phases were observed), with a detectionlimit of {small tilde}1 wt.%, depending on the mineral assemblage.Marked variations in grain size (i.e., granite vs. trachyte)provide no difficulties for the X-ray method. The X-ray resultscompare very favourably with (1) optical modes determined forthe medium–coarse-grained samples by point counting, (2)normative calculations obtained using locally enhanced catanormand mesonorm software, and (3) corresponding Rietveld modesdetermined, for two samples, from neutron powder data. Wheredifferences occur, these are discussed in relation to the limitationsof each of the methods. The improved accuracy of the X-ray method is due primarily tothe incorporation of the full diffraction profile in the Rietveldanalysis calculations, and the elimination of preferred orientationby collecting the data from samples packed in glass capillaries(i.e., Debye–Scherrer mode). The good agreement of theX-ray and neutron modes shows that the usual problems encounteredwith microabsorption, extinction, and sampling are of littleconcern in these rocks. The results highlight one of the majoradvantages provided by Rietveld modal analysis over the moretraditional ‘reference intensity’ X-ray methods,namely, that the crystal chemistry (and thus the calibrationconstants) of the individual phases can be adjusted dynamicallyduring each individual analysis. This not only provides moreaccurate phase abundances, but also gives important supplementaryinformation about the mineralogy of the major components.     

Platinum-group elements in alpine-type ultramafic rocks and related chromite ores of the main ophiolite belt of the Urals

On the basis of a representative collection of ultramafic rocks and chromite ores and a series of technological samples from the largest (Central and Western) deposits in the Rai-Iz massif of the Polar Urals and the Almaz-Zhemchuzhina and Poiskovy deposits in the Kempirsai massif of the southern Urals, the distribution and speciation of platinum-group elements (PGE) in various type sections of mafic-ultramafic massifs of the Main ophiolite belt of the Urals have been studied. Spectral-chemical and spectrophotometric analyses were carried out to estimate PGE in 700 samples of ultramafic rocks and chromite ores; 400 analyses of minerals from rocks, ores, and concentrates and 100 analyses of PGE minerals (PGM) in chromite ores and concentrates were performed using an electron microprobe. Near-chondritic and nonchondritic PGE patterns in chromitebearing sections have been identified. PGE mineralization has been established to occur in chromite ore from all parts of the mafic-ultramafic massifs in the Main ophiolite belt of the Urals. The PGE deposits and occurrences discovered therein are attributed to four types (Kraka, Kempirsai, Nurali-Upper Neiva, and Shandasha), which are different in mode of geological occurrence, geochemical specialization, and placer-forming capability. Fluid-bearing minerals of the pargasite-edenite series have been identified for the first time in the matrix of chromite ore of the Kempirsai massif (the Almaz-Zhemchuzhina deposit) and Voikar-Syn’ya massif (the Kershor deposit). The PGE grade in various types of chromite ore ranges from 0.1–0.2 to 1–2 g/t or higher. According to technological sampling, the average PGE grade in the largest deposits of the southeastern ore field of the Kempirsai massif is 0.5–0.7 g/t. Due to the occurrence of most PGE as PGM 10–100 mm in size and the proved feasibility of their recovery into nickel alloys, chromites of the Kempirsai massif can be considered a complex ore with elevated and locally high Os, Ir, and Ru contents. The Nurali-Upper Neiva type of ore is characterized by small-sized primary deposits, which nevertheless are the main source of large Os-Ir placers in the Miass and Nev’yansk districts of the southern and central Urals, respectively.     

Biosorption of Rare-Earth Elements and Yttrium by Heterotrophic Bacteria in an Aqueous Environment

This paper reports the results of the experimental determination of the coefficient of sorption of rare-earth elements and yttrium (REY) under conditions of acidic pH using several strains of heterotrophic bacteria (Microbacterium sp., Curtobacterium sp., Bacillus subtilis, Pseudomonas putida, and Bacillus pumilis) that are widespread in natural and technogenic waters of the Far East (Russia). Insignificant fractionation between heavy and light rare-earth elements, negative cerium and dysprosium anomalies, and a positive europium anomaly were revealed. The selectivity of REY biosorption by gram-positive and gram-negative bacteria, as well as inertia of the biosorption process under more acidic conditions of the medium, were shown.     

Carbon-Oxidizing and Sulfate-Reducing Bacteria in Mozhaisk Reservoir Soils

The population and distribution of carbon-oxidizing and sulfate-reducing bacteria in the soils of the Mozhaisk Reservoir are studied.     

Sources of dissolved REE in mountainous streams draining granitic rocks, Sierras Pampeanas (Córdoba, Argentina)

Stream waters draining granitic terrains from the highest part (850 to 2200 m a.s.l.) of Sierras Pampeanas (Córdoba, Argentina, ∼32°S, ∼65°W) were sampled in order to define sources and distribution of dissolved rare earth elements (REE), and to describe the geochemical processes that govern their mobility. The contribution of the regional granite to the dissolved REE pool in stream water is limited due to the physical conditions predominating in the area (i.e., steep slopes and semiarid climate). Therefore, precipitation is considered a seasonally significant source controlling REE concentration in stream water. Dissolved REE concentrations are inversely correlated with monthly precipitation and rainfall frequency. During the rainy season (i.e., the austral summer) REE concentrations in stream water are lower than during the dry season (i.e., austral winter). Such low concentrations reflect the balance between the REE input from precipitation and their removal by adsorption. In contrast, during the dry season, the longer residence time of water within fractures and colluvium determines an increased REE concentration in the base flow. Lower pH values also contribute to raise REE concentration through desorption from mineral surfaces.     

The neotectonics and geodynamics of the Lower Oka Region (East European Craton)

The neotectonic structures of the Lower Oka (Nizhneokskii) Region formed under different geodynamic conditions. This is attested by the morphology, orientation, internal structure, and jointing of the structures. The Oka-Tsna arc formed under the effect of tension from an inner source on the one hand and stress from the Alpian belt on the other hand. The latitudinally-oriented structures of the northwestern slope of the Tokmovo arc emerged as a result of uplift and widening. Both types of structure are combined within the limits of the Oka-Murom trough, which is a geodynamically active zone.