Testing for Trends in Data Unevenly Distributed in Time

Summary  The question discussed in this study is how to calculate linear trends in data that are not distributed evenly in time. This is examined with time series of ten climate elements at a single station, stratified according to a classification based on daily circulation patterns. Trends are calculated in three different ways: (i) from seasonal means, which is a common approach, (ii) from means of individual events, the event being defined as a sequence of days classified as one particular type, preceded and succeeded by another type, and (iii) from individual daily values. The most common method of estimating trend significance, i.e. the t-test of the Pearson correlation coefficient, has been shown to be applicable to seasonal and event-mean trends for all variables. For daily trends, the Monte Carlo test should be used instead. The daily, event-mean and seasonal trends differ from each other considerably for many combinations of climate variable and circulation type. The reason for this difference is identified. Received December 3, 1998 Revised June 21, 1999     

Schorlomite: a discussion of the crystal chemistry, formula, and inter-species boundaries

Examination of schorlomite from ijolite at Magnet Cove (USA) and silicocarbonatite at Afrikanda (Russia), using electron-microprobe and hydrogen analyses, X-ray diffraction and Mössbauer spectroscopy, shows the complexity of substitution mechanisms operating in Ti-rich garnets. These substitutions involve incorporation of Na in the eightfold-coordinated X site, Fe²⁺ and Mg in the octahedrally coordinated Y site, and Fe³⁺, Al and Fe²⁺ in the tetrahedrally coordinated Z site. Substitutions Ti⁴⁺Fe³⁺Fe³⁺_–1Si_–1 and Ti⁴⁺Al³⁺Fe³⁺_–1Si_–1 are of major significance to the crystal chemistry of schorlomite, whereas Fe²⁺ enters the Z site in relatively minor quantities (<3% Fe). There is no evidence (either structural or indirect, such as discrepancies between the measured and calculated Fe²⁺ contents) for the presence of ^[6]Ti³⁺ or ^[4]Ti⁴⁺ in schorlomite. The simplified general formula of schorlomite can be written as Ca₃Ti⁴⁺₂[Si_3-x(Fe³⁺,Al,Fe²⁺)_xO₁₂], keeping in mind that the notion of end-member composition is inapplicable to this mineral. In the published analyses of schorlomite with low to moderate Zr contents, x ranges from 0.6 to 1.0, i.e. Ti⁴⁺ in the Y site is <2 and accompanied by appreciable amounts of lower-charged cations (in particular, Fe³⁺, Fe²⁺ and Mg). For classification purposes, the mole percentage of schorlomite can be determined as the amount of ^[6]Ti⁴⁺, balanced by substitutions in the Z site, relative to the total occupancy in the Y site: (^[6]Ti⁴⁺–^[6]Fe²⁺–^[6]Mg²⁺– ^[8]Na⁺)/2. In addition to the predominant schorlomite component, the crystals examined in this work contain significant (>15 mol.%) proportions of andradite (Ca₃Fe³⁺₂Si₃O₁₂), morimotoite (Ca₃Fe²⁺TiSi₃O₁₂), and Ca₃MgTiSi₃O₁₂. The importance of accurate quantitative determination and assignment of Fe, Ti and other cations to the crystallographic sites for petrogenetic studies is discussed.

Brachiopods from China seas

A collection of brachiopods by the Institute of Oceanology, Academia Sinica (Qingdao), contains eight species from seven genera. Six of the species have been recorded previously from China seas—Lingula adamsi, L. anatina, Discinisca stella, Pelagodiscus atlanticus, Campages mariae, Terebratalia coreanica. Two species (Terebratulina hataiana andFrenulina sanguinolenta) have been described from other parts of the Pacific area. The apparent absence of any endemic species is a noteworthy feature of Chinese in comparison with Japanese faunas.     

Observations of OH maser lines at an 18-cm wavelength in 9P/Temper1 and Lulin C/2007 N3 comets with RT-22 at the Crimean Astrophysical Observatory

Investigations on OH maser lines in comets have been performed with the RT-22 at CrAO. The results of observations of 9P/Temper1 and Lulin C/2007 N3 comets in the OH molecule line at a wavelength of 18 cm are presented. An original technique for observation data analysis has been developed. The gas production rate of OH molecules in these comets is estimated.     

Dunes on Titan observed by Cassini Radar

Thousands of longitudinal dunes have recently been discovered by the Titan Radar Mapper on the surface of Titan. These are found mainly within ±30° of the equator in optically-, near-infrared-, and radar-dark regions, indicating a strong proportion of organics, and cover well over 5% of Titan's surface. Their longitudinal duneform, interactions with topography, and correlation with other aeolian forms indicate a single, dominant wind direction aligned with the dune axis plus lesser, off-axis or seasonally alternating winds. Global compilations of dune orientations reveal the mean wind direction is dominantly eastwards, with regional and local variations where winds are diverted around topographically high features, such as mountain blocks or broad landforms. Global winds may carry sediments from high latitude regions to equatorial regions, where relatively drier conditions prevail, and the particles are reworked into dunes, perhaps on timescales of thousands to tens of thousands of years. On Titan, adequate sediment supply, sufficient wind, and the absence of sediment carriage and trapping by fluids are the dominant factors in the presence of dunes.     

Petrophysical properties of rocks in seismogenic crustal blocks of the southeastern Greater Caucasus and their geological and geophysical interpretation

The elastic and density properties of rocks of the Shamakha-Ismailly seismogenic blocks are studied by the ultrasonic pulse method in quasi-hydrostatic high pressure apparatuses. An attempt is made to more accurately determine the upper crustal lithology of these blocks. The observed values of the elastic and density characteristics of the rocks at high pressures suggest that the upper layers in the Ismailly and Shamakha blocks can consist of sedimentary carbonate rocks such as marls, sandstones, mudstones, and limestones. The middle layers apparently consist of volcaniclastic rocks: lithoclastic tuffs, andesites, etc. The lower layer (basement) in both blocks is likely composed of basic rocks such as basalts, trachybasalts, etc. According to the values of elastic wave velocities and densities, gabbroid rocks may compose the fourth layer of the Buinuz intrusion, identified from seismic data.     

Oceanic versus island arc origin of ophiolites

The silica content of basaltic rocks is an unreliable variable with which to distinguish ultramafic-mafic complexes developed at ocean ridges from those potentially formed beneath volcanic island arcs. Data from Appalachian ophiolites supports the view that silica metasomatism is responsible for the high silica content of supposed calc-alkaline basaltic rocks found in ophiolites such as Troodos, and that the high-silica (70 wt.%) leucocratic rocks associated with ophiolites are of tholeiitic rather than calc-alkaline parentage. The use of titanium as a discriminant of tectonic environment is also suspect because the titanium content of basalts associated with Appalachian ophiolites as well as those recently recovered from the Atlantic ocean floor ranges from values even lower than those typical of island arc tholeiites to values typical of abyssal tholeiites. However, the internal stratigraphy of ophiolites in both the Appalachian and Tethyan systems can only be explained on the basis of the postulate that ophiolites originate at oceanic spreading centres rather than beneath island arcs.