Improved Petrological Modal Analyses from X-ray Powder Diffraction Data by use of the Rietveld Method I. Selected Igneous, Volcanic, and Metamorphic Rocks

Mineral modes have been determined for specimens of eight rocktypes from CuK X-ray powder diffraction data using the Rietveldmethod. The samples include two granites, a granodiorite, adamellite,gabbro, basalt, trachyte, and two granulite-facies metamorphicrocks. Up to eight individual mineral components have been measuredin each sample (no glassy phases were observed), with a detectionlimit of {small tilde}1 wt.%, depending on the mineral assemblage.Marked variations in grain size (i.e., granite vs. trachyte)provide no difficulties for the X-ray method. The X-ray resultscompare very favourably with (1) optical modes determined forthe medium–coarse-grained samples by point counting, (2)normative calculations obtained using locally enhanced catanormand mesonorm software, and (3) corresponding Rietveld modesdetermined, for two samples, from neutron powder data. Wheredifferences occur, these are discussed in relation to the limitationsof each of the methods. The improved accuracy of the X-ray method is due primarily tothe incorporation of the full diffraction profile in the Rietveldanalysis calculations, and the elimination of preferred orientationby collecting the data from samples packed in glass capillaries(i.e., Debye–Scherrer mode). The good agreement of theX-ray and neutron modes shows that the usual problems encounteredwith microabsorption, extinction, and sampling are of littleconcern in these rocks. The results highlight one of the majoradvantages provided by Rietveld modal analysis over the moretraditional ‘reference intensity’ X-ray methods,namely, that the crystal chemistry (and thus the calibrationconstants) of the individual phases can be adjusted dynamicallyduring each individual analysis. This not only provides moreaccurate phase abundances, but also gives important supplementaryinformation about the mineralogy of the major components.     

Biosorption of Rare-Earth Elements and Yttrium by Heterotrophic Bacteria in an Aqueous Environment

This paper reports the results of the experimental determination of the coefficient of sorption of rare-earth elements and yttrium (REY) under conditions of acidic pH using several strains of heterotrophic bacteria (Microbacterium sp., Curtobacterium sp., Bacillus subtilis, Pseudomonas putida, and Bacillus pumilis) that are widespread in natural and technogenic waters of the Far East (Russia). Insignificant fractionation between heavy and light rare-earth elements, negative cerium and dysprosium anomalies, and a positive europium anomaly were revealed. The selectivity of REY biosorption by gram-positive and gram-negative bacteria, as well as inertia of the biosorption process under more acidic conditions of the medium, were shown.     

Carbon-Oxidizing and Sulfate-Reducing Bacteria in Mozhaisk Reservoir Soils

The population and distribution of carbon-oxidizing and sulfate-reducing bacteria in the soils of the Mozhaisk Reservoir are studied.     

Sources of dissolved REE in mountainous streams draining granitic rocks, Sierras Pampeanas (Córdoba, Argentina)

Stream waters draining granitic terrains from the highest part (850 to 2200 m a.s.l.) of Sierras Pampeanas (Córdoba, Argentina, ∼32°S, ∼65°W) were sampled in order to define sources and distribution of dissolved rare earth elements (REE), and to describe the geochemical processes that govern their mobility. The contribution of the regional granite to the dissolved REE pool in stream water is limited due to the physical conditions predominating in the area (i.e., steep slopes and semiarid climate). Therefore, precipitation is considered a seasonally significant source controlling REE concentration in stream water. Dissolved REE concentrations are inversely correlated with monthly precipitation and rainfall frequency. During the rainy season (i.e., the austral summer) REE concentrations in stream water are lower than during the dry season (i.e., austral winter). Such low concentrations reflect the balance between the REE input from precipitation and their removal by adsorption. In contrast, during the dry season, the longer residence time of water within fractures and colluvium determines an increased REE concentration in the base flow. Lower pH values also contribute to raise REE concentration through desorption from mineral surfaces.     

The neotectonics and geodynamics of the Lower Oka Region (East European Craton)

The neotectonic structures of the Lower Oka (Nizhneokskii) Region formed under different geodynamic conditions. This is attested by the morphology, orientation, internal structure, and jointing of the structures. The Oka-Tsna arc formed under the effect of tension from an inner source on the one hand and stress from the Alpian belt on the other hand. The latitudinally-oriented structures of the northwestern slope of the Tokmovo arc emerged as a result of uplift and widening. Both types of structure are combined within the limits of the Oka-Murom trough, which is a geodynamically active zone.     

Formalization of assessing radioactive waste burial site seismic regime parameters from seismological and geological data

A model is proposed that shows the relation of the block structure of the crust and earthquake sources (Sadovskii, 1979; Rodionov, 1979, 1984, 1994; Bugaev, 1999, 2011, 2014, 2015). The model can formalize how to assess the prediction of seismic regime parameters depending on the elastic limit and conditions and rate of deformation of the Earth’s crust. The spent nuclear fuel repository site in Olkiluoto (Finland) and a site in the area of the Krasnoyarsk Mining and Chemical Combine are considered as examples. It is demonstrated that the parameters of the prediction graphs limit the location of the points of magnitude repeatability graphs calculated for a site based on samples of earthquakes in the area according to different authors. This makes it possible to recommend predictive assessment of seismic regime parameters for stability monitoring of the seismic regime and safety analysis of a geological environment’s insulation properties for waste sites from the results of seismological monitoring and high-precision observations of modern movements of the Earth’s crust.     

Soil bentonite wall protects foundation from thrust faulting: analyses and experiment

When seismic thrust faults emerge on the ground surface,they are particularly damaging to buildings,bridges and lifelines that lie on the rupture path.To protect a structure founded on a rigid raft,a thick diaphragm-type soil bentonite wall(SBW) is installed in front of and near the foundation,at sufficient depth to intercept the propagating fault rupture.Extensive numerical analyses,verified against reduced–scale(1 g) split box physical model tests,reveal that such a wall,thanks to its high deformability and low shear resistance,"absorbs" the compressive thrust of the fault and forces the rupture to deviate upwards along its length.As a consequence,the foundation is left essentially intact.The effectiveness of SBW is demonstrated to depend on the exact location of the emerging fault and the magnitude of the fault offset.When the latter is large,the unprotected foundation experiences intolerable rigid-body rotation even if the foundation structural distress is not substantial.     

Wiener optimal filtering of GRACE data

We present a spatial averaging method for Gravity Recovery and Climate Experiment (GRACE) gravity-field solutions based on the Wiener optimal filtering. The optimal filter is designed from the least-square minimization of the difference between the desired and filtered signals. It requires information about the power spectra of the desired gravitational signal and the contaminating noise, which is inferred from the average GRACE degree-power spectrum. We show that the signal decreases with increasing spherical harmonic degree j with approximately j^−b, where b = 1.5 for GRACE data investigations. This is termed the Second Kaula rule of thumb for temporal variations of the Earth’s gravity field. The degree power of the noise increases, in the logarithmic scale, linearly with increasing j. The Wiener optimal filter obtained for the signal model with b = 1.5 closely corresponds to a Gaussian filter with a spatial half width of 4° (∼440 km). We find that the filtered GRACE gravity signal is relatively insensitive to the exponent b of the signal model, which indicates the robustness of Wiener optimal filtering. This is demonstrated using the GFZ-GRACE gravity-field solution for April 2004.