Petrology,isotope characteristics,and K-Ar ages of the Maranhão,northern Brazil,Mesozoic basalt province

Northern Brazil contains remnants of Mesozoic flood basalts and hypabyssal rocks that were apparently emplaced during tectonism related to opening of the Atlantic Ocean. Analyses and new K-Ar ages reveal that this 700x250 km Maranhão province (5°–8°S) has low-Ti basalts (1.1 wt% TiO₂) in the western part that range about 160 to 190 Ma, and high-Ti basalts (3.4–4.4 wt% TiO₂) in the eastern part about 115–122 Ma. Low-Ti basalt compositions are less evolved and have a smaller range, Mg# 62-56, than the high-Ti basalts, Mg# 44–33. General characteristics of the least evolved members of low- and high-Ti groups include, respectively, Zr 100 and 250 ppm, Sr 225 and 475 ppm, Ba 200 and 500 ppm, Nb 10 and 26 ppm, Y 29 and 36 ppm, La/Yb_(n) 4.2 and 8.8, where La_(n) is 30 and 90. Overall compositions resemble the low- and high-Ti basaltic rocks of the Mesozoic Serra Geral (Paraná) province in southern Brazil. The Maranhão low-Ti basalts have more radiogenic Sr and Pb and higher ¹⁸O than the high-Ti basalts. Respectively, low- vs high-Ti: _Sr26–54 vs 15–18; ²⁰⁶Pb/²⁰⁴Pb=18.25–.78 vs 18.22–.24; and ¹⁸O 8.9–12.6 vs 6.5–8.6. Nd isotopes overlap: _Nd–1.6 to –3.8 vs –2.1 to –3. Ages, compositions, and isotopes indicate that the low- and high-Ti groups had independent parentages from enriched subcontinental mantle. However, both groups can be modeled from one source composition if low-Ti basalt isotopes reflect crustal contamination, and if the parentages for each group were picritic liquids that represent either higher (for low-Ti) or lower (for high-Ti) percentages of melting of that single source. When comparing Pb isotopes of Maranhão and Serra Geral high-Ti basalts (uncontaminated) to evaluate the DUPAL anomaly, Maranhão has Pb 7/4=4.6–11, and Pb 8/4=72–87; Serra Geral has Pb 7/4=10–13, and Pb 8/4=95–125. The small difference is not enough to conform to DUPAL contours, and is inconsistent with large-scale isotopic heterogeneity of mantle beneath Brazil prior to rifting of South America from Africa. Maranhão low-Ti magmas probably relate to the opening of central North Atlantic, and high-Ti magmas to the opening of equatorial Atlantic. The proposed greater percentage of source melting for low-Ti basalts may reflect a Triassic-Jurassic hotspot, while lesser melting for high-Ti magmas may relate to Cretaceous decompressional (rifting) melting.     

The effects of source size on concentration fluctuations in plumes

The effects of source size on plume behaviour have been examined in a 1.2 m wind tunnel boundary layer for isokinetic sources with diameters from 3 to 35 mm at source heights of 230 mm and at ground level. Experimental measurements of mean concentration and the variance, intermittency and probability density functions of the concentration fluctuations were obtained. In addition, a fluctuating Gaussian plume model is presented which reproduces many of the observed features of the elevated emission. The mean plume width becomes independent of source size much more rapidly than the instantaneous plume width. Since it is the meandering of the instantaneous plume which generates most of the concentration fluctuations near the source, these are also dependent on source size. The flux of variance in the plume reaches a maximum, whose value is greatest for the smallest source size, close to the source and thereafter is monotonically decreasing. The intermittency factor reaches a minimum, whose value is lowest for the smallest source, and increases back towards one. Concentration fluctuations for the ground-level source are much less dependent on source size due to the effects of the surface.     

Observations of polar patches generated by solar wind Alfvén wave coupling to the dayside magnetosphere

A long series of polar patches was observed by ionosondes and an all-sky imager during a disturbed period (K_p = 7- and IMF B_z <0). The ionosondes measured electron densities of up to 9 × 10¹¹ m⁻³ in the patch center, an increase above the density minimum between patches by a factor of ≈4.5. Bands of F-region irregularities generated at the equatorward edge of the patches were tracked by HF radars. The backscatter bands were swept northward and eastward across the polar cap in a fan-like formation as the afternoon convection cell expanded due to the IMF B_y > 0. Near the north magnetic pole, an all-sky imager observed the 630-nm emission patches of a distinctly band-like shape drifting northeastward to eastward. The 630-nm emission patches were associated with the density patches and backscatter bands. The patches originated in, or near, the cusp footprint where they were formed by convection bursts (flow channel events, FCEs) structuring the solar EUV-produced photoionization and the particle-produced auroral/cusp ionization by segmenting it into elongated patches. Just equatorward of the cusp footprint Pc5 field line resonances (FLRs) were observed by magnetometers, riometers and VHF/HF radars. The AC electric field associated with the FLRs resulted in a poleward-progressing zonal flow pattern and backscatter bands. The VHF radar Doppler spectra indicated the presence of steep electron density gradients which, through the gradient drift instability, can lead to the generation of the ionospheric irregularities found in patches. The FLRs and FCEs were associated with poleward-progressing DPY currents (Hall currents modulated by the IMF B_y) and riometer absorption enhancements. The temporal and spatial characteristics of the VHF backscatter and associated riometer absorptions closely resembled those of poleward moving auroral forms (PMAFs). In the solar wind, IMP 8 observed large amplitude Alfvén waves that were correlated with Pc5 pulsations observed by the ground magnetometers, riometers and radars. It is concluded that the FLRs and FCEs that produced patches were driven by solar wind Alfvén waves coupling to the dayside magnetosphere. During a period of southward IMF the dawn-dusk electric field associated with the Alfvén waves modulated the subsolar magnetic reconnection into pulses that resulted in convection flow bursts mapping to the ionospheric footprint of the cusp.     

Long-term comparison of macrobenthos within the soft bottoms of the Bay of Banyuls-sur-mer (northwestern Mediterranean Sea)

The macrofauna present at seven of the stations within the Bay of Banyuls-sur-mer (northwestern Mediterranean) initially sampled by Guille during the late 1960s was reassessed in 1994, using the same gear and techniques as those used during the reference study. Results showed an increase both in the number of species and of individuals (all species pooled) per unit of surface area at nearly all stations. This trend was not significant for total biomass. The most important changes were linked to the increase of the polychaete Ditrupa arietina (both within the Spisula subtruncata and the Nephtys hombergii community) and the decrease of the polychaetes Scoloplos armiger and Notomastus latericeus within the Scoloplos armiger community. The possible causes underlying these changes are discussed. The most probable cause is considered to be a slight modification of sediment composition (decrease of fine material in the sediment) within the Spisula subtruncata, the Nephtys hombergii and the Scoloplos armiger communities. Temporal changes in (1) Rhone river input, (2) small coastal river inputs, and (3) frequency of easterly storms may all have contributed to such a decrease.     

A note on wave action conservation in a dissipative current wave motion

We consider steady, slowly varying water waves propagating on a steady current over a gently sloping bed, so-called current depth refraction. All expressions are correct to second order in wave amplitude. Formulating the energy equation for the fluctuating motion in terms of wave action (wave energy divided by intrinsic angular frequency) results in an expression, where the dissipative term is strikingly similar to wave action itself. It is simply the ‘extra’ dissipation (per unit area) caused by the fluctuating motion (i.e. total dissipation minus the effect of current acting on total mean bed shear stress) divided by the intrinsic angular frequency. We call it ‘wave action dissipation’. An inconsistency in Phillips' (1977) book is pointed out. A new formula for the calculation of wave amplitudes along rays is set forth.     

THREE-WAY METHODS FOR THE CALIBRATION OF CHROMATOGRAPHIC SYSTEMS:COMPARING PARAFAC AND THREE-WAY PLS

For the calibration of chromatographic systems,different methods can be used.One class of methodsutilizes three-way approaches.The calibration problem is stated in such a way that the decompositionof a three-way array can serve for the prediction of retention on new stationary phases.Two three-way approaches are presented:the Unfold-PCA and PARAFAC models.The theory ofboth methods is presented and the differences are highlighted,the main difference being that PARAFACis a trilinear decomposition whereas Unfold-PCA is not.Both three-way methods are evaluated on asmall data set consisting of retention measurements of eight solutes at six mobile phase compositions onsix stationary phases.The differences in performance of the two models are minor,For calibration purposes,two variants of the methods are discussed:three-way PLS and an extensionof PARAFAC.Again the theory and differences between the two methods are explained.The predictiveperformance of the two methods is compared using the same data set as earlier.The differences inpredictive performance,however,are minor.Both methods are capable of predicting 98% of thevariation in the test sets.Yet,there are other considerations when comparing methods than predictiveperformance,e.g.the quality of the predictions.     

Heavy metals distribution in agricultural topsoils in urban area

Intensive urbanisation of the Croatian capital of Zagreb has led to a situation where very good agricultural soils, developed mostly on Pleistocene eolian sediments and alluvial and proluvian Holocene sediments are entrapped within urban and suburban areas. Therefore the influence of urban and industrialised environments on the accumulation of metals in agricultural topsoils has been investigated. On an area of 860 km² of the wider Zagreb region, 331 samples were taken according to a regular 1ǵ km square mesh. Samples were dissolved in aqua regia and analysed for Cd, Cu, Fe, Mn, Ni, Pb and Zn with flame atomic aqua regia absorption spectroscopy. The following concentration ranges have been determined: Cd 0.25-3.85 mg kg^-1 (average 0.66 mg kg^-1), Cu 4.30-183 mg kg^-1 (average 20.8 mg kg^-1), Fe 5.8-51.8 g kg^-1 (average 27 g kg^-1), Mn 79.2-1282 mg kg^-1 (average 613 mg kg^-1), Ni 0.70-282 mg kg^-1 (average 49.5 mg kg^-1), Pb 1.50-139 mg kg^-1 (average 25.9 mg kg^-1), and Zn 15.2-277 mg kg^-1 (average 77.9 mg kg^-1). Visualisation of the spatial data is made by the aid of GIS, and selected maps of the heavy metal concentrations in topsoils are displayed. Statistical multivariate analysis was carried out for quantitative study and data were processed by means of R-mode factor analysis, applying the varimax-raw rotational technique. F1, which grouped Cd, Pb, Cu, Zn and partially Ni, is characterized as a factor with strongly scattered anthropogenic influence. The elements in F2, Fe, Mn and partially Ni are mainly of geogenic, i.e. pedogenic, origin. The variations in concentrations of the investigated elements are thus of both natural and anthropogenic origins. The variations in the main soil constituents, particularly Fe and Mn, are determined primarily by the composition of different regolithic substrates of the fluvial origin in recent pedogenesis. High concentrations of nickel are also related to morphogenetic characteristics of the wider region, primarily basic and ultrabasic magmatic rocks of the surrounding mountain range. It is, however, assumed that the anomalous nickel concentrations in the vicinity of the highway and the airport are of anthropogenic origin, i.e. caused by fuel combustion. Copper is characterized by strongly scattered anthropogenic influence, which is related particularly to uncontrolled solid waste disposals or discharges of liquid waste from households or agricultural enterprises. With Zn, Pb and Cd, there are two possible ways of diffuse pollution. The Sava River, which drains the area and feeds the abundant Quaternary aquifer spreading below the major part of the investigated agricultural areas, has been exposed to intensive pollution by mining, industry and cities in the recent history. The part of the area with the highest determined concentrations of Zn, Pb and Cd was repeatedly flooded as recently as the previous decade; therefore, the recent sedimentation of the river deposits exposed to pollution is a very probable cause of the accumulation of metals in this until recently inundation area. The other way is atmospheric deposition of particles from urban sources (industrial emission, traffic, waste disposals, heating plants, etc.). In addition to agricultural enterprises, several economically important, but ecologically risky, facilities are situated in the vicinity of the water-protection area. The area is intersected by a very busy ring road, while a marshalling yard, the city dump, pharmaceutical and chemical industry, the district-heating plant and the airport are all located in close proximity. The geochemical maps show a clear relationship between human activities and metal concentration gradients.     

湘江中下游农田土壤和蔬菜的重金属污染

A total of 219 agricultural soil and 48 vegetable samples were collected from the midstream and downstream of the Xiangjiang River（the Hengyang-Changsha section）in Hunan Province.The accumulation characteristics,spatial distribution and potential risk of heavy metals in the agricultural soils and vegetables were depicted.There are higher accumulations of heavy metals such as As,Cd,Cu,Ni,Pb and Zn in agricultural soils,and the contents of Cd（2.44 mg kg^-1 ）,Pb（65.00 mg kg^-1 ）and Zn（144.13 mg kg^-1 ）are 7.97,3.69 and 1.63 times the corresponding background contents in soils of Hunan Province,respectively. 13.2%of As,68.5%of Cd,2.7%of Cu,2.7%of Ni,8.7%of Pb and 15.1%of Zn in soil samples from the investigated sites exceeded the maximum allowable heavy metal contents in the China Environmental Quality Standard for Soils（GB15618-1995,Grade Ⅱ）.The pollution characteristics of multi-metals in soils are mainly due to Cd.The contents of As,Cd,Cu,Pb and Zn in vegetable soils are significantly higher than the contents in paddy soils.95.8%, 68.8%,10.4%and 95.8%of vegetable samples exceeded the Maximum Levels of Contaminants in Foods（GB2762-2005）for As,Cd,Ni and Pb concentrations,respectively.There are significantly positive correlations between the concentrations of Cd,Pb and Zn in vegetables and the concentrations in the corresponding vegetable soils（p〈0.01）.It is very necessary to focus on the potential risk of heavy metals for food safety and human health in agricultural soils and vegetables in the midstream and downstream of the Xiangjiang River,Hunan Province of China.     

Correlation between molecular absorption spectral slope ratios and fluorescence humification indices in characterizing CDOM

Ultraviolet–visible absorption spectral slope ratios S_R (slope in 275–295 nm divided by slope in 350–400 nm) and humification index (HIX, integrated fluorescence emission in 435–480 nm divided by that in 435–480 and 300–345 nm) were compared when characterizing chromophoric dissolved organic matter (CDOM) in three humic acids and 44 whole water samples. HIX increased with increasing pH for humic acids, while their S_R showed much more complicated dependencies on pH. There was a negative correlation between S_R and HIX. S_R increased in the order terrestrial coal/peat < terrestrial soil/river < seawater, while HIX increased in the order seawater < terrestrial soil/river < terrestrial coal/peat. The comparative study in this work indicates that terrestrially derived CDOM has higher HIX and lower S_R than marine CDOM. Investigators may potentially use these two indices to compare qualitatively the character of CDOM in different sources (e.g., terrestrial vs. marine).     

The transmission of spatially-compact internal wave packets through a critical level

Results are presented from numerical simulations of the incidence of a spatially-compact beam of internal waves on a shear layer containing a critical level. It is found that a significant fraction of the energy of the incident beam is transmitted across the critical level when the packet is narrow in physical space and when the energy density of the packet is not too high so that nonlinear effects are weak. As either the packet width or its energy density increases, the presence of a critical level renders the shear layer increasingly opaque to the transmission of energy. The familiar exponentially small value of the transmission coefficient is recovered as the spatial width of the packet exceeds (roughly) eight to ten wave lengths.