大别山碧溪岭深色榴辉岩和片麻状花岗质岩石SHRIMP分析：晋宁期？…

本文报道大别山安徽省岳西县碧溪岭深色榴辉岩和片麻状花岗质岩石的锆石SHRIMP分析结果.深色榴辉岩的原岩为基性凝灰岩,锆石在岩石中主要产于石英、石榴子石和绿辉石内,为高压-超高压变质作用的产物,内部主体形成年龄约为757±7 Ma,代表高压-超高压榴辉岩相变质事件的时代;经受了后期流体改造的锆石边部年龄为223±3 Ma.在片麻状花岗质岩石中,发育韵律环带结构的深熔锆石形成于约727±15 Ma,受后期流体改造的锆石边部年龄为219±3 Ma.综合野外地质关系、区域地质背景和锆石的岩相学特征,笔者提出了碧溪岭榴辉岩相岩石高压-超高压变质作用发生于晋宁期,印支期仅代表一次后期流体改造事件的观点.     

中国东北黑龙江杂岩体蓝闪石片岩岩石学研究

黑龙江杂岩主要由蓝闪石片岩构成,蓝闪石片岩主要包括绿帘石、绿泥石、钠长石、钠质角闪石、多硅白云母和石英以及为数不多的榍石、钛铁矿和黑硬绿泥石。其中,钠质角闪石包括蓝闪石和镁质钠闪石。变质条件的压力（P）温度（T）评价条件为400－425℃和0.69－0.86 MPa,对应岩相为绿帘蓝闪石片岩相。黑龙江杂岩蓝闪石片岩的地球化学研究表明,其原岩是可与洋岛型（OIB）玄武岩和一些洋中脊型（E-MORB）玄武岩相对比的大洋玄武岩,这说明黑龙江杂岩蓝闪石片岩的玄武岩原岩是在海底山或者在大洋隆起条件下由富集源形成的;具有洋岛型玄武岩地球化学特征的变质玄武岩以及富锰的变质燧石、大理石、变质硬砂岩和蛇绿岩鳞片的加入证明黑龙江杂岩是消减—增生杂岩,它含有变形洋壳的碎块和在被改造的前震旦纪佳木斯岩体西边缘上形成于侏罗纪的增生楔岩石;黑龙江杂岩在原岩成分上可与活动大陆边缘许多增生的杂岩相当。     

流体包裹体轻烃有机气体组成及对矿床成因的制约

嵩溪银(锑)矿是一个新发现的大型独立银矿。矿物流体包裹体超高真空四极气相质谱系统测定显示，该矿成矿流体中存在多种轻烃有机气体，主要由C     

青海共和盆地达连海湖泊流域表土花粉-气候响应面分析

孢粉分析是研究过去全球变化的一种重要方法,而研究花粉与现代气候之间的相互关系是古气候定量重建研究中的前沿课题。要预测未来气候的中长期变化,必须从花粉记录中定量提取古气候信息,建立的多种孢粉-气候数学模型必须经过不同边界条件下的古气候数据检验校正才能应用到实际当中。花粉-气候响应面方法是考虑了花粉与气候间的非线形关系上,提出的将现代花粉丰度在地理空间的分布转换为气候空间的分布,并以提供定量的古气候数据,已被广泛应用于COHMAP等各种重要古气候研究项目。本文就是利用该方法,以青藏高原东北部共和盆地达连海湖泊流域54个表土样品中的花粉丰度及采样点的气候参数为基础数据,通过主成分分析选择了特征值高且指示意义明显的4种花粉类型,对其丰度与7月平均温度及年平均降水量两个气候参数进行多项式回归分析,其结果显示模型对数据拟合较好,为定量重建该区古气候变化提出了较为准确的数量指标。     

Mineralogy and Geochemistry of Uraniferous Sandstones in Fault Zone,Wadi El Sahu Area,Southwestern Sinai,Egypt: Implications for Provenance,Weathering and Tectonic Setting

Paleozoic rocks in the Wadi El Sahu area are affected by many major faults in different directions. A reverse fault trending NE-SW is exposed for about 300 m of its length as it cuts through the Abu Hamata and Adedia formations on the south side of Wadi El Sahu. A secondary ascending hydrothermal solution carrying heavy metals and radioactive minerals passed through the fault plain and the surrounding fractures, forming mineralized and radioactive zone. The mineralized zone thickness ranges from 60 cm to 200 cm along the fault plain. These rocks were analyzed radiometrically using a portable gamma-ray spectrometer, chemically by employing ICP-ES and ICP-MS, as well as mineralogically by both binocular and Environmental Scanning Electron microscope. Gold content was also determined by fire assay. REE and U contents reached up to 2682 and 1216 ppm, respectively. Mineralogical investigations indicated the presence of uraninite, torbernite, autunite, sklodowskite, kasolite as uranium minerals, thorite as a thorium mineral, monazite, allanite and xenotime as REE-bearing minerals, zircon and columbite as accessory minerals, gold and nickel as precious and base metals, in addition to cassiterite, chalcopyrite, chalcocite and chrysocolla. High REE and U contents are attributed to the circulation of epigenetic U and REE-bearing hydrothermal solutions along the fault plain and its surrounding fractures. Hydrothermal alteration processes could then be confirmed by the presence of the M-type tetrad effect in the REE-patterns of the ferruginous sandstone. The non-chondritic ratio of Nb/Ta, Zr/Hf and Y/Ho in the studied sandstone may be attributed to the tetrad effect. The Ce and Eu anomaly with unusual REE-patterns was represented by the presence of conjugated M-W tetrad effects, indicating either the dual effect of hydrothermal solutions or groundwater with seawater. The results clarify that the tetrad-effects could be used as evidence for the environment of deposition and as an indication for gold mineralization.     

冀东金厂峪金矿区钠长岩脉及青山口花岗岩体SHRIMP锆石U-Pb定年及其意义

金厂峪金矿床是冀东最大的金矿床 ,具有早期复脉型和晚期石英大脉型两种矿石类型。矿区产有多期钠长岩脉 ,且与含金矿脉有密切的时间和空间关系。青山口花岗岩体位于矿区西约 2～ 3km,有研究者认为金矿床成因上与花岗岩体有关。应用先进的 SHRIMP测年技术 ,测得肉红色钠长岩脉的锆石 w (2 0 7Pb) / w (2 0 6Pb)年龄为 (185 8± 8) Ma,青山口花岗岩体锆石 w(2 0 6Pb) / w(2 3 8U )年龄为 (199± 2 ) Ma。金厂峪金矿床的的复脉型矿化早于肉红色钠长岩脉 ,故其矿化的时代应在晚元古代。青山口岩体的年龄和区域上与辉钼矿化有关的花岗岩年龄一致 ,均为燕山早期。推测金厂峪金矿床晚期石英大脉型矿化中的辉钼矿化可能与青山口花岗岩体有关 ,石英大脉型金矿化时代为中生代燕山期     

Compositional Variation and Mineral Chemistry of the Jinshajiang and Lancangjiang Serpentinites,Yunnan Province,SW China

We present the whole rock and the mineral chemical data for upper mantle peridotites from the San-Jiang region in Yunnan, SW China. These peridotites are a part of a Paleo-Tethyan ophiolite belt occurring along the Jinshajiang and Lancangjiang suture zones. All samples of the Jinshajiang and Lancangjiang ultramafic rocks are completely serpentinized. The Jinshajiang serpentinites are characterized by no relict of olivine and pyroxene, and the Cr# content of spinels is 0.32–0.49. The Lancangjiang serpentinites were collected from two different locations; the northern location which has some relict of Opx(Al2O3 is 0.13–2.2 wt%, TiO 2 is 0.004–0.057 wt% and Mg# content is 0.895–0.933) and the Cr# content of spinel is 0.26-0.55; the southern location, which has some relict of Olivine(Fo = 90–92.5 and NiO = 0.12–0.26 wt%), and spinel Cr# ranging from 0.41 to 0.57. The whole rock geochemical and the mineral chemistry data imply that the Jinshajiang and Lancangjiang serpentinites represent abyssal peridotites residues after ~15–20% partial melting for the Jinshajiang and Lancangjiang serpentinites(south location), and ~11–19% partial melting for the Lancangjiang serpentinites(north location). In addition, the compositional trends of the spinel analyses of the Lancangjiang serpentinites imply that the MORB melt-peridotite interaction process played a significant role during their evolution. These processes are evidenced by an increase in Cr# with an increase in TiO 2, whereas the spinel analyses of the Jinshajiang serpentinites display an increase in Cr# with a decrease in Ti O2, indicating that the Jinshajiang serpentinites were subjected to a simple partial melting process.     

铁岭地区地下水电导率特征及其与主要污染元素的相关性分析

基于野外调查和室内测试,分析了铁岭地区不同水文地质单元内地下水的电导率特征,并圈定了其异常范围。对比研究证实,地下水的电导率异常与其污染状况密切相关。相关分析表明,营养盐离子NO3-、NO2-及Mg2 等不仅是引起地下水污染的重要组分,也是导致电导率异常的主要因素。     

飞机排放的NOx对中国地区NOx和臭氧的影响

根据2000年亚音速飞机排放的NO_x,利用三维全球化学输送模式(OSLOCTM2)研究亚音速飞机排放的NO_x对中国地区NO_x和臭氧的影响。模式结果表明:亚音速飞机排放的NO_x明显地影响中国北方地区,在1月份,250hPa高度NO_x的浓度增加大约50pptv,最大的相对变化为60％;在4月份,250hPa高度臭氧增加8ppbv,相对变化为5％。NO_x的增加主要是由于输送过程引起的,但臭氧的增加则是化学过程生成的结果。由于中国地区亚音速飞机排放的NO_x造成的NO_x的增加不超过10pptv,而且臭氧增加小于0.4ppbv。即使中国地区亚音速飞机排放的NO_x增加一倍,这个影响仍然比较小。     

Aliphatic and aromatic hydrocarbons in coastal Caspian Sea sediments

This investigation represents the first extensive study of the spatial distribution and sources of aliphatic (n-alkanes and unresolved complex mixture of fossil hydrocarbons) and polycyclic aromatic hydrocarbons (PAHs) in coastal sediments from the Caspian Sea. PAH concentrations, n-alkanes and biomarker profiles all suggested that there was limited petrogenic contamination in the shallow North Caspian Sea sediments, which are coarse with a low total organic carbon content. In contrast, moderate to high petrogenic contamination was found in the South Caspian Sea, in particular in the offshore oil fields near Baku, Azerbaijan. Contaminant patterns indicated that the PAHs were mainly from fossil sources, with higher contributions of pyrolytic only near industrialized and urban areas. A high contribution of perylene, a geochemically derived PAH, to the total PAHs was found in the west and south at sites influenced by the Kura, Safid Rud, Terek, Sulak and Samur Rivers.