Petroleum-related hydrocarbons in deep and subsurface sediments from South-Western Barents Sea

Subsurface sediments from a pockmark area in South-Western Barents Sea have been earlier found to contain elevated levels of petroleum-related polycyclic aromatic hydrocarbons. This work describes a comprehensive analysis of various biomarkers, including the highly source-specific hopanes, in a 4.5?m long gravity core from the same area, together with subsurface sediment samples from other areas in the region without pockmarks present ("background samples"). A clear difference between the pockmark gravity core and the background sediment cores was found, both with regard to genesis and the level of transformation of organic matter. A number of indicator parameters, such as methylphenanthrene index (MPI-1), point towards a significantly higher maturity of hydrocarbons in the pockmark core throughout its length as compared to the other sampled locations. Higher contents of microbial hopanoids (hopenes) may indicate the former presence of petroleum. These findings confirm the hypothesis of a natural hydrocarbon source in the deeper strata present in the studied location with pockmarks.     

http://www.sciencedirect.com/science/article/pii/S1674987111000594

A new model is suggested for the history of the Baikal Rift,in deviation from the classic two-stage evolution scenario,based on a synthesis of the available data from the Baikal Basin and revised correlation between tectonic-lithological-stratigraphic complexes(TLSC) in sedimentary sections around Lake Baikal and seismic stratigraphic sequences(SSS) in the lake sediments.Unlike the previous models,the revised model places the onset of rifting during Late Cretaceous and comprises three major stages which are subdivided into several substages.The stages and the substages are separated by events of tectonic activity and stress reversal when additional compression produced folds and shear structures.The events that mark the stage boundaries show up as gaps,unconformities,and deformation features in the deposition patterns. The earliest Late Cretaceous-Oligocene stage began long before the India-Eurasia collision in a setting of diffuse extension that acted over a large territory of Asia.The NW-SE far-field pure extension produced an NE-striking half-graben oriented along an old zone of weakness at the edge of the Siberian craton.That was already the onset of rift evolution recorded in weathered lacustrine deposits on the Baikal shore and in a wedge-shaped acoustically transparent seismic unit in the lake sediments.The second stage spanning Late Oligocene-Early Pliocene time began with a stress change when the effect from the Eocene India-Eurasia collision had reached the region and became a major control of its geodynamics.The EW and NE transpression and shear from the collisional front transformed the Late Cretaceous half-graben into a U-shaped one which accumulated a deformed layered sequence of sediments.Rifting at the latest stage was driven by extension from a local source associated with hot mantle material rising to the base of the rifted crust.The asthenospheric upwarp first induced the growth of the Baikal dome and the related change from finer to coarser molasse deposition.With time,the upwarp became a more powerful stress source than the collision,and the stress vector returned to the previous NW-SE extension that changed the rift geometry back to a half-graben. The layered Late Pliocene-Quaternary subaerial tectonic-lithological-stratigraphic and the Quaternary submarine seismic stratigraphic units filling the latest half-graben remained almost undeformed.The rifting mechanisms were thus passive during two earlier stages and active during the third stage. The three-stage model of the rift history does not rule out the previous division into two major stages but rather extends its limits back into time as far as the Maastrichtian.Our model is consistent with geological, stratigraphic,structural,and geophysical data and provides further insights into the understanding of rifting in the Baikal region in particular and continental rifting in general.     

Delayed impact of new volcanic ejecta on ground water quality

We observed long-term changes in the concentrations of dissolved ions in ground water caused by leachate from new volcanic ejecta deposited on the ground surface of the volcanic Miyakejima Island, Japan. Water samples were collected from nine wells and two rain collectors over a period of more than 10 years, and samples of runoff water were collected periodically. The samples were analyzed for temperature, pH, alkalinity, Cl⁻, and SO₄²⁻; some of the samples were also analyzed for δ¹³C. Because the leachate from the volcanic ejecta contained sulfate, we recorded an increase in SO₄²⁻ concentrations in the (unconfined) well water. The increase in SO₄²⁻ was initially detected between less than 1.4 and 5.2 years after the eruption, showing peak concentrations from 2.4 to 6.4 years after the eruption. This delayed response reflects the transit time of downward-moving SO₄²⁻ in the vadose zone, corresponding to an apparent movement rate of 0.4 to 7.2 cm/d. The rate relates to the mean recharge, represented as a fraction of local mean rainfall, and is calculated using the Cl⁻ balance method. The magnitude of the recorded increases reflects the volume of volcanic mudflow on the ground surface within the basin. For the management of ground water after an eruption, it is therefore important to know the chemical properties of the volcanic ejecta and the spatial distribution of mudflow to estimate the magnitude of the effect of ejecta on ground water quality.     

Impacts of macroalgal spores on the dynamics of adult macroalgae in a eutrophic estuary: high versus low hydrodynamic seasons and long-term simulations for global warming scenarios

A model describing macroalgal early life stages and adult dynamics was used to quantify the effects of non-adult forms on the productivity of adult macroalgae in a eutrophic estuary. Predictions indicate that during years with mild winters and low rainfall, spring blooms will occur at the expense of the growth and reproduction of overwintering adults and without the contribution of the spore bank. In these circumstances, there is a positive correlation between the intensity of the blooms and the biomass of overwintering adults until a maximum threshold value. On the contrary, in years with high rainfall and low or inexistent biomass of overwintering adults, the onset of adult’s growth depends on the biomass of viable dormant spores, the growing season occurs later and adult productivity is very limited. Long-term predictions for climate change scenarios suggest that, in general, global warming will have adverse affects on Ulva intestinalis productivity, with the adults being more affected than the early life stages.     

Simplified approach for design of raft foundations against fault rupture. Part Ⅱ： soil-structure interaction

This is the second paper of two, which describe the results of an integrated research effort to develop a four-step simplified approach for design of raft foundations against dip-slip （normal and thrust） fault rupture. The first two steps dealing with fault rupture propagation in the free-field were presented in the companion paper. This paper develops an approximate analytical method to analyze soil-foundation-structure interaction （SFSI）, involving two additional phenomena： （i） fault rupture diversion （Step 3）; and （ii） modification of the vertical displacement profile （Step 4）. For the first phenomenon （Step 3）, an approximate energy-based approach is developed to estimate the diversion of a fault rupture due to presence of a raft foundation. The normalized critical load for complete diversion is shown to be a function of soil strength, coefficient of earth pressure at rest, bedrock depth, and the horizontal position of the foundation relative to the outcropping fault rupture. For the second phenomenon （Step 4）, a heuristic approach is proposed, which ＂scans＂ through possible equilibrium positions to detect the one that best satisfies force and moment equilibrium. Thus, we account for the strong geometric nonlinearities that govern this interaction, such as uplifting and second order （P-△） effects. Comparisons with centrifuge-validated finite element analyses demonstrate the efficacy of the method. Its simplicity makes possible its utilization for preliminary design.     

Lethal toxicity of industrial detergent on bottom dwelling sentinels

We used fresh and brackish water shrimp （Desmoscaris trispinosa and Palaemonetes africanus）, in sediment bioassays to assess the toxicity of an industrial detergent containing high levels of anionic surfactant （linear alkylbenzene sulphonate （LAS））. The Organization for Economic Cooperation and Development （OECD）, # 218 direct sediment toxicity assessment was employed. The organisms were exposed to different concentrations （31.25, 62.5, 125,250 and 500 mg/kg） of the chemical （Neatex） in replicate treatments. Percentage mortality was measured as the ecological endpoint. Mean mortality and estimated lethal concentration LCso values varied with species type, concentration and exposure duration. The statistical variation in the observed mean mortality of the test organisms in the chemical and the control treatment shows that mortality may be induced by the effect of the chemicals. The lethal concentration （LCso） was significantly different at levels ofp 〈 0.05 for the fresh and brackish water experiments. Consequently, assessment of water and sediment quality as a result of chemical pollutants was necessary for protecting some of the more sensitive benthic invertebrates representing the major proportion of the diet of many species in the Niger Delta ecological zone.     

2009年意大利中部阿奎拉地震DInSAR同震位移的有限断层反演

根据环境卫星Envisat和COSMO—SkyMed模型（为同震位错研究而首次设计的X波段反演干涉图）的DInSAR干涉图,确定了2009年4月6日阿奎拉Mw=6．3级地震时激发的断层几何形状及运动特征。我们的主震最佳拟合解为一个约16km长、12km宽的正断层,存在小的右旋分量,向西南倾斜47°,最大滑动约90cm。虽然地震位错可能只有1km深,但是断层面的上倾投影与标绘的帕加尼卡-南德米特里奥断层的北段相符合,在现场观察到了该断层地表破裂的迹线。该断层在现有震源目录中的缺失表明,需要对具体的地表和地下进行进一步的地质和地球物理勘测,以便对局部规模的地震危险性做出更准确的评估。