Distribution of petroleum hydrocarbons and organochlorinated contaminants in marine biota and coastal sediments from the ROPME Sea Area during 2005

The composition and spatial distribution of various petroleum hydrocarbons (PHs), comprising both aliphatic and polycyclic aromatic hydrocarbons (PAHs), and selected chlorinated pesticides and PCBs were measured in biota and coastal sediments from seven countries in the Persian Gulf and the Gulf of Oman (Bahrain, Iran, Kuwait, Oman, Qatar, Saudi Arabia and the United Arab Emirates). Evidence of extensive marine contamination with respect to organochlorinated compounds and PHs was not observed. Only one site, namely the BAPCO oil refinery in Bahrain, was considered to be chronically contaminated. Comparison of the results from this survey for Σ DDTs and Σ PCBs in rock oysters from the Gulf of Oman with similar measurements made at the same locations over the past two decades indicates a temporal trend of overall decreasing Σ PCB concentrations in oysters, whereas Σ DDTs levels have little changed during that period.     

PCBs and PAHs in sea-surface microlayer and sub-surface water samples of the Venice Lagoon (Italy)

Polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) are two classes of micropollutants intensively monitored and regulated due to their toxicity, persistency and wide diffusion. Their concentrations have been investigated in sea-microlayer (SML) and sub-surface water (SSW) samples collected at two sites of the Venice Lagoon, a fragile ecosystem highly influenced by industrial and anthropogenic emissions. The total sigmaPCB concentration varies from 0.45 ng/l to 2.1 ng/l in SSW while a clear enrichment is observed in the SML, where it ranges from 1.2 ng/l to 10.5 ng/l. The total sigmaPAH concentration shows marked differences between the two stations and varies from 12.4 ng/l to 266.8 ng/l in SSW; in SML it is more uniform and ranges from 19.6 ng/l to 178.9 ng/l. The enrichment factors are not larger than 1 for both pollutants in the 'dissolved' phase, while they are most significant for the 'particulate' phase (sigmaPCB: 5-9; sigmaPAH: 4-14).     

A biomonitoring study: Heavy metals in macroalgae from eastern Aegean coastal areas

The concentrations of metals were measured in macroalgae species seasonally at eight coastal stations along the eastern Aegean coast. Sediment and seawater samples were also collected to detect their metal contents in order to gain more information on the environmental conditions of the area and possible bioaccumulation patterns. The aim of this study is, to gather more information on the use of selected species as cosmopolitan biomonitors for the eastern Aegean; to provide information on the marine environmental quality by the use of macroalgae and to determine which algae species are suitable as biomonitoring species for the study area. The relative abundance of metals in macroalgae decreases in the order: Fe-Zn-Cu-Cr-Cd-Hg-Pb and seawater: Fe-Zn-Pb-Cu-Cr-Cd-Hg. In sediment the distribution order from higher to lower was Fe-Cr-Zn-Pb-Cu-Hg-Cd. The brown algae Cystoseira sp., the green algae Ulva sp. and Enteromorpha sp. possess high potential as cosmopolitan biomonitors for trace metals in the Aegean Sea.     

中国主要地块显生宙古地磁视极移曲线与地块运动

基于华北、扬子和塔里木三大地块最新古地磁结果,并重新审视已有的古地磁数据,绘制了三大地块显生宙以来的古地磁视极移曲线.以此为基础,推算了各地块古纬度和取向的变化特征.进而分析了三大地块及其周边地块的运动学特征及相互间的对接和缝合过程.早古生代,华北、扬子、塔里木地块都位于南半球中低纬度地区.华北地块在动力学上是独立的,其运动特征以平移为主,旋转运动为辅;扬子和塔里木地块与冈瓦纳大陆关系密切,塔里木地块很可能在晚奥陶世远离冈瓦纳大陆,在二叠纪与西伯利亚板块对接;我国华北和蒙古联合地块与西伯利亚板块的对接则是在晚保罗世完成的 扬子与华北地块的对接过程是先东后西,东部的对接发生在晚二叠世,对接时结合带位于北纬6°～8°.晚三叠世两地块在西部门合时,结合带位于北纬25°左右.两地块在西部对接的同时,在东部产生了应力释放,使最初俯冲到上地慢的部分陆壳物质被推挤上升,与苏鲁-大别地区的超高压变质岩形成的时代相同.从晚二叠世到早中侏罗世华北与扬子地块以东部为支点经历了大规模的相对旋转.晚侏罗世三大地块在动力学意义上已成为整体.在中国拉萨地块和印度次大陆与中国大陆对接缝合产生的力矩作用下.晚保罗世以来三大地块统一显示了约为20°的顺时针旋转运动.     

华北克拉通太古宙研究若干进展

华北克拉通存在3.8 Ga以上的地质演化历史。本文对近年来我们在鞍本、冀东、鲁西、胶东和阴山地区研究取得的进展作了简要介绍。在鞍山,深沟寺杂岩获得~3770 Ma,3600–3660 Ma,~3450 Ma,3310–3330 Ma和~3120 Ma锆石年龄,与白家坟杂岩和东山杂岩的岩浆事件十分类似。在冀东,对曹庄杂岩副变质斜长角闪岩和石榴黑云片麻岩定年,发现大量3.5–3.8 Ga碎屑锆石,并获得~2.5 Ga变质锆石年龄,冀东地区很可能存在始太古代岩石,可把曹庄杂岩形成时代限定在2.5 Ga和3.4 Ga之间。在鲁西,把太古宙基底从东北到西南依次划分为A、B、C三个岩带:A带主要为新太古代晚期的壳源花岗岩,B带主要为新太古代早期的岩石,C带主要为新太古代晚期的新生岩浆岩。鲁西是华北克拉通新太古代早期岩石分布最广泛的地区,也是华北克拉通确认新太古代早期和晚期表壳岩系共存的唯一地区。在胶东,规模巨大的2.9 Ga岩浆热事件被识别出来,它是强烈地幔添加作用的产物。可能作为岩浆板底垫托作用的结果,2.9 Ga岩石与2.7 Ga岩石一道,在新太古代晚期(~2.5 Ga)遭受强烈变质改造。在阴山地块,除2.5 Ga表壳岩和侵入岩外,还存在2.7 Ga英云闪长岩和2.6 Ga花岗岩。新获得的资料表明阴山地块与华北克拉通东部陆块具有类似的早前寒武纪地质演化历史。还对华北克拉通太古宙变质基底的锆石年龄和Hf同位素组成及全岩Nd同位素组成进行了统计研究。结合前人工作,初步总结了华北克拉通太古宙地质演化特点。认为华北克拉通与其它克拉通类似,新太古代早期—中太古代晚期是陆壳形成增生的主要时期,但最强烈广泛的构造热事件存在于新太古代晚期。在我们新提出的构造区划中,划分出了三个古陆块(2.6 Ga),即东部古陆块、南部古陆块和中部古陆块。     

高速发展的中国超硬材料

中国经过40年超硬材料艰辛的研发历程，现在全国超硬材料已由开始的研制开发，发展成今日的超硬材料行业，年产量已达20亿ct以上(还有信息说达25亿ct左右)。它已是国民经济发展高新技术产业不可缺少的重要组成部分。同样在发展探矿工程、岩土工程及多种金刚石钻探、多种特种钻探方面，也是无可替代的重要磨料，这方面的信息对我们指导发展近代探矿工程、岩土工程是有意义的。     

密坑山锡矿同位素年代学研究的启示

密坑山锡矿田位于江西省会昌县西南约40km处。该区为一晚中生代破火山,火山岩为上侏罗统鸡笼嶂组流纹质凝灰熔岩及火山碎屑岩,火山口周围环状及放射状断裂发育,火山口中心为浅成相的密坑山似斑状钾长花岗岩中央岩株侵入体所充填。上世纪80年代以来,在该岩体与流纹质凝灰熔岩的内外接触带相继发现了岩背、淘锡坝、苦竹岽、矿背、上湾等一批大、中型锡多金属矿床或矿点,表明这一岩体对成矿具有重要的制约作用。本文运用LA-ICP-MS锆石U-Pb、全岩Rb-Sr和辉钼矿Re-Os同位素定年技术,对密坑山岩体及相关锡矿床的成岩和成矿年龄进行了精确测…     

应力作用下岩石的化学动力学溶解机制研究

通过结合化学热力学及动力学、过渡态理论和岩石力学等方面的知识,建立了应力作用下岩石的溶解动力学模型,分析了应力作用对岩石固相物质活度及矿物溶解动力学速率的影响,探讨了应力作用下水岩相互作用机制。研究结果表明：岩石所承受应力与周围流体压力之间存在的应力差所产生的化学势差是应力作用下溶解反应的驱动力;应力的施加显著提高了岩石中固相物质的活度,由此加快了矿物溶解反应的动力学速率;应力作用下的岩石细观溶解机制可根据固液界面应力分配及优先溶解部位上的差别分别用水膜扩散模型或岛渠模型进行描述;应力作用下水岩相互作用存在着应力、化学与渗流的3场耦合问题：应力推动化学反应的发生,化学作用使得岩石表面的细观形貌发生改变,局部的应力分布及大小也随着形貌的变化而改变,进而影响化学反应发生的位置及进程,同时也改变渗流通道的演化规律     

印度前寒武纪沉积岩层序特征及其与现代沉积物的对比

引言印度半岛地盾含有许多厚的前寒武纪时代的沉积岩层。Pichamuthu(1967)对印度的前寒武纪地层作了很好的评述;Naqvi等(1974)总结了印度地盾的演化历史。印度地盾前寒武纪沉积岩层显示了不同程度的变质。比17亿年老的沉积岩层都经受了变质作用,范围从麻粒岩相到低级角闪岩相。不过,在许多沉积盆地中,是可以认识和研究它们的沉积特征的。     

Age and Geochemical Characteristics of Major Mafic Dyke Swarms in the Southern Part of the Siberian Craton

正Several generations of mafic dyke swarms of different ages and geochemical characteristics cut Precambrian rocks of the southern part of the Siberian craton(Irkutsk Promontory).Each generation of dykes is related to a